[Baulch et al. (1994a)]

Next: [Frenklach et al. (1995)] Up: Reaction Mechanisms Previous: [Allen et al. (1995)]

[Baulch et al. (1994a)]

The fall-off relation used (typically) in [Baulch et al. (1994a)] for constant F_c is a special case of the SRI form with a = F_c, b = 0, and c = 0. The data, as published, although intended as such, were not in a convenient form for use in modeling. Many of the rates were stated as unidirectional for consumption of the reactants, sometimes with a list of possible products, but often without detailed branching information. Naturally, a complete mechanism requires detailed accounting of all species. Where a choice of products was given without proportioning data, the overall rate was divided equally among the products. Unidirectional rates were used wherever reverse rates were independently provided. Only reactions considered pertinent to the current work have been included. More hydrocarbon rates (for molecules larger than CH₄) are available from the original publication.

Reaction A (cm-molecules-sec-K) n E (K)

O+H2 $\rightleftharpoons$ OH+H 8.500E-20 2.67 3160

O+OH $\Rightarrow$ O2+H 2.400E-11 0.00 353

O+HO2 $\rightleftharpoons$ OH+O2 5.300E-11 0.00 0

O+H2O2 $\rightleftharpoons$ OH+HO2 1.100E-12 0.00 2000

O+NO $\Rightarrow$ O2+N 1.140E-15 1.13 19200

O+N2 $\Rightarrow$ N+NO 3.000E-10 0.00 38300

O+NH $\rightleftharpoons$ NO+H 0.750E-10 0.00 0

O+NH $\rightleftharpoons$ N+OH 0.750E-10 0.00 0

O+NH3 $\Rightarrow$ OH+NH2 1.600E-11 0.00 3670

O+CH $\rightleftharpoons$ CO+H 6.600E-11 0.00 0

O+CH2 $\rightleftharpoons$ CO+2H 1.200E-10 0.00 0

O+CH2 $\rightleftharpoons$ CO+H2 0.800E-10 0.00 0

O+CH3 $\rightleftharpoons$ CH2O+H 1.400E-10 0.00 0

O+CH4 $\rightleftharpoons$ OH+CH3 1.200E-15 1.56 4270

O+HCO $\rightleftharpoons$ OH+CO 5.000E-11 0.00 0

O+HCO $\rightleftharpoons$ CO2+H 5.000E-11 0.00 0

O+CH2O $\rightleftharpoons$ OH+HCO 6.900E-13 0.57 1390

O+CH3O $\Rightarrow$ O2+CH3 2.200E-11 0.00 0

O+CH3O $\rightleftharpoons$ OH+CH2O 0.300E-11 0.00 0

O+CN $\Rightarrow$ CO+N 1.700E-11 0.00 0

O+NCO $\rightleftharpoons$ NO+CO 3.500E-11 0.00 0

O+NCO $\Rightarrow$ O2+CN 3.500E-11 0.00 0

O+HCN $\Rightarrow$ NCO+H 0.767E-18 2.10 3075

O+HCN $\rightleftharpoons$ CO+NH 0.767E-18 2.10 3075

O+HCN $\Rightarrow$ OH+CN 0.767E-18 2.10 3075

O+C2H $\rightleftharpoons$ CO+CH 0.360E-11 0.00 0

O+C2H2 $\rightleftharpoons$ CO+CH2 0.840E-17 2.10 790

O+C2H2 $\rightleftharpoons$ HCCO+H 1.200E-17 2.10 790

O+HCCO $\rightleftharpoons$ 2CO+H 1.600E-10 0.00 0

O2+CH4 $\rightleftharpoons$ HO2+CH3 6.600E-11 0.00 28630

O2+CH2O $\rightleftharpoons$ HO2+HCO 1.000E-10 0.00 20460

H+O2 $\Rightarrow$ OH+O 1.620E-10 0.00 7470

H+O2+M $\rightleftharpoons$ HO2+M 1.700E-30 -0.80 0

Enhanced Collision Efficiencies:

H2=3.41, N2=2.29

H+H+M $\Rightarrow$ H2+M 1.800E-30 -1.00 0

Enhanced Collision Efficiencies:

H2=0.00

H+H+H2 $\Rightarrow$ H2+H2 2.700E-31 -0.60 0

H+OH+M $\Rightarrow$ H2O+M 2.300E-26 -2.00 0

Enhanced Collision Efficiencies:

H2O=16.96, N2=2.65

H+HO2 $\rightleftharpoons$ H2+O2 7.100E-11 0.00 710

H+HO2 $\rightleftharpoons$ 2OH 2.800E-10 0.00 440

H+HO2 $\rightleftharpoons$ H2O+O 5.000E-11 0.00 866

H+H2O $\Rightarrow$ OH+H2 7.500E-16 1.6 9270

H+H2O2 $\rightleftharpoons$ H2+HO2 2.800E-12 0.00 1890

H+H2O2 $\rightleftharpoons$ OH+H2O 1.700E-11 0.00 1800

H+NO $\Rightarrow$ OH+N 3.600E-10 0.00 24910

H+NH $\rightleftharpoons$ H2+N 1.700E-11 0.00 0

H+NH2 $\rightleftharpoons$ H2+NH 1.000E-11 0.00 0

H+CO+M $\Rightarrow$ HCO+M 5.300E-34 0.00 370

H+CH2 $\Rightarrow$ H2+CH 1.000E-11 0.00 -900

H+CH3 $\Rightarrow$ H2+CH2(S) 1.000E-10 0.00 7600

H+CH3(+M) $\Rightarrow$ CH4(+M) 3.500E-10 0.00 0

Low pressure limit 1.700E-24 -1.80 0.0

Troe parameters: a=0.37, T $^{\ast\ast\ast}$ =3315, T $^\ast$ =61

H+CH4 $\Rightarrow$ H2+CH3 2.200E-20 3.00 4045

H+HCO $\rightleftharpoons$ H2+CO 1.500E-10 0.00 0

H+CH2O $\rightleftharpoons$ H2+HCO 2.100E-16 1.62 1090

H+CH3O $\rightleftharpoons$ H2+CH2O 3.000E-11 0.00 0

H+HNCO $\rightleftharpoons$ H2+NCO 3.400E-10 -0.27 10190

H+NCO $\rightleftharpoons$ NH+CO 4.350E-11 0.00 0

H+NCO $\Rightarrow$ HCN+O 4.350E-11 0.00 0

H+C2H2 $\Rightarrow$ H2+C2H 1.100E-10 0.00 14000

H+HCCO $\rightleftharpoons$ CH2+CO 0.833E-10 0.00 0

H+HCCO $\rightleftharpoons$ H2+C2O 0.833E-10 0.00 0

H+CH2CO $\rightleftharpoons$ CH3+CO 3.000E-11 0.00 1700

H2+M $\Rightarrow$ 2H+M 3.700E-10 0.00 48350

Enhanced Collision Efficiencies:

H2=4.05

OH+H2 $\Rightarrow$ H2O+H 1.700E-16 1.60 1660

2OH $\rightleftharpoons$ H2O+O 2.500E-15 1.14 50

OH+OH(+M) $\Rightarrow$ H2O2(+M) 1.200E-10 -0.37 0

Low pressure limit 6.1E-29 -0.76 0.0

SRI parameters: a=0.5, b=0.0, c=0.0

Enhanced Collision Efficiencies:

H2O=0.0

OH+OH(+H2O) $\Rightarrow$ H2O2(+H2O) 1.200E-10 -0.37 0

Low pressure limit 4.0E-30 0.0 0.0

OH+HO2 $\rightleftharpoons$ H2O+O2 4.800E-11 0.00 -250

OH+H2O2 $\rightleftharpoons$ H2O+HO2 1.300E-11 0.00 670

OH+NH $\rightleftharpoons$ NO+H2 4.000E-11 0.00 0

OH+NH $\rightleftharpoons$ H2O+N 4.000E-11 0.00 0

OH+NH2 $\Rightarrow$ O+NH3 3.300E-14 0.405 250

OH+CO $\rightleftharpoons$ H+CO2 1.050E-17 1.50 -250

OH+CH3 $\rightleftharpoons$ H2O+CH2(S) 1.200E-11 0.00 1400

OH+CH3(+M) $\rightleftharpoons$ CH3OH(+M) 1.000E-10 0.00 0

Low pressure limit 4.40E-04 -8.2 0.0

Troe parameters: a=0.82, T $^{\ast\ast\ast}$ =200, T $^\ast$ =1438

OH+CH4 $\rightleftharpoons$ H2O+CH3 2.600E-17 1.83 1400

OH+HCO $\rightleftharpoons$ H2O+CO 1.700E-10 0.00 0

OH+CH2O $\rightleftharpoons$ H2O+HCO 5.700E-15 1.18 -225

OH+CN $\Rightarrow$ O+HCN 0.500E-10 0.00 0

OH+CN $\rightleftharpoons$ NCO+H 0.500E-10 0.00 0

OH+HCN $\Rightarrow$ H2O+CN 1.500E-11 0.00 5400

OH+C2H2 $\rightleftharpoons$ H2O+C2H 0.500E-10 0.00 6500

OH+C2H2 $\rightleftharpoons$ H+CH2CO 0.500E-10 0.00 6500

OH+CH2CO $\rightleftharpoons$ CH2OH+CO 0.850E-11 0.00 0

OH+CH2CO $\rightleftharpoons$ CH2O+HCO 0.850E-11 0.00 0

H2O+M $\Rightarrow$ H+OH+M 5.800E-09 0.00 52920

HO2+HO2 $\rightleftharpoons$ H2O2+O2 7.000E-10 0.00 6030

HO2+NH2 $\rightleftharpoons$ NH3+O2 1.300E-11 0.00 0

HO2+NH2 $\rightleftharpoons$ HNO+H2O 1.300E-11 0.00 0

HO2+CH3 $\rightleftharpoons$ OH+CH3O 3.000E-11 0.00 0

HO2+CH4 $\rightleftharpoons$ H2O2+CH3 1.500E-11 0.00 12440

HO2+CH2O $\rightleftharpoons$ H2O2+HCO 5.000E-12 0.00 6580

H2O2(+M) $\Rightarrow$ OH+OH(+M) 3.000E+14 0.00 24400

Low pressure limit 3.000E-08 0.00 21600

SRI parameters: a=0.5, b=0.0, c=0.0

Enhanced Collision Efficiencies:

N2=0.00

H2O2(+N2) $\Rightarrow$ OH+OH(+N2) 3.000E+14 0.00 24400

Low pressure limit 2.000E-07 0.00 22900

SRI parameters: a=0.5, b=0.0, c=0.0

N+O2 $\Rightarrow$ NO+O 1.500E-14 1.00 3270

N+OH $\Rightarrow$ NO+H 4.700E-11 0.00 0

N+NO $\Rightarrow$ N2+O 7.100E-11 0.00 790

N+CN $\Rightarrow$ N2+C 3.000E-10 0.00 0

N+NCO $\rightleftharpoons$ N2+CO 3.300E-11 0.00 0

NH+O2 $\rightleftharpoons$ NO+OH 0.650E-13 0.00 770

NH+O2 $\rightleftharpoons$ NO2+H 0.650E-13 0.00 770

NH+O2 $\rightleftharpoons$ HNO+O 6.500E-11 0.00 9000

NH+NO $\rightleftharpoons$ N2O+H 0.933E-10 0.00 6400

NH+NO $\rightleftharpoons$ NNH+O 0.933E-10 0.00 6400

NH+NO $\rightleftharpoons$ N2+OH 0.933E-10 0.00 6400

NH2+NO $\rightleftharpoons$ N2+H2O 0.792E-12 0.00 -650

NH2+NO $\rightleftharpoons$ N2+H+OH 0.108E-12 0.00 -650

NH2+NO $\rightleftharpoons$ NNH+OH 0.108E-12 0.00 -650

NH2+NO $\rightleftharpoons$ N2O+H2 0.792E-12 0.00 -650

NH3(+M) $\rightleftharpoons$ NH2+H(+M) 8.300E+15 0.00 55170

Low pressure limit 7.400E-9 0.0 41560

Troe parameters: a=0.42, T $^{\ast\ast\ast}$ =4581, T $^\ast$ =102

C+N2 $\Rightarrow$ CN+N 8.700E-11 0.00 22600

C+NO $\rightleftharpoons$ CN+O 3.200E-11 0.00 0

C+NO $\Rightarrow$ CO+N 4.800E-11 0.00 0

CH+O2 $\rightleftharpoons$ HCO+O 2.750E-11 0.00 0

CH+O2 $\rightleftharpoons$ CO+OH 2.750E-11 0.00 0

CH+H2 $\Rightarrow$ CH2+H 2.400E-10 0.00 1760

CH+N2 $\rightleftharpoons$ HCN+N 2.600E-12 0.00 9030

CH+NO $\rightleftharpoons$ CO+NH 0.667E-10 0.00 0

CH+NO $\rightleftharpoons$ CN+OH 0.667E-10 0.00 0

CH+NO $\rightleftharpoons$ HCN+O 0.667E-10 0.00 0

CH2+O2 $\rightleftharpoons$ CO+H+OH 0.820E-11 0.00 750

CH2+O2 $\rightleftharpoons$ CO2+H+H 0.820E-11 0.00 750

CH2+O2 $\rightleftharpoons$ CO+H2O 0.820E-11 0.00 750

CH2+O2 $\rightleftharpoons$ CO2+H2 0.820E-11 0.00 750

CH2+O2 $\rightleftharpoons$ CH2O+O 0.820E-11 0.00 750

CH2+CH2 $\rightleftharpoons$ C2H2+H2 0.200E-10 0.00 400

CH2+CH2 $\rightleftharpoons$ C2H2+2H 1.800E-10 0.00 400

CH2(S)+AR $\rightleftharpoons$ CH2+AR 6.000E-12 0.00 0

CH2(S)+N2 $\rightleftharpoons$ CH2+N2 1.000E-11 0.00 0

CH2(S)+CH4 $\rightleftharpoons$ CH2+CH4 1.200E-11 0.00 0

CH2(S)+C2H2 $\rightleftharpoons$ CH2+C2H2 8.000E-11 0.00 0

CH2(S)+O2 $\rightleftharpoons$ CO+H+OH 1.300E-11 0.00 0

CH2(S)+O2 $\rightleftharpoons$ CO2+H2 1.300E-11 0.00 0

CH2(S)+O2 $\rightleftharpoons$ CO+H2O 1.300E-11 0.00 0

CH2(S)+O2 $\rightleftharpoons$ CH2+O2 1.300E-11 0.00 0

CH2(S)+H2 $\Rightarrow$ CH3+H 1.200E-10 0.00 0

CH3+M $\rightleftharpoons$ CH2+H+M 1.700E-08 0.00 45600

CH3+O2 $\Rightarrow$ CH3O+O 2.200E-10 0.00 15800

CH3+O2 $\rightleftharpoons$ CH2O+OH 5.500E-13 0.00 4500

CH3+H2 $\Rightarrow$ CH4+H 1.140E-20 2.74 4740

CH3+CH2O $\rightleftharpoons$ CH4+HCO 1.300E-31 6.10 990

CH4(+M) $\Rightarrow$ CH3+H(+M) 2.400E+16 0.00 52800

Low pressure limit 7.8E+23 -8.2 59200

Troe parameters: a=1.0, T $^{\ast\ast\ast}$ =0.0, T $^\ast$ =1350, T $^{\ast\ast}$ =7830

Enhanced Collision Efficiencies:

CH4=0.0

CH4(+CH4) $\Rightarrow$ CH3+H(+CH4) 2.400E+16 0.00 52800

Low pressure limit 1.4E-06 0.0 45700

Troe parameters: a=0.69, T $^{\ast\ast\ast}$ =90, T $^\ast$ =2210

HCO+M $\Rightarrow$ H+CO+M 2.600E-10 0.00 7930

HCO+O2 $\rightleftharpoons$ CO+HO2 2.500E-12 0.00 0

HCO+O2 $\rightleftharpoons$ OH+CO2 2.500E-12 0.00 0

HCO+HCO $\rightleftharpoons$ CH2O+CO 5.000E-11 0.00 0

CH2O+M $\rightleftharpoons$ H+HCO+M 0.810E+12 -5.54 48660

CH2O+M $\rightleftharpoons$ H2+CO+M 1.890E+12 -5.54 48660

CH2OH+O2 $\rightleftharpoons$ CH2O+HO2 2.600E-09 -1.00 0

Duplicate Reaction

CH2OH+O2 $\rightleftharpoons$ CH2O+HO2 1.200E-10 0.00 1800

Duplicate Reaction

CH3O+M $\rightleftharpoons$ CH2O+H+M 9.000E-11 0.00 6790

CH3O+O2 $\rightleftharpoons$ CH2O+HO2 3.600E-14 0.00 880

CN+O2 $\Rightarrow$ NCO+O 1.200E-11 0.00 -210

CN+H2 $\rightleftharpoons$ HCN+H 3.200E-20 2.87 820

CN+H2O $\Rightarrow$ HCN+OH 0.650E-11 0.00 3750

CN+H2O $\rightleftharpoons$ HOCN+H 0.650E-11 0.00 3750

CN+CH4 $\rightleftharpoons$ HCN+CH3 1.500E-19 2.64 -150

NCO+M $\rightleftharpoons$ N+CO+M 1.700E-09 0.00 23500

NCO+NO $\rightleftharpoons$ N2O+CO 0.767E-06 -1.73 380

NCO+NO $\rightleftharpoons$ N2+CO2 0.767E-06 -1.73 380

NCO+NO $\rightleftharpoons$ N2+CO+O 0.767E-06 -1.73 380

C2H+O2 $\rightleftharpoons$ CO2+CH 0.750E-11 0.00 0

C2H+O2 $\rightleftharpoons$ 2CO+H 0.750E-11 0.00 0

C2H+O2 $\rightleftharpoons$ CO+HCO 0.750E-11 0.00 0

C2H+H2 $\Rightarrow$ C2H2+H 1.800E-11 0.00 1090

HCCO+O2 $\rightleftharpoons$ CO2+HCO 0.675E-12 0.00 430

HCCO+O2 $\rightleftharpoons$ 2CO+OH 0.675E-12 0.00 430

HCCO+O2 $\rightleftharpoons$ C2O+HO2 0.675E-12 0.00 430

Next: [Frenklach et al. (1995)] Up: Reaction Mechanisms Previous: [Allen et al. (1995)]

Joe E. Shepherd
2000-01-17

Reaction	A (cm-molecules-sec-K)	n	E (K)

O+H2 $\rightleftharpoons$ OH+H	8.500E-20	2.67	3160
O+OH $\Rightarrow$ O2+H	2.400E-11	0.00	353
O+HO2 $\rightleftharpoons$ OH+O2	5.300E-11	0.00	0
O+H2O2 $\rightleftharpoons$ OH+HO2	1.100E-12	0.00	2000
O+NO $\Rightarrow$ O2+N	1.140E-15	1.13	19200
O+N2 $\Rightarrow$ N+NO	3.000E-10	0.00	38300
O+NH $\rightleftharpoons$ NO+H	0.750E-10	0.00	0
O+NH $\rightleftharpoons$ N+OH	0.750E-10	0.00	0
O+NH3 $\Rightarrow$ OH+NH2	1.600E-11	0.00	3670
O+CH $\rightleftharpoons$ CO+H	6.600E-11	0.00	0
O+CH2 $\rightleftharpoons$ CO+2H	1.200E-10	0.00	0
O+CH2 $\rightleftharpoons$ CO+H2	0.800E-10	0.00	0
O+CH3 $\rightleftharpoons$ CH2O+H	1.400E-10	0.00	0
O+CH4 $\rightleftharpoons$ OH+CH3	1.200E-15	1.56	4270
O+HCO $\rightleftharpoons$ OH+CO	5.000E-11	0.00	0
O+HCO $\rightleftharpoons$ CO2+H	5.000E-11	0.00	0
O+CH2O $\rightleftharpoons$ OH+HCO	6.900E-13	0.57	1390
O+CH3O $\Rightarrow$ O2+CH3	2.200E-11	0.00	0
O+CH3O $\rightleftharpoons$ OH+CH2O	0.300E-11	0.00	0
O+CN $\Rightarrow$ CO+N	1.700E-11	0.00	0
O+NCO $\rightleftharpoons$ NO+CO	3.500E-11	0.00	0
O+NCO $\Rightarrow$ O2+CN	3.500E-11	0.00	0
O+HCN $\Rightarrow$ NCO+H	0.767E-18	2.10	3075
O+HCN $\rightleftharpoons$ CO+NH	0.767E-18	2.10	3075
O+HCN $\Rightarrow$ OH+CN	0.767E-18	2.10	3075
O+C2H $\rightleftharpoons$ CO+CH	0.360E-11	0.00	0
O+C2H2 $\rightleftharpoons$ CO+CH2	0.840E-17	2.10	790
O+C2H2 $\rightleftharpoons$ HCCO+H	1.200E-17	2.10	790
O+HCCO $\rightleftharpoons$ 2CO+H	1.600E-10	0.00	0
O2+CH4 $\rightleftharpoons$ HO2+CH3	6.600E-11	0.00	28630
O2+CH2O $\rightleftharpoons$ HO2+HCO	1.000E-10	0.00	20460
H+O2 $\Rightarrow$ OH+O	1.620E-10	0.00	7470
H+O2+M $\rightleftharpoons$ HO2+M	1.700E-30	-0.80	0
Enhanced Collision Efficiencies:
H2=3.41, N2=2.29
H+H+M $\Rightarrow$ H2+M	1.800E-30	-1.00	0
Enhanced Collision Efficiencies:
H2=0.00
H+H+H2 $\Rightarrow$ H2+H2	2.700E-31	-0.60	0
H+OH+M $\Rightarrow$ H2O+M	2.300E-26	-2.00	0
Enhanced Collision Efficiencies:
H2O=16.96, N2=2.65
H+HO2 $\rightleftharpoons$ H2+O2	7.100E-11	0.00	710
H+HO2 $\rightleftharpoons$ 2OH	2.800E-10	0.00	440
H+HO2 $\rightleftharpoons$ H2O+O	5.000E-11	0.00	866
H+H2O $\Rightarrow$ OH+H2	7.500E-16	1.6	9270
H+H2O2 $\rightleftharpoons$ H2+HO2	2.800E-12	0.00	1890
H+H2O2 $\rightleftharpoons$ OH+H2O	1.700E-11	0.00	1800
H+NO $\Rightarrow$ OH+N	3.600E-10	0.00	24910
H+NH $\rightleftharpoons$ H2+N	1.700E-11	0.00	0
H+NH2 $\rightleftharpoons$ H2+NH	1.000E-11	0.00	0
H+CO+M $\Rightarrow$ HCO+M	5.300E-34	0.00	370
H+CH2 $\Rightarrow$ H2+CH	1.000E-11	0.00	-900
H+CH3 $\Rightarrow$ H2+CH2(S)	1.000E-10	0.00	7600
H+CH3(+M) $\Rightarrow$ CH4(+M)	3.500E-10	0.00	0
Low pressure limit	1.700E-24	-1.80	0.0
Troe parameters: a=0.37, T $^{\ast\ast\ast}$ =3315, T $^\ast$ =61
H+CH4 $\Rightarrow$ H2+CH3	2.200E-20	3.00	4045
H+HCO $\rightleftharpoons$ H2+CO	1.500E-10	0.00	0
H+CH2O $\rightleftharpoons$ H2+HCO	2.100E-16	1.62	1090
H+CH3O $\rightleftharpoons$ H2+CH2O	3.000E-11	0.00	0
H+HNCO $\rightleftharpoons$ H2+NCO	3.400E-10	-0.27	10190
H+NCO $\rightleftharpoons$ NH+CO	4.350E-11	0.00	0
H+NCO $\Rightarrow$ HCN+O	4.350E-11	0.00	0
H+C2H2 $\Rightarrow$ H2+C2H	1.100E-10	0.00	14000
H+HCCO $\rightleftharpoons$ CH2+CO	0.833E-10	0.00	0
H+HCCO $\rightleftharpoons$ H2+C2O	0.833E-10	0.00	0
H+CH2CO $\rightleftharpoons$ CH3+CO	3.000E-11	0.00	1700
H2+M $\Rightarrow$ 2H+M	3.700E-10	0.00	48350
Enhanced Collision Efficiencies:
H2=4.05
OH+H2 $\Rightarrow$ H2O+H	1.700E-16	1.60	1660
2OH $\rightleftharpoons$ H2O+O	2.500E-15	1.14	50
OH+OH(+M) $\Rightarrow$ H2O2(+M)	1.200E-10	-0.37	0
Low pressure limit	6.1E-29	-0.76	0.0
SRI parameters: a=0.5, b=0.0, c=0.0
Enhanced Collision Efficiencies:
H2O=0.0
OH+OH(+H2O) $\Rightarrow$ H2O2(+H2O)	1.200E-10	-0.37	0
Low pressure limit	4.0E-30	0.0	0.0
OH+HO2 $\rightleftharpoons$ H2O+O2	4.800E-11	0.00	-250
OH+H2O2 $\rightleftharpoons$ H2O+HO2	1.300E-11	0.00	670
OH+NH $\rightleftharpoons$ NO+H2	4.000E-11	0.00	0
OH+NH $\rightleftharpoons$ H2O+N	4.000E-11	0.00	0
OH+NH2 $\Rightarrow$ O+NH3	3.300E-14	0.405	250
OH+CO $\rightleftharpoons$ H+CO2	1.050E-17	1.50	-250
OH+CH3 $\rightleftharpoons$ H2O+CH2(S)	1.200E-11	0.00	1400
OH+CH3(+M) $\rightleftharpoons$ CH3OH(+M)	1.000E-10	0.00	0
Low pressure limit	4.40E-04	-8.2	0.0
Troe parameters: a=0.82, T $^{\ast\ast\ast}$ =200, T $^\ast$ =1438
OH+CH4 $\rightleftharpoons$ H2O+CH3	2.600E-17	1.83	1400
OH+HCO $\rightleftharpoons$ H2O+CO	1.700E-10	0.00	0
OH+CH2O $\rightleftharpoons$ H2O+HCO	5.700E-15	1.18	-225
OH+CN $\Rightarrow$ O+HCN	0.500E-10	0.00	0
OH+CN $\rightleftharpoons$ NCO+H	0.500E-10	0.00	0
OH+HCN $\Rightarrow$ H2O+CN	1.500E-11	0.00	5400
OH+C2H2 $\rightleftharpoons$ H2O+C2H	0.500E-10	0.00	6500
OH+C2H2 $\rightleftharpoons$ H+CH2CO	0.500E-10	0.00	6500
OH+CH2CO $\rightleftharpoons$ CH2OH+CO	0.850E-11	0.00	0
OH+CH2CO $\rightleftharpoons$ CH2O+HCO	0.850E-11	0.00	0
H2O+M $\Rightarrow$ H+OH+M	5.800E-09	0.00	52920
HO2+HO2 $\rightleftharpoons$ H2O2+O2	7.000E-10	0.00	6030
HO2+NH2 $\rightleftharpoons$ NH3+O2	1.300E-11	0.00	0
HO2+NH2 $\rightleftharpoons$ HNO+H2O	1.300E-11	0.00	0
HO2+CH3 $\rightleftharpoons$ OH+CH3O	3.000E-11	0.00	0
HO2+CH4 $\rightleftharpoons$ H2O2+CH3	1.500E-11	0.00	12440
HO2+CH2O $\rightleftharpoons$ H2O2+HCO	5.000E-12	0.00	6580
H2O2(+M) $\Rightarrow$ OH+OH(+M)	3.000E+14	0.00	24400
Low pressure limit	3.000E-08	0.00	21600
SRI parameters: a=0.5, b=0.0, c=0.0
Enhanced Collision Efficiencies:
N2=0.00
H2O2(+N2) $\Rightarrow$ OH+OH(+N2)	3.000E+14	0.00	24400
Low pressure limit	2.000E-07	0.00	22900
SRI parameters: a=0.5, b=0.0, c=0.0
N+O2 $\Rightarrow$ NO+O	1.500E-14	1.00	3270
N+OH $\Rightarrow$ NO+H	4.700E-11	0.00	0
N+NO $\Rightarrow$ N2+O	7.100E-11	0.00	790
N+CN $\Rightarrow$ N2+C	3.000E-10	0.00	0
N+NCO $\rightleftharpoons$ N2+CO	3.300E-11	0.00	0
NH+O2 $\rightleftharpoons$ NO+OH	0.650E-13	0.00	770
NH+O2 $\rightleftharpoons$ NO2+H	0.650E-13	0.00	770
NH+O2 $\rightleftharpoons$ HNO+O	6.500E-11	0.00	9000
NH+NO $\rightleftharpoons$ N2O+H	0.933E-10	0.00	6400
NH+NO $\rightleftharpoons$ NNH+O	0.933E-10	0.00	6400
NH+NO $\rightleftharpoons$ N2+OH	0.933E-10	0.00	6400
NH2+NO $\rightleftharpoons$ N2+H2O	0.792E-12	0.00	-650
NH2+NO $\rightleftharpoons$ N2+H+OH	0.108E-12	0.00	-650
NH2+NO $\rightleftharpoons$ NNH+OH	0.108E-12	0.00	-650
NH2+NO $\rightleftharpoons$ N2O+H2	0.792E-12	0.00	-650
NH3(+M) $\rightleftharpoons$ NH2+H(+M)	8.300E+15	0.00	55170
Low pressure limit	7.400E-9	0.0	41560
Troe parameters: a=0.42, T $^{\ast\ast\ast}$ =4581, T $^\ast$ =102
C+N2 $\Rightarrow$ CN+N	8.700E-11	0.00	22600
C+NO $\rightleftharpoons$ CN+O	3.200E-11	0.00	0
C+NO $\Rightarrow$ CO+N	4.800E-11	0.00	0
CH+O2 $\rightleftharpoons$ HCO+O	2.750E-11	0.00	0
CH+O2 $\rightleftharpoons$ CO+OH	2.750E-11	0.00	0
CH+H2 $\Rightarrow$ CH2+H	2.400E-10	0.00	1760
CH+N2 $\rightleftharpoons$ HCN+N	2.600E-12	0.00	9030
CH+NO $\rightleftharpoons$ CO+NH	0.667E-10	0.00	0
CH+NO $\rightleftharpoons$ CN+OH	0.667E-10	0.00	0
CH+NO $\rightleftharpoons$ HCN+O	0.667E-10	0.00	0
CH2+O2 $\rightleftharpoons$ CO+H+OH	0.820E-11	0.00	750
CH2+O2 $\rightleftharpoons$ CO2+H+H	0.820E-11	0.00	750
CH2+O2 $\rightleftharpoons$ CO+H2O	0.820E-11	0.00	750
CH2+O2 $\rightleftharpoons$ CO2+H2	0.820E-11	0.00	750
CH2+O2 $\rightleftharpoons$ CH2O+O	0.820E-11	0.00	750
CH2+CH2 $\rightleftharpoons$ C2H2+H2	0.200E-10	0.00	400
CH2+CH2 $\rightleftharpoons$ C2H2+2H	1.800E-10	0.00	400
CH2(S)+AR $\rightleftharpoons$ CH2+AR	6.000E-12	0.00	0
CH2(S)+N2 $\rightleftharpoons$ CH2+N2	1.000E-11	0.00	0
CH2(S)+CH4 $\rightleftharpoons$ CH2+CH4	1.200E-11	0.00	0
CH2(S)+C2H2 $\rightleftharpoons$ CH2+C2H2	8.000E-11	0.00	0
CH2(S)+O2 $\rightleftharpoons$ CO+H+OH	1.300E-11	0.00	0
CH2(S)+O2 $\rightleftharpoons$ CO2+H2	1.300E-11	0.00	0
CH2(S)+O2 $\rightleftharpoons$ CO+H2O	1.300E-11	0.00	0
CH2(S)+O2 $\rightleftharpoons$ CH2+O2	1.300E-11	0.00	0
CH2(S)+H2 $\Rightarrow$ CH3+H	1.200E-10	0.00	0
CH3+M $\rightleftharpoons$ CH2+H+M	1.700E-08	0.00	45600
CH3+O2 $\Rightarrow$ CH3O+O	2.200E-10	0.00	15800
CH3+O2 $\rightleftharpoons$ CH2O+OH	5.500E-13	0.00	4500
CH3+H2 $\Rightarrow$ CH4+H	1.140E-20	2.74	4740
CH3+CH2O $\rightleftharpoons$ CH4+HCO	1.300E-31	6.10	990
CH4(+M) $\Rightarrow$ CH3+H(+M)	2.400E+16	0.00	52800
Low pressure limit	7.8E+23	-8.2	59200
Troe parameters: a=1.0, T $^{\ast\ast\ast}$ =0.0, T $^\ast$ =1350, T $^{\ast\ast}$ =7830
Enhanced Collision Efficiencies:
CH4=0.0
CH4(+CH4) $\Rightarrow$ CH3+H(+CH4)	2.400E+16	0.00	52800
Low pressure limit	1.4E-06	0.0	45700
Troe parameters: a=0.69, T $^{\ast\ast\ast}$ =90, T $^\ast$ =2210
HCO+M $\Rightarrow$ H+CO+M	2.600E-10	0.00	7930
HCO+O2 $\rightleftharpoons$ CO+HO2	2.500E-12	0.00	0
HCO+O2 $\rightleftharpoons$ OH+CO2	2.500E-12	0.00	0
HCO+HCO $\rightleftharpoons$ CH2O+CO	5.000E-11	0.00	0
CH2O+M $\rightleftharpoons$ H+HCO+M	0.810E+12	-5.54	48660
CH2O+M $\rightleftharpoons$ H2+CO+M	1.890E+12	-5.54	48660
CH2OH+O2 $\rightleftharpoons$ CH2O+HO2	2.600E-09	-1.00	0
Duplicate Reaction
CH2OH+O2 $\rightleftharpoons$ CH2O+HO2	1.200E-10	0.00	1800
Duplicate Reaction
CH3O+M $\rightleftharpoons$ CH2O+H+M	9.000E-11	0.00	6790
CH3O+O2 $\rightleftharpoons$ CH2O+HO2	3.600E-14	0.00	880
CN+O2 $\Rightarrow$ NCO+O	1.200E-11	0.00	-210
CN+H2 $\rightleftharpoons$ HCN+H	3.200E-20	2.87	820
CN+H2O $\Rightarrow$ HCN+OH	0.650E-11	0.00	3750
CN+H2O $\rightleftharpoons$ HOCN+H	0.650E-11	0.00	3750
CN+CH4 $\rightleftharpoons$ HCN+CH3	1.500E-19	2.64	-150
NCO+M $\rightleftharpoons$ N+CO+M	1.700E-09	0.00	23500
NCO+NO $\rightleftharpoons$ N2O+CO	0.767E-06	-1.73	380
NCO+NO $\rightleftharpoons$ N2+CO2	0.767E-06	-1.73	380
NCO+NO $\rightleftharpoons$ N2+CO+O	0.767E-06	-1.73	380
C2H+O2 $\rightleftharpoons$ CO2+CH	0.750E-11	0.00	0
C2H+O2 $\rightleftharpoons$ 2CO+H	0.750E-11	0.00	0
C2H+O2 $\rightleftharpoons$ CO+HCO	0.750E-11	0.00	0
C2H+H2 $\Rightarrow$ C2H2+H	1.800E-11	0.00	1090
HCCO+O2 $\rightleftharpoons$ CO2+HCO	0.675E-12	0.00	430
HCCO+O2 $\rightleftharpoons$ 2CO+OH	0.675E-12	0.00	430
HCCO+O2 $\rightleftharpoons$ C2O+HO2	0.675E-12	0.00	430