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[Frenklach et al. (1995)] (GRI-Mech 2.11)

GRI-Mech 2.11 is the latest version of a mechanism created, validated, and maintained by the Gas Research Institute. It and other information are available in electronic form through the World Wide Web at http://www.gri.org and http://www.me.berkeley.edu/gri_mech/.

Reaction A (cm-moles-sec-K) n E (cal/mole)
       
2O+M $\rightleftharpoons$O2+M 1.200E+17 -1.000 .00
Enhanced Collision Efficiencies:
H2=2.40, H2O=15.40, CH4=2.00, CO=1.75, CO2=3.60, C2H6=3.00, AR=.83
O+H+M $\rightleftharpoons$OH+M 5.000E+17 -1.000 .00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
O+H2 $\rightleftharpoons$H+OH 5.000E+04 2.670 6290.00
O+HO2 $\rightleftharpoons$OH+O2 2.000E+13 .000 .00
O+H2O2 $\rightleftharpoons$OH+HO2 9.630E+06 2.000 4000.00
O+CH $\rightleftharpoons$H+CO 5.700E+13 .000 .00
O+CH2 $\rightleftharpoons$H+HCO 8.000E+13 .000 .00
O+CH2(S) $\rightleftharpoons$H2+CO 1.500E+13 .000 .00
O+CH2(S) $\rightleftharpoons$H+HCO 1.500E+13 .000 .00
O+CH3 $\rightleftharpoons$H+CH2O 8.430E+13 .000 .00
O+CH4 $\rightleftharpoons$OH+CH3 1.020E+09 1.500 8600.00
O+CO+M $\rightleftharpoons$CO2+M 6.020E+14 .000 3000.00
Enhanced Collision Efficiencies:
H2=2.00, O2=6.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=3.50, C2H6=3.00, AR=.50
O+HCO $\rightleftharpoons$OH+CO 3.000E+13 .000 .00
O+HCO $\rightleftharpoons$H+CO2 3.000E+13 .000 .00
O+CH2O $\rightleftharpoons$OH+HCO 3.900E+13 .000 3540.00
O+CH2OH $\rightleftharpoons$OH+CH2O 1.000E+13 .000 .00
O+CH3O $\rightleftharpoons$OH+CH2O 1.000E+13 .000 .00
O+CH3OH $\rightleftharpoons$OH+CH2OH 3.880E+05 2.500 3100.00
O+CH3OH $\rightleftharpoons$OH+CH3O 1.300E+05 2.500 5000.00
O+C2H $\rightleftharpoons$CH+CO 5.000E+13 .000 .00
O+C2H2 $\rightleftharpoons$H+HCCO 1.020E+07 2.000 1900.00
O+C2H2 $\rightleftharpoons$OH+C2H 4.600E+19 -1.410 28950.00
O+C2H2 $\rightleftharpoons$CO+CH2 1.020E+07 2.000 1900.00
O+C2H3 $\rightleftharpoons$H+CH2CO 3.000E+13 .000 .00
O+C2H4 $\rightleftharpoons$CH3+HCO 1.920E+07 1.830 220.00
O+C2H5 $\rightleftharpoons$CH3+CH2O 1.320E+14 .000 .00
O+C2H6 $\rightleftharpoons$OH+C2H5 8.980E+07 1.920 5690.00
O+HCCO $\rightleftharpoons$H+2CO 1.000E+14 .000 .00
O+CH2CO $\rightleftharpoons$OH+HCCO 1.000E+13 .000 8000.00
O+CH2CO $\rightleftharpoons$CH2+CO2 1.750E+12 .000 1350.00
O2+CO $\rightleftharpoons$O+CO2 2.500E+12 .000 47800.00
O2+CH2O $\rightleftharpoons$HO2+HCO 1.000E+14 .000 40000.00
H+O2+M $\rightleftharpoons$HO2+M 2.800E+18 -.860 .00
Enhanced Collision Efficiencies:
O2=.00, H2O=.00, CO=.75, CO2=1.50, C2H6=1.50, N2=.00, AR=.00
H+2O2 $\rightleftharpoons$HO2+O2 3.000E+20 -1.720 .00
H+O2+H2O $\rightleftharpoons$HO2+H2O 9.380E+18 -.760 .00
H+O2+N2 $\rightleftharpoons$HO2+N2 3.750E+20 -1.720 .00
H+O2+AR $\rightleftharpoons$HO2+AR 7.000E+17 -.800 .00
H+O2 $\rightleftharpoons$O+OH 8.300E+13 .000 14413.00
2H+M $\rightleftharpoons$H2+M 1.000E+18 -1.000 .00
Enhanced Collision Efficiencies:
H2=.00, H2O=.00, CH4=2.00, CO2=.00, C2H6=3.00, AR=.63
2H+H2 $\rightleftharpoons$2H2 9.000E+16 -.600 .00
2H+H2O $\rightleftharpoons$H2+H2O 6.000E+19 -1.250 .00
2H+CO2 $\rightleftharpoons$H2+CO2 5.500E+20 -2.000 .00
H+OH+M $\rightleftharpoons$H2O+M 2.200E+22 -2.000 .00
Enhanced Collision Efficiencies:
H2=.73, H2O=3.65, CH4=2.00, C2H6=3.00, AR=.38
H+HO2 $\rightleftharpoons$O+H2O 3.970E+12 .000 671.00
H+HO2 $\rightleftharpoons$O2+H2 2.800E+13 .000 1068.00
H+HO2 $\rightleftharpoons$2OH 1.340E+14 .000 635.00
H+H2O2 $\rightleftharpoons$HO2+H2 1.210E+07 2.000 5200.00
H+H2O2 $\rightleftharpoons$OH+H2O 1.000E+13 .000 3600.00
H+CH $\rightleftharpoons$C+H2 1.100E+14 .000 .00
H+CH2(+M) $\rightleftharpoons$CH3(+M) 2.500E+16 -.800 .00
Low pressure limit 3.200E+27 -3.140 1230.00
Troe parameters: a=.6800, T $^{\ast\ast\ast}$=78.00, T$^\ast$=1995.00, T $^{\ast\ast}$=5590.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+CH2(S) $\rightleftharpoons$CH+H2 3.000E+13 .000 .00
H+CH3(+M) $\rightleftharpoons$CH4(+M) 1.270E+16 -.630 383.00
Low pressure limit 2.477E+33 -4.760 2440.00
Troe parameters: a=.7830, T $^{\ast\ast\ast}$=74.00, T$^\ast$=2941.00, T $^{\ast\ast}$=6964.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+CH4 $\rightleftharpoons$CH3+H2 6.600E+08 1.620 10840.00
H+HCO(+M) $\rightleftharpoons$CH2O(+M) 1.090E+12 .480 -260.00
Low pressure limit 1.350E+24 -2.570 1425.00
Troe parameters: a=.7824, T $^{\ast\ast\ast}$=271.00, T$^\ast$=2755.00, T $^{\ast\ast}$=6570.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+HCO $\rightleftharpoons$H2+CO 7.340E+13 .000 .00
H+CH2O(+M) $\rightleftharpoons$CH2OH(+M) 5.400E+11 .454 3600.00
Low pressure limit 1.270E+32 -4.820 6530.00
Troe parameters: a=.7187, T $^{\ast\ast\ast}$=103.00, T$^\ast$=1291.00, T $^{\ast\ast}$=4160.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
H+CH2O(+M) $\rightleftharpoons$CH3O(+M) 5.400E+11 .454 2600.00
Low pressure limit 2.200E+30 -4.800 5560.00
Troe parameters: a=.7580, T $^{\ast\ast\ast}$=94.00, T$^\ast$=1555.00, T $^{\ast\ast}$=4200.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
H+CH2O $\rightleftharpoons$HCO+H2 2.300E+10 1.050 3275.00
H+CH2OH(+M) $\rightleftharpoons$CH3OH(+M) 1.800E+13 .000 .00
Low pressure limit 3.000E+31 -4.800 3300.00
Troe parameters: a=.7679, T $^{\ast\ast\ast}$=338.00, T$^\ast$=1812.00, T $^{\ast\ast}$=5081.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
H+CH2OH $\rightleftharpoons$H2+CH2O 2.000E+13 .000 .00
H+CH2OH $\rightleftharpoons$OH+CH3 1.200E+13 .000 .00
H+CH2OH $\rightleftharpoons$CH2(S)+H2O 6.000E+12 .000 .00
H+CH3O(+M) $\rightleftharpoons$CH3OH(+M) 5.000E+13 .000 .00
Low pressure limit 8.600E+28 -4.000 3025.00
Troe parameters: a=.8902, T $^{\ast\ast\ast}$=144.00, T$^\ast$=2838.00, T $^{\ast\ast}$=45569.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
H+CH3O $\rightleftharpoons$H+CH2OH 3.400E+06 1.600 .00
H+CH3O $\rightleftharpoons$H2+CH2O 2.000E+13 .000 .00
H+CH3O $\rightleftharpoons$OH+CH3 3.200E+13 .000 .00
H+CH3O $\rightleftharpoons$CH2(S)+H2O 1.600E+13 .000 .00
H+CH3OH $\rightleftharpoons$CH2OH+H2 1.700E+07 2.100 4870.00
H+CH3OH $\rightleftharpoons$CH3O+H2 4.200E+06 2.100 4870.00
H+C2H(+M) $\rightleftharpoons$C2H2(+M) 1.000E+17 -1.000 .00
Low pressure limit 3.750E+33 -4.800 1900.00
Troe parameters: a=.6464, T $^{\ast\ast\ast}$=132.00, T$^\ast$=1315.00, T $^{\ast\ast}$=5566.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+C2H2(+M) $\rightleftharpoons$C2H3(+M) 5.600E+12 .000 2400.00
Low pressure limit 3.800E+40 -7.270 7220.00
Troe parameters: a=.7507, T $^{\ast\ast\ast}$=98.50, T$^\ast$=1302.00, T $^{\ast\ast}$=4167.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+C2H3(+M) $\rightleftharpoons$C2H4(+M) 6.080E+12 .270 280.00
Low pressure limit 1.400E+30 -3.860 3320.00
Troe parameters: a=.7820, T $^{\ast\ast\ast}$=207.50, T$^\ast$=2663.00, T $^{\ast\ast}$=6095.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+C2H3 $\rightleftharpoons$H2+C2H2 3.000E+13 .000 .00
H+C2H4(+M) $\rightleftharpoons$C2H5(+M) 1.080E+12 .454 1820.00
Low pressure limit 1.200E+42 -7.620 6970.00
Troe parameters: a=.9753, T $^{\ast\ast\ast}$=210.00, T$^\ast$=984.00, T $^{\ast\ast}$=4374.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+C2H4 $\rightleftharpoons$C2H3+H2 1.325E+06 2.530 12240.00
H+C2H5(+M) $\rightleftharpoons$C2H6(+M) 5.210E+17 -.990 1580.00
Low pressure limit 1.990E+41 -7.080 6685.00
Troe parameters: a=.8422, T $^{\ast\ast\ast}$=125.00, T$^\ast$=2219.00, T $^{\ast\ast}$=6882.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H+C2H5 $\rightleftharpoons$H2+C2H4 2.000E+12 .000 .00
H+C2H6 $\rightleftharpoons$C2H5+H2 1.150E+08 1.900 7530.00
H+HCCO $\rightleftharpoons$CH2(S)+CO 1.000E+14 .000 .00
H+CH2CO $\rightleftharpoons$HCCO+H2 5.000E+13 .000 8000.00
H+CH2CO $\rightleftharpoons$CH3+CO 1.130E+13 .000 3428.00
H+HCCOH $\rightleftharpoons$H+CH2CO 1.000E+13 .000 .00
H2+CO(+M) $\rightleftharpoons$CH2O(+M) 4.300E+07 1.500 79600.00
Low pressure limit 5.070E+27 -3.420 84350.00
Troe parameters: a=.9320, T $^{\ast\ast\ast}$=197.00, T$^\ast$=1540.00, T $^{\ast\ast}$=10300.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
OH+H2 $\rightleftharpoons$H+H2O 2.160E+08 1.510 3430.00
2OH(+M) $\rightleftharpoons$H2O2(+M) 7.400E+13 -.370 .00
Low pressure limit 2.300E+18 -.900 -1700.00
Troe parameters: a=.7346, T $^{\ast\ast\ast}$=94.00, T$^\ast$=1756.00, T $^{\ast\ast}$=5182.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
2OH $\rightleftharpoons$O+H2O 3.570E+04 2.400 -2110.00
OH+HO2 $\rightleftharpoons$O2+H2O 2.900E+13 .000 -500.00
OH+H2O2 $\rightleftharpoons$HO2+H2O 1.750E+12 .000 320.00
Duplicate Reaction    
OH+H2O2 $\rightleftharpoons$HO2+H2O 5.800E+14 .000 9560.00
Duplicate Reaction    
OH+C $\rightleftharpoons$H+CO 5.000E+13 .000 .00
OH+CH $\rightleftharpoons$H+HCO 3.000E+13 .000 .00
OH+CH2 $\rightleftharpoons$H+CH2O 2.000E+13 .000 .00
OH+CH2 $\rightleftharpoons$CH+H2O 1.130E+07 2.000 3000.00
OH+CH2(S) $\rightleftharpoons$H+CH2O 3.000E+13 .000 .00
OH+CH3(+M) $\rightleftharpoons$CH3OH(+M) 6.300E+13 .000 .00
Low pressure limit 2.700E+38 -6.300 3100.00
Troe parameters: a=.2105, T $^{\ast\ast\ast}$=83.50, T$^\ast$=5398.00, T $^{\ast\ast}$=8370.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
OH+CH3 $\rightleftharpoons$CH2+H2O 5.600E+07 1.600 5420.00
OH+CH3 $\rightleftharpoons$CH2(S)+H2O 2.501E+13 .000 .00
OH+CH4 $\rightleftharpoons$CH3+H2O 1.000E+08 1.600 3120.00
OH+CO $\rightleftharpoons$H+CO2 4.760E+07 1.228 70.00
OH+HCO $\rightleftharpoons$H2O+CO 5.000E+13 .000 .00
OH+CH2O $\rightleftharpoons$HCO+H2O 3.430E+09 1.180 -447.00
OH+CH2OH $\rightleftharpoons$H2O+CH2O 5.000E+12 .000 .00
OH+CH3O $\rightleftharpoons$H2O+CH2O 5.000E+12 .000 .00
OH+CH3OH $\rightleftharpoons$CH2OH+H2O 1.440E+06 2.000 -840.00
OH+CH3OH $\rightleftharpoons$CH3O+H2O 6.300E+06 2.000 1500.00
OH+C2H $\rightleftharpoons$H+HCCO 2.000E+13 .000 .00
OH+C2H2 $\rightleftharpoons$H+CH2CO 2.180E-04 4.500 -1000.00
OH+C2H2 $\rightleftharpoons$H+HCCOH 5.040E+05 2.300 13500.00
OH+C2H2 $\rightleftharpoons$C2H+H2O 3.370E+07 2.000 14000.00
OH+C2H2 $\rightleftharpoons$CH3+CO 4.830E-04 4.000 -2000.00
OH+C2H3 $\rightleftharpoons$H2O+C2H2 5.000E+12 .000 .00
OH+C2H4 $\rightleftharpoons$C2H3+H2O 3.600E+06 2.000 2500.00
OH+C2H6 $\rightleftharpoons$C2H5+H2O 3.540E+06 2.120 870.00
OH+CH2CO $\rightleftharpoons$HCCO+H2O 7.500E+12 .000 2000.00
2HO2 $\rightleftharpoons$O2+H2O2 1.300E+11 .000 -1630.00
Duplicate Reaction    
2HO2 $\rightleftharpoons$O2+H2O2 4.200E+14 .000 12000.00
Duplicate Reaction    
HO2+CH2 $\rightleftharpoons$OH+CH2O 2.000E+13 .000 .00
HO2+CH3 $\rightleftharpoons$O2+CH4 1.000E+12 .000 .00
HO2+CH3 $\rightleftharpoons$OH+CH3O 2.000E+13 .000 .00
HO2+CO $\rightleftharpoons$OH+CO2 1.500E+14 .000 23600.00
HO2+CH2O $\rightleftharpoons$HCO+H2O2 1.000E+12 .000 8000.00
C+O2 $\rightleftharpoons$O+CO 5.800E+13 .000 576.00
C+CH2 $\rightleftharpoons$H+C2H 5.000E+13 .000 .00
C+CH3 $\rightleftharpoons$H+C2H2 5.000E+13 .000 .00
CH+O2 $\rightleftharpoons$O+HCO 3.300E+13 .000 .00
CH+H2 $\rightleftharpoons$H+CH2 1.107E+08 1.790 1670.00
CH+H2O $\rightleftharpoons$H+CH2O 1.713E+13 .000 -755.00
CH+CH2 $\rightleftharpoons$H+C2H2 4.000E+13 .000 .00
CH+CH3 $\rightleftharpoons$H+C2H3 3.000E+13 .000 .00
CH+CH4 $\rightleftharpoons$H+C2H4 6.000E+13 .000 .00
CH+CO(+M) $\rightleftharpoons$HCCO(+M) 5.000E+13 .000 .00
Low pressure limit 2.690E+28 -3.740 1936.00
Troe parameters: a=.5757, T $^{\ast\ast\ast}$=237.00, T$^\ast$=1652.00, T $^{\ast\ast}$=5069.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
CH+CO2 $\rightleftharpoons$HCO+CO 3.400E+12 .000 690.00
CH+CH2O $\rightleftharpoons$H+CH2CO 9.460E+13 .000 -515.00
CH+HCCO $\rightleftharpoons$CO+C2H2 5.000E+13 .000 .00
CH2+O2 $\rightleftharpoons$OH+HCO 1.320E+13 .000 1500.00
CH2+H2 $\rightleftharpoons$H+CH3 5.000E+05 2.000 7230.00
2CH2 $\rightleftharpoons$H2+C2H2 3.200E+13 .000 .00
CH2+CH3 $\rightleftharpoons$H+C2H4 4.000E+13 .000 .00
CH2+CH4 $\rightleftharpoons$2CH3 2.460E+06 2.000 8270.00
CH2+CO(+M) $\rightleftharpoons$CH2CO(+M) 8.100E+11 .500 4510.00
Low pressure limit 2.690E+33 -5.110 7095.00
Troe parameters: a=.5907, T $^{\ast\ast\ast}$=275.00, T$^\ast$=1226.00, T $^{\ast\ast}$=5185.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
CH2+HCCO $\rightleftharpoons$C2H3+CO 3.000E+13 .000 .00
CH2(S)+N2 $\rightleftharpoons$CH2+N2 1.500E+13 .000 600.00
CH2(S)+AR $\rightleftharpoons$CH2+AR 9.000E+12 .000 600.00
CH2(S)+O2 $\rightleftharpoons$H+OH+CO 2.800E+13 .000 .00
CH2(S)+O2 $\rightleftharpoons$CO+H2O 1.200E+13 .000 .00
CH2(S)+H2 $\rightleftharpoons$CH3+H 7.000E+13 .000 .00
CH2(S)+H2O(+M) $\rightleftharpoons$CH3OH(+M) 2.000E+13 .000 .00
Low pressure limit 2.700E+38 -6.300 3100.00
Troe parameters: a=.1507, T $^{\ast\ast\ast}$=134.00, T$^\ast$=2383.00, T $^{\ast\ast}$=7265.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
CH2(S)+H2O $\rightleftharpoons$CH2+H2O 3.000E+13 .000 .00
CH2(S)+CH3 $\rightleftharpoons$H+C2H4 1.200E+13 .000 -570.00
CH2(S)+CH4 $\rightleftharpoons$2CH3 1.600E+13 .000 -570.00
CH2(S)+CO $\rightleftharpoons$CH2+CO 9.000E+12 .000 .00
CH2(S)+CO2 $\rightleftharpoons$CH2+CO2 7.000E+12 .000 .00
CH2(S)+CO2 $\rightleftharpoons$CO+CH2O 1.400E+13 .000 .00
CH2(S)+C2H6 $\rightleftharpoons$CH3+C2H5 4.000E+13 .000 -550.00
CH3+O2 $\rightleftharpoons$O+CH3O 2.675E+13 .000 28800.00
CH3+O2 $\rightleftharpoons$OH+CH2O 3.600E+10 .000 8940.00
CH3+H2O2 $\rightleftharpoons$HO2+CH4 2.450E+04 2.470 5180.00
2CH3(+M) $\rightleftharpoons$C2H6(+M) 2.120E+16 -.970 620.00
Low pressure limit 1.770E+50 -9.670 6220.00
Troe parameters: a=.5325, T $^{\ast\ast\ast}$=151.00, T$^\ast$=1038.00, T $^{\ast\ast}$=4970.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
2CH3 $\rightleftharpoons$H+C2H5 4.990E+12 .100 10600.00
CH3+HCO $\rightleftharpoons$CH4+CO 2.648E+13 .000 .00
CH3+CH2O $\rightleftharpoons$HCO+CH4 3.320E+03 2.810 5860.00
CH3+CH3OH $\rightleftharpoons$CH2OH+CH4 3.000E+07 1.500 9940.00
CH3+CH3OH $\rightleftharpoons$CH3O+CH4 1.000E+07 1.500 9940.00
CH3+C2H4 $\rightleftharpoons$C2H3+CH4 2.270E+05 2.000 9200.00
CH3+C2H6 $\rightleftharpoons$C2H5+CH4 6.140E+06 1.740 10450.00
HCO+H2O $\rightleftharpoons$H+CO+H2O 2.244E+18 -1.000 17000.00
HCO+M $\rightleftharpoons$H+CO+M 1.870E+17 -1.000 17000.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00
HCO+O2 $\rightleftharpoons$HO2+CO 7.600E+12 .000 400.00
CH2OH+O2 $\rightleftharpoons$HO2+CH2O 1.800E+13 .000 900.00
CH3O+O2 $\rightleftharpoons$HO2+CH2O 4.280E-13 7.600 -3530.00
C2H+O2 $\rightleftharpoons$HCO+CO 5.000E+13 .000 1500.00
C2H+H2 $\rightleftharpoons$H+C2H2 4.070E+05 2.400 200.00
C2H3+O2 $\rightleftharpoons$HCO+CH2O 3.980E+12 .000 -240.00
C2H4(+M) $\rightleftharpoons$H2+C2H2(+M) 8.000E+12 .440 88770.00
Low pressure limit 7.000E+50 -9.310 99860.00
Troe parameters: a=.7345, T $^{\ast\ast\ast}$=180.00, T$^\ast$=1035.00, T $^{\ast\ast}$=5417.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
C2H5+O2 $\rightleftharpoons$HO2+C2H4 8.400E+11 .000 3875.00
HCCO+O2 $\rightleftharpoons$OH+2CO 1.600E+12 .000 854.00
2HCCO $\rightleftharpoons$2CO+C2H2 1.000E+13 .000 .00
N+NO $\rightleftharpoons$N2+O 3.500E+13 .000 330.00
N+O2 $\rightleftharpoons$NO+O 2.650E+12 .000 6400.00
N+OH $\rightleftharpoons$NO+H 7.333E+13 .000 1120.00
N2O+O $\rightleftharpoons$N2+O2 1.400E+12 .000 10810.00
N2O+O $\rightleftharpoons$2NO 2.900E+13 .000 23150.00
N2O+H $\rightleftharpoons$N2+OH 4.400E+14 .000 18880.00
N2O+OH $\rightleftharpoons$N2+HO2 2.000E+12 .000 21060.00
N2O(+M) $\rightleftharpoons$N2+O(+M) 1.300E+11 .000 59620.00
Low pressure limit 6.200E+14 .000 56100.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
HO2+NO $\rightleftharpoons$NO2+OH 2.110E+12 .000 -480.00
NO+O+M $\rightleftharpoons$NO2+M 1.060E+20 -1.410 .00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
NO2+O $\rightleftharpoons$NO+O2 3.900E+12 .000 -240.00
NO2+H $\rightleftharpoons$NO+OH 1.320E+14 .000 360.00
NH+O $\rightleftharpoons$NO+H 5.000E+13 .000 .00
NH+H $\rightleftharpoons$N+H2 3.200E+13 .000 330.00
NH+OH $\rightleftharpoons$HNO+H 2.000E+13 .000 .00
NH+OH $\rightleftharpoons$N+H2O 2.000E+09 1.200 .00
NH+O2 $\rightleftharpoons$HNO+O 4.610E+05 2.000 6500.00
NH+O2 $\rightleftharpoons$NO+OH 1.280E+06 1.500 100.00
NH+N $\rightleftharpoons$N2+H 1.500E+13 .000 .00
NH+H2O $\rightleftharpoons$HNO+H2 2.000E+13 .000 13850.00
NH+NO $\rightleftharpoons$N2+OH 2.160E+13 -.230 .00
NH+NO $\rightleftharpoons$N2O+H 4.160E+14 -.450 .00
NH2+O $\rightleftharpoons$OH+NH 7.000E+12 .000 .00
NH2+O $\rightleftharpoons$H+HNO 4.600E+13 .000 .00
NH2+H $\rightleftharpoons$NH+H2 4.000E+13 .000 3650.00
NH2+OH $\rightleftharpoons$NH+H2O 9.000E+07 1.500 -460.00
NNH $\rightleftharpoons$N2+H 3.300E+08 .000 .00
NNH+M $\rightleftharpoons$N2+H+M 1.300E+14 -.110 4980.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
NNH+O2 $\rightleftharpoons$HO2+N2 5.000E+12 .000 .00
NNH+O $\rightleftharpoons$OH+N2 2.500E+13 .000 .00
NNH+O $\rightleftharpoons$NH+NO 7.000E+13 .000 .00
NNH+H $\rightleftharpoons$H2+N2 5.000E+13 .000 .00
NNH+OH $\rightleftharpoons$H2O+N2 2.000E+13 .000 .00
NNH+CH3 $\rightleftharpoons$CH4+N2 2.500E+13 .000 .00
H+NO+M $\rightleftharpoons$HNO+M 8.950E+19 -1.320 740.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
HNO+O $\rightleftharpoons$NO+OH 2.500E+13 .000 .00
HNO+H $\rightleftharpoons$H2+NO 4.500E+11 .720 660.00
HNO+OH $\rightleftharpoons$NO+H2O 1.300E+07 1.900 -950.00
HNO+O2 $\rightleftharpoons$HO2+NO 1.000E+13 .000 13000.00
CN+O $\rightleftharpoons$CO+N 7.700E+13 .000 .00
CN+OH $\rightleftharpoons$NCO+H 4.000E+13 .000 .00
CN+H2O $\rightleftharpoons$HCN+OH 8.000E+12 .000 7460.00
CN+O2 $\rightleftharpoons$NCO+O 6.140E+12 .000 -440.00
CN+H2 $\rightleftharpoons$HCN+H 2.100E+13 .000 4710.00
NCO+O $\rightleftharpoons$NO+CO 2.350E+13 .000 .00
NCO+H $\rightleftharpoons$NH+CO 5.400E+13 .000 .00
NCO+OH $\rightleftharpoons$NO+H+CO 2.500E+12 .000 .00
NCO+N $\rightleftharpoons$N2+CO 2.000E+13 .000 .00
NCO+O2 $\rightleftharpoons$NO+CO2 2.000E+12 .000 20000.00
NCO+M $\rightleftharpoons$N+CO+M 8.800E+16 -.500 48000.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
NCO+NO $\rightleftharpoons$N2O+CO 2.850E+17 -1.520 740.00
NCO+NO $\rightleftharpoons$N2+CO2 5.700E+18 -2.000 800.00
HCN+M $\rightleftharpoons$H+CN+M 1.040E+29 -3.300 126600.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
HCN+O $\rightleftharpoons$NCO+H 1.107E+04 2.640 4980.00
HCN+O $\rightleftharpoons$NH+CO 2.767E+03 2.640 4980.00
HCN+O $\rightleftharpoons$CN+OH 2.134E+09 1.580 26600.00
HCN+OH $\rightleftharpoons$HOCN+H 1.100E+06 2.030 13370.00
HCN+OH $\rightleftharpoons$HNCO+H 4.400E+03 2.260 6400.00
HCN+OH $\rightleftharpoons$NH2+CO 1.600E+02 2.560 9000.00
H+HCN+M $\rightleftharpoons$H2CN+M 1.400E+26 -3.400 1900.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
H2CN+N $\rightleftharpoons$N2+CH2 6.000E+13 .000 400.00
C+N2 $\rightleftharpoons$CN+N 6.300E+13 .000 46020.00
CH+N2 $\rightleftharpoons$HCN+N 2.857E+08 1.100 20400.00
CH+N2(+M) $\rightleftharpoons$HCNN(+M) 3.100E+12 .150 .00
Low pressure limit 1.300E+25 -3.160 740.00
Troe parameters: a=.6670, T $^{\ast\ast\ast}$=235.00, T$^\ast$=2117.00, T $^{\ast\ast}$=4536.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
CH2+N2 $\rightleftharpoons$HCN+NH 1.000E+13 .000 74000.00
CH2(S)+N2 $\rightleftharpoons$NH+HCN 1.000E+11 .000 65000.00
C+NO $\rightleftharpoons$CN+O 1.900E+13 .000 .00
C+NO $\rightleftharpoons$CO+N 2.900E+13 .000 .00
CH+NO $\rightleftharpoons$HCN+O 5.000E+13 .000 .00
CH+NO $\rightleftharpoons$H+NCO 2.000E+13 .000 .00
CH+NO $\rightleftharpoons$N+HCO 3.000E+13 .000 .00
CH2+NO $\rightleftharpoons$H+HNCO 3.100E+17 -1.380 1270.00
CH2+NO $\rightleftharpoons$OH+HCN 2.900E+14 -.690 760.00
CH2+NO $\rightleftharpoons$H+HCNO 3.800E+13 -.360 580.00
CH2(S)+NO $\rightleftharpoons$H+HNCO 3.100E+17 -1.380 1270.00
CH2(S)+NO $\rightleftharpoons$OH+HCN 2.900E+14 -.690 760.00
CH2(S)+NO $\rightleftharpoons$H+HCNO 3.800E+13 -.360 580.00
CH3+NO $\rightleftharpoons$HCN+H2O 9.600E+13 .000 28800.00
CH3+NO $\rightleftharpoons$H2CN+OH 1.000E+12 .000 21750.00
HCNN+O $\rightleftharpoons$CO+H+N2 2.200E+13 .000 .00
HCNN+O $\rightleftharpoons$HCN+NO 2.000E+12 .000 .00
HCNN+O2 $\rightleftharpoons$O+HCO+N2 1.200E+13 .000 .00
HCNN+OH $\rightleftharpoons$H+HCO+N2 1.200E+13 .000 .00
HCNN+H $\rightleftharpoons$CH2+N2 1.000E+14 .000 .00
HNCO+O $\rightleftharpoons$NH+CO2 9.800E+07 1.410 8500.00
HNCO+O $\rightleftharpoons$HNO+CO 1.500E+08 1.570 44000.00
HNCO+O $\rightleftharpoons$NCO+OH 2.200E+06 2.110 11400.00
HNCO+H $\rightleftharpoons$NH2+CO 2.250E+07 1.700 3800.00
HNCO+H $\rightleftharpoons$H2+NCO 1.050E+05 2.500 13300.00
HNCO+OH $\rightleftharpoons$NCO+H2O 4.650E+12 .000 6850.00
HNCO+OH $\rightleftharpoons$NH2+CO2 1.550E+12 .000 6850.00
HNCO+M $\rightleftharpoons$NH+CO+M 1.180E+16 .000 84720.00
Enhanced Collision Efficiencies:
H2=2.00, H2O=6.00, CH4=2.00, CO=1.50, CO2=2.00, C2H6=3.00, AR=.70
HCNO+H $\rightleftharpoons$H+HNCO 2.100E+15 -.690 2850.00
HCNO+H $\rightleftharpoons$OH+HCN 2.700E+11 .180 2120.00
HCNO+H $\rightleftharpoons$NH2+CO 1.700E+14 -.750 2890.00
HOCN+H $\rightleftharpoons$H+HNCO 2.000E+07 2.000 2000.00
HCCO+NO $\rightleftharpoons$HCNO+CO 2.350E+13 .000 .00
CH3+N $\rightleftharpoons$H2CN+H 6.100E+14 -.310 290.00
CH3+N $\rightleftharpoons$HCN+H2 3.700E+12 .150 -90.00
NH3+H $\rightleftharpoons$NH2+H2 5.400E+05 2.400 9915.00
NH3+OH $\rightleftharpoons$NH2+H2O 5.000E+07 1.600 955.00
NH3+O $\rightleftharpoons$NH2+OH 9.400E+06 1.940 6460.00

next up previous contents
Next: Modified [Miller and Bowman Up: Reaction Mechanisms Previous: [Baulch et al. (1994a)]
Joe E. Shepherd
2000-01-17