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Next: [Miller et al. (1983)] Up: Reaction Mechanisms Previous: [Frenklach et al. (1995)]

Modified [Miller and Bowman (1989)]

This mechanism is a modified version of the listing published by [Miller and Bowman (1989)]. The separate mechanisms listed in Appendix A and Appendix B of that paper have been combined to handle hydrocarbon and ammonia combustion simultaneously. The original version was found to be deficient for ammonia combustion under highly dilute conditions where thermal dissocation of NH3 is important. To rectify this difficulty, the mechanism of [Fujii et al. (1981)] was blended into the [Miller and Bowman (1989)] mechanism. The [Fujii et al. (1981)] mechanism was tested against shock tube experiments.

Reaction A (cm-moles-sec-K) n E (cal/mole)
       
2CH3(+M) $\rightleftharpoons$C2H6(+M) 9.030E+16 -1.20 654
Low pressure limit 3.180E+41 -7.0 2762
Troe parameters: a=6.04E-1, T $^{\ast\ast\ast}$=6927.0, T$^\ast$=0.0, T $^{\ast\ast}$=132.0
Enhanced Collision Efficiencies:
H2=2.0, CO=2.0, CO2=3.0, H2O=5.0
CH3+H(+M) $\rightleftharpoons$CH4(+M) 6.000E+16 -1.00 0
Low pressure limit 8.000E+26 -3.0 0
SRI parameters: a=4.50E-1, b=797.0, c=979.0, d=1.0, e=0.0
Enhanced Collision Efficiencies:
H2=2.0, CO=2.0, CO2=3.0, H2O=5.0
CH4+O2 $\rightleftharpoons$CH3+HO2 7.900E+13 0.00 56000
CH4+H $\rightleftharpoons$CH3+H2 2.200E+04 3.00 8750
CH4+OH $\rightleftharpoons$CH3+H2O 1.600E+06 2.10 2460
CH4+O $\rightleftharpoons$CH3+OH 1.020E+09 1.50 8604
CH4+HO2 $\rightleftharpoons$CH3+H2O2 1.800E+11 0.00 18700
CH3+HO2 $\rightleftharpoons$CH3O+OH 2.000E+13 0.00 0
CH3+O2 $\rightleftharpoons$CH3O+O 2.050E+19 -1.57 29229
CH3+O $\rightleftharpoons$CH2O+H 8.000E+13 0.00 0
CH2OH+H $\rightleftharpoons$CH3+OH 1.000E+14 0.00 0
CH3O+H $\rightleftharpoons$CH3+OH 1.000E+14 0.00 0
CH3+OH $\rightleftharpoons$CH2+H2O 7.500E+06 2.00 5000
CH3+H $\rightleftharpoons$CH2+H2 9.000E+13 0.00 15100
CH3O+M $\rightleftharpoons$CH2O+H+M 1.000E+14 0.00 25000
CH2OH+M $\rightleftharpoons$CH2O+H+M 1.000E+14 0.00 25000
CH3O+H $\rightleftharpoons$CH2O+H2 2.000E+13 0.00 0
CH2OH+H $\rightleftharpoons$CH2O+H2 2.000E+13 0.00 0
CH3O+OH $\rightleftharpoons$CH2O+H2O 1.000E+13 0.00 0
CH2OH+OH $\rightleftharpoons$CH2O+H2O 1.000E+13 0.00 0
CH3O+O $\rightleftharpoons$CH2O+OH 1.000E+13 0.00 0
CH2OH+O $\rightleftharpoons$CH2O+OH 1.000E+13 0.00 0
CH3O+O2 $\rightleftharpoons$CH2O+HO2 6.300E+10 0.00 2600
CH2OH+O2 $\rightleftharpoons$CH2O+HO2 1.480E+13 0.00 1500
CH2+H $\rightleftharpoons$CH+H2 1.000E+18 -1.56 0
CH2+OH $\rightleftharpoons$CH+H2O 1.130E+07 2.00 3000
CH2+OH $\rightleftharpoons$CH2O+H 2.500E+13 0.00 0
CH+O2 $\rightleftharpoons$HCO+O 3.300E+13 0.00 0
CH+O $\rightleftharpoons$CO+H 5.700E+13 0.00 0
CH+OH $\rightleftharpoons$HCO+H 3.000E+13 0.00 0
CH+CO2 $\rightleftharpoons$HCO+CO 3.400E+12 0.00 690
CH+H $\rightleftharpoons$C+H2 1.500E+14 0.00 0
CH+H2O $\rightleftharpoons$CH2O+H 1.170E+15 -0.75 0
CH+CH2O $\rightleftharpoons$CH2CO+H 9.460E+13 0.00 -515
CH+C2H2 $\rightleftharpoons$C3H2+H 1.000E+14 0.00 0
CH+CH2 $\rightleftharpoons$C2H2+H 4.000E+13 0.00 0
CH+CH3 $\rightleftharpoons$C2H3+H 3.000E+13 0.00 0
CH+CH4 $\rightleftharpoons$C2H4+H 6.000E+13 0.00 0
C+O2 $\rightleftharpoons$CO+O 2.000E+13 0.00 0
C+OH $\rightleftharpoons$CO+H 5.000E+13 0.00 0
C+CH3 $\rightleftharpoons$C2H2+H 5.000E+13 0.00 0
C+CH2 $\rightleftharpoons$C2H+H 5.000E+13 0.00 0
CH2+CO2 $\rightleftharpoons$CH2O+CO 1.100E+11 0.00 1000
CH2+O $\rightleftharpoons$CO+2H 5.000E+13 0.00 0
CH2+O $\rightleftharpoons$CO+H2 3.000E+13 0.00 0
CH2+O2 $\rightleftharpoons$CO2+2H 1.600E+12 0.00 1000
CH2+O2 $\rightleftharpoons$CH2O+O 5.000E+13 0.00 9000
CH2+O2 $\rightleftharpoons$CO2+H2 6.900E+11 0.00 500
CH2+O2 $\rightleftharpoons$CO+H2O 1.900E+10 0.00 -1000
CH2+O2 $\rightleftharpoons$CO+OH+H 8.600E+10 0.00 -500
CH2+O2 $\rightleftharpoons$HCO+OH 4.300E+10 0.00 -500
CH2O+OH $\rightleftharpoons$HCO+H2O 3.430E+09 1.18 -447
CH2O+H $\rightleftharpoons$HCO+H2 2.190E+08 1.77 3000
CH2O+M $\rightleftharpoons$HCO+H+M 3.310E+16 0.00 81000
CH2O+O $\rightleftharpoons$HCO+OH 1.800E+13 0.00 3080
HCO+OH $\rightleftharpoons$H2O+CO 1.000E+14 0.00 0
HCO+M $\rightleftharpoons$H+CO+M 2.500E+14 0.00 16802
Enhanced Collision Efficiencies:
CO=1.9, H2=1.9, CH4=2.8, CO2=3.0, H2O=5.0
HCO+H $\rightleftharpoons$CO+H2 1.190E+13 0.25 0
HCO+O $\rightleftharpoons$CO+OH 3.000E+13 0.00 0
HCO+O $\rightleftharpoons$CO2+H 3.000E+13 0.00 0
HCO+O2 $\rightleftharpoons$HO2+CO 3.300E+13 -0.40 0
CO+O+M $\rightleftharpoons$CO2+M 6.170E+14 0.00 3000
CO+OH $\rightleftharpoons$CO2+H 1.510E+07 1.30 -758
CO+O2 $\rightleftharpoons$CO2+O 1.600E+13 0.00 41000
HO2+CO $\rightleftharpoons$CO2+OH 5.800E+13 0.00 22934
C2H6+CH3 $\rightleftharpoons$C2H5+CH4 5.500E-01 4.00 8300
C2H6+H $\rightleftharpoons$C2H5+H2 5.400E+02 3.50 5210
C2H6+O $\rightleftharpoons$C2H5+OH 3.000E+07 2.00 5115
C2H6+OH $\rightleftharpoons$C2H5+H2O 8.700E+09 1.05 1810
C2H4+H $\rightleftharpoons$C2H3+H2 1.100E+14 0.00 8500
C2H4+O $\rightleftharpoons$CH3+HCO 1.600E+09 1.20 746
C2H4+OH $\rightleftharpoons$C2H3+H2O 2.020E+13 0.00 5955
CH2+CH3 $\rightleftharpoons$C2H4+H 3.000E+13 0.00 0
H+C2H4(+M) $\rightleftharpoons$C2H5(+M) 2.210E+13 0.00 2066
Low pressure limit 6.37E+27 -2.8 -54
Enhanced Collision Efficiencies:
H2=2.0, CO=2.0, CO2=3.0, H2O=5.0
C2H5+H $\rightleftharpoons$2CH3 1.000E+14 0.00 0
C2H5+O2 $\rightleftharpoons$C2H4+HO2 8.430E+11 0.00 3875
C2H2+O $\rightleftharpoons$CH2+CO 1.020E+07 2.00 1900
C2H2+O $\rightleftharpoons$HCCO+H 1.020E+07 2.00 1900
H2+C2H $\rightleftharpoons$C2H2+H 4.090E+05 2.39 864
H+C2H2(+M) $\rightleftharpoons$C2H3(+M) 5.540E+12 0.00 2410
Low pressure limit 2.67E+27 -3.5 2410
Enhanced Collision Efficiencies:
H2=2.0, CO=2.0, CO2=3.0, H2O=5.0
C2H3+H $\rightleftharpoons$C2H2+H2 4.000E+13 0.00 0
C2H3+O $\rightleftharpoons$CH2CO+H 3.000E+13 0.00 0
C2H3+O2 $\rightleftharpoons$CH2O+HCO 4.000E+12 0.00 -250
C2H3+OH $\rightleftharpoons$C2H2+H2O 5.000E+12 0.00 0
C2H3+CH2 $\rightleftharpoons$C2H2+CH3 3.000E+13 0.00 0
C2H3+C2H $\rightleftharpoons$2C2H2 3.000E+13 0.00 0
C2H3+CH $\rightleftharpoons$CH2+C2H2 5.000E+13 0.00 0
OH+C2H2 $\rightleftharpoons$C2H+H2O 3.370E+07 2.00 14000
OH+C2H2 $\rightleftharpoons$HCCOH+H 5.040E+05 2.30 13500
OH+C2H2 $\rightleftharpoons$CH2CO+H 2.180E-04 4.50 -1000
OH+C2H2 $\rightleftharpoons$CH3+CO 4.830E-04 4.00 -2000
HCCOH+H $\rightleftharpoons$CH2CO+H 1.000E+13 0.00 0
C2H2+O $\rightleftharpoons$C2H+OH 3.160E+15 -0.60 15000
CH2CO+O $\rightleftharpoons$CO2+CH2 1.750E+12 0.00 1350
CH2CO+H $\rightleftharpoons$CH3+CO 1.130E+13 0.00 3428
CH2CO+H $\rightleftharpoons$HCCO+H2 5.000E+13 0.00 8000
CH2CO+O $\rightleftharpoons$HCCO+OH 1.000E+13 0.00 8000
CH2CO+OH $\rightleftharpoons$HCCO+H2O 7.500E+12 0.00 2000
CH2CO(+M) $\rightleftharpoons$CH2+CO(+M) 3.000E+14 0.00 70980
Low pressure limit 3.60E+15 0.0 59270
C2H+O2 $\rightleftharpoons$2CO+H 5.000E+13 0.00 1500
C2H+C2H2 $\rightleftharpoons$C4H2+H 3.000E+13 0.00 0
H+HCCO $\rightleftharpoons$CH2(S)+CO 1.000E+14 0.00 0
O+HCCO $\rightleftharpoons$H+2CO 1.000E+14 0.00 0
HCCO+O2 $\rightleftharpoons$2CO+OH 1.600E+12 0.00 854
CH+HCCO $\rightleftharpoons$C2H2+CO 5.000E+13 0.00 0
2HCCO $\rightleftharpoons$C2H2+2CO 1.000E+13 0.00 0
CH2(S)+M $\rightleftharpoons$CH2+M 1.000E+13 0.00 0
Enhanced Collision Efficiencies:
H=0.0
CH2(S)+CH4 $\rightleftharpoons$2CH3 4.000E+13 0.00 0
CH2(S)+C2H6 $\rightleftharpoons$CH3+C2H5 1.200E+14 0.00 0
CH2(S)+O2 $\rightleftharpoons$CO+OH+H 3.000E+13 0.00 0
CH2(S)+H2 $\rightleftharpoons$CH3+H 7.000E+13 0.00 0
CH2(S)+H $\rightleftharpoons$CH2+H 2.000E+14 0.00 0
C2H+O $\rightleftharpoons$CH+CO 5.000E+13 0.00 0
C2H+OH $\rightleftharpoons$HCCO+H 2.000E+13 0.00 0
2CH2 $\rightleftharpoons$C2H2+H2 4.000E+13 0.00 0
CH2+HCCO $\rightleftharpoons$C2H3+CO 3.000E+13 0.00 0
CH2+C2H2 $\rightleftharpoons$C3H3+H 1.200E+13 0.00 6600
C4H2+OH $\rightleftharpoons$C3H2+HCO 6.660E+12 0.00 -410
C3H2+O2 $\rightleftharpoons$HCO+HCCO 1.000E+13 0.00 0
C3H3+O2 $\rightleftharpoons$CH2CO+HCO 3.000E+10 0.00 2868
C3H3+O $\rightleftharpoons$CH2O+C2H 2.000E+13 0.00 0
C3H3+OH $\rightleftharpoons$C3H2+H2O 2.000E+13 0.00 0
2C2H2 $\rightleftharpoons$C4H3+H 2.000E+12 0.00 45900
C4H3+M $\rightleftharpoons$C4H2+H+M 1.000E+16 0.00 59700
CH2(S)+C2H2 $\rightleftharpoons$C3H3+H 3.000E+13 0.00 0
C4H2+O $\rightleftharpoons$C3H2+CO 1.200E+12 0.00 0
C2H2+O2 $\rightleftharpoons$HCCO+OH 2.000E+08 1.50 30100
C2H2+M $\rightleftharpoons$C2H+H+M 4.200E+16 0.00 107000
C2H4+M $\rightleftharpoons$C2H2+H2+M 1.500E+15 0.00 55800
C2H4+M $\rightleftharpoons$C2H3+H+M 1.400E+16 0.00 82360
H2+O2 $\rightleftharpoons$2OH 1.700E+13 0.00 47780
OH+H2 $\rightleftharpoons$H2O+H 1.170E+09 1.30 3626
O+OH $\rightleftharpoons$O2+H 4.000E+14 -0.50 0
O+H2 $\rightleftharpoons$OH+H 5.060E+04 2.67 6290
H+O2+M $\rightleftharpoons$HO2+M 3.61E+17 -0.72 0
Enhanced Collision Efficiencies:
H2O=18.6, CO2=4.2, H2=2.9, CO=2.1, N2=1.3
OH+HO2 $\rightleftharpoons$H2O+O2 7.500E+12 0.00 0
H+HO2 $\rightleftharpoons$2OH 1.400E+14 0.00 1073
O+HO2 $\rightleftharpoons$O2+OH 1.400E+13 0.00 1073
2OH $\rightleftharpoons$O+H2O 6.000E+08 1.30 0
2H+M $\rightleftharpoons$H2+M 1.000E+18 -1.00 0
Enhanced Collision Efficiencies:
H2=0.0, H2O=0.0, CO2=0.0
2H+H2 $\rightleftharpoons$2H2 9.200E+16 -0.60 0
2H+H2O $\rightleftharpoons$H2+H2O 6.000E+19 -1.25 0
2H+CO2 $\rightleftharpoons$H2+CO2 5.490E+20 -2.00 0
H+OH+M $\rightleftharpoons$H2O+M 1.600E+22 -2.00 0
Enhanced Collision Efficiencies:
H2O=5.0
H+O+M $\rightleftharpoons$OH+M 6.200E+16 -0.60 0
Enhanced Collision Efficiencies:
H2O=5.0
2O+M $\rightleftharpoons$O2+M 1.890E+13 0.00 -1788
H+HO2 $\rightleftharpoons$H2+O2 1.250E+13 0.00 0
2HO2 $\rightleftharpoons$H2O2+O2 2.000E+12 0.00 0
H2O2+M $\rightleftharpoons$2OH+M 1.300E+17 0.00 45500
H2O2+H $\rightleftharpoons$HO2+H2 1.600E+12 0.00 3800
H2O2+OH $\rightleftharpoons$H2O+HO2 1.000E+13 0.00 1800
CH+N2 $\rightleftharpoons$HCN+N 3.000E+11 0.00 13600
CN+N $\rightleftharpoons$C+N2 1.040E+15 -0.50 0
CH2+N2 $\rightleftharpoons$HCN+NH 1.000E+13 0.00 74000
H2CN+N $\rightleftharpoons$N2+CH2 2.000E+13 0.00 0
H2CN+M $\rightleftharpoons$HCN+H+M 3.000E+14 0.00 22000
C+NO $\rightleftharpoons$CN+O 6.600E+13 0.00 0
CH+NO $\rightleftharpoons$HCN+O 1.100E+14 0.00 0
CH2+NO $\rightleftharpoons$HCNO+H 1.390E+12 0.00 -1100
CH3+NO $\rightleftharpoons$HCN+H2O 1.000E+11 0.00 15000
CH3+NO $\rightleftharpoons$H2CN+OH 1.000E+11 0.00 15000
HCCO+NO $\rightleftharpoons$HCNO+CO 2.000E+13 0.00 0
CH2(S)+NO $\rightleftharpoons$HCN+OH 2.000E+13 0.00 0
HCNO+H $\rightleftharpoons$HCN+OH 1.000E+14 0.00 12000
CH2+N $\rightleftharpoons$HCN+H 5.000E+13 0.00 0
CH+N $\rightleftharpoons$CN+H 1.300E+13 0.00 0
CO2+N $\rightleftharpoons$NO+CO 1.900E+11 0.00 3400
HCCO+N $\rightleftharpoons$HCN+CO 5.000E+13 0.00 0
CH3+N $\rightleftharpoons$H2CN+H 3.000E+13 0.00 0
C2H3+N $\rightleftharpoons$HCN+CH2 2.000E+13 0.00 0
C3H3+N $\rightleftharpoons$HCN+C2H2 1.000E+13 0.00 0
HCN+OH $\rightleftharpoons$CN+H2O 1.450E+13 0.00 10929
OH+HCN $\rightleftharpoons$HOCN+H 5.850E+04 2.40 12500
OH+HCN $\rightleftharpoons$HNCO+H 1.980E-03 4.00 1000
OH+HCN $\rightleftharpoons$NH2+CO 7.830E-04 4.00 4000
HOCN+H $\rightleftharpoons$HNCO+H 1.000E+13 0.00 0
HCN+O $\rightleftharpoons$NCO+H 1.380E+04 2.64 4980
HCN+O $\rightleftharpoons$NH+CO 3.450E+03 2.64 4980
HCN+O $\rightleftharpoons$CN+OH 2.700E+09 1.58 26600
CN+H2 $\rightleftharpoons$HCN+H 2.950E+05 2.45 2237
CN+O $\rightleftharpoons$CO+N 1.800E+13 0.00 0
CN+O2 $\rightleftharpoons$NCO+O 5.600E+12 0.00 0
CN+OH $\rightleftharpoons$NCO+H 6.000E+13 0.00 0
CN+HCN $\rightleftharpoons$C2N2+H 2.000E+13 0.00 0
CN+NO2 $\rightleftharpoons$NCO+NO 3.000E+13 0.00 0
CN+N2O $\rightleftharpoons$NCO+N2 1.000E+13 0.00 0
C2N2+O $\rightleftharpoons$NCO+CN 4.570E+12 0.00 8880
C2N2+OH $\rightleftharpoons$HOCN+CN 1.860E+11 0.00 2900
HO2+NO $\rightleftharpoons$NO2+OH 2.110E+12 0.00 -479
NO2+H $\rightleftharpoons$NO+OH 3.500E+14 0.00 1500
NO2+O $\rightleftharpoons$NO+O2 1.000E+13 0.00 600
NO2+M $\rightleftharpoons$NO+O+M 1.100E+16 0.00 66000
NCO+H $\rightleftharpoons$NH+CO 5.000E+13 0.00 0
NCO+O $\rightleftharpoons$NO+CO 2.000E+13 0.00 0
NCO+N $\rightleftharpoons$N2+CO 2.000E+13 0.00 0
NCO+OH $\rightleftharpoons$NO+CO+H 1.000E+13 0.00 0
NCO+M $\rightleftharpoons$N+CO+M 3.100E+16 -0.50 48000
NCO+NO $\rightleftharpoons$N2O+CO 1.000E+13 0.00 -390
NCO+H2 $\rightleftharpoons$HNCO+H 8.580E+12 0.00 9000
HNCO+H $\rightleftharpoons$NH2+CO 2.000E+13 0.00 3000
NH+O2 $\rightleftharpoons$NO+OH 7.600E+10 0.00 1530
NH+NO $\rightleftharpoons$N2O+H 2.400E+15 -0.80 0
N2O+OH $\rightleftharpoons$N2+HO2 2.000E+12 0.00 10000
N2O+H $\rightleftharpoons$N2+OH 7.600E+13 0.00 15200
N2O+M $\rightleftharpoons$N2+O+M 1.600E+14 0.00 51600
N2O+O $\rightleftharpoons$N2+O2 1.000E+14 0.00 28200
N2O+O $\rightleftharpoons$2NO 1.000E+14 0.00 28200
NH+OH $\rightleftharpoons$HNO+H 2.000E+13 0.00 0
NH+OH $\rightleftharpoons$N+H2O 5.000E+11 0.50 2000
NH+N $\rightleftharpoons$N2+H 3.000E+13 0.00 0
NH+H $\rightleftharpoons$N+H2 1.000E+14 0.00 0
NH2+O $\rightleftharpoons$HNO+H 6.630E+14 -0.50 0
NH2+O $\rightleftharpoons$NH+OH 6.750E+12 0.00 0
NH2+OH $\rightleftharpoons$NH+H2O 4.000E+06 2.00 1000
NH2+H $\rightleftharpoons$NH+H2 6.920E+13 0.00 3650
NH2+NO $\rightleftharpoons$NNH+OH 6.400E+15 -1.25 0
NH2+NO $\rightleftharpoons$N2+H2O 6.200E+15 -1.25 0
NNH+M $\rightleftharpoons$N2+H+M 1.000E+04 0.00 0
NNH+NO $\rightleftharpoons$N2+HNO 5.000E+13 0.00 0
NNH+H $\rightleftharpoons$N2+H2 1.000E+14 0.00 0
NNH+OH $\rightleftharpoons$N2+H2O 5.000E+13 0.00 0
NNH+NH2 $\rightleftharpoons$N2+NH3 5.000E+13 0.00 0
NNH+NH $\rightleftharpoons$N2+NH2 5.000E+13 0.00 0
NNH+O $\rightleftharpoons$N2O+H 1.000E+14 0.00 0
HNO+M $\rightleftharpoons$H+NO+M 1.500E+16 0.00 48680
Enhanced Collision Efficiencies:
H2O=10.0, O2=2.0, N2=2.0, H2=2.0
HNO+OH $\rightleftharpoons$NO+H2O 3.600E+13 0.00 0
HNO+H $\rightleftharpoons$H2+NO 5.000E+12 0.00 0
HNO+NH2 $\rightleftharpoons$NH3+NO 2.000E+13 0.0 1000
N+NO $\rightleftharpoons$N2+O 3.270E+12 0.30 0
N+O2 $\rightleftharpoons$NO+O 6.400E+09 1.00 6280
N+OH $\rightleftharpoons$NO+H 3.800E+13 0.00 0
NH+O $\rightleftharpoons$NO+H 2.000E+13 0.00 0
HNO+HNO $\rightleftharpoons$N2O+H2O 3.950E+12 0.00 5000
HNO+NO $\rightleftharpoons$N2O+OH 2.000E+12 0.00 26000
NH2+NH $\rightleftharpoons$N2H2+H 5.000E+13 0.00 0
2NH $\rightleftharpoons$N2+2H 2.540E+13 0.00 0
NH2+N $\rightleftharpoons$N2+2H 7.200E+13 0.00 0
N2H2+M $\rightleftharpoons$NNH+H+M 5.000E+16 0.00 50000
Enhanced Collision Efficiencies:
H2O=15.0, O2=2.0, N2=2.0, H2=2.0
N2H2+H $\rightleftharpoons$NNH+H2 5.000E+13 0.00 1000
N2H2+O $\rightleftharpoons$NH2+NO 1.000E+13 0.00 0
N2H2+O $\rightleftharpoons$NNH+OH 2.000E+13 0.00 1000
N2H2+OH $\rightleftharpoons$NNH+H2O 1.000E+13 0.00 1000
N2H2+NO $\rightleftharpoons$N2O+NH2 3.000E+12 0.00 0
N2H2+NH $\rightleftharpoons$NNH+NH2 1.000E+13 0.00 1000
N2H2+NH2 $\rightleftharpoons$NH3+NNH 1.000E+13 0.00 1000
2NH2 $\rightleftharpoons$N2H2+H2 5.000E+11 0.00 0
NH3+M $\rightleftharpoons$NH2+H+M 1.778E+16 0.00 92100
NH3+O2 $\rightleftharpoons$NH2+HO2 1.000E+12 0.00 61500
NH3+H $\rightleftharpoons$NH2+H2 1.259E+14 0.00 22000
NH3+O $\rightleftharpoons$NH2+OH 1.514E+12 0.00 6000
NH3+OH $\rightleftharpoons$NH2+H2O 2.512E+12 0.00 2000
NH2+O2 $\rightleftharpoons$HNO+OH 1.5849E+13 0.00 28600
HNO+O2 $\rightleftharpoons$NO+HO2 3.1623E+12 0.00 3000
NH2+O2 $\rightleftharpoons$NH+HO2 1.0000E+14 0.00 50000
NH+O2 $\rightleftharpoons$O+HNO 1.0000E+14 0.00 1000

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Next: [Miller et al. (1983)] Up: Reaction Mechanisms Previous: [Frenklach et al. (1995)]
Joe E. Shepherd
2000-01-17