#**************************************************************************************
#
# Foundational Fuel Chemistry Model Version 2 (FFCM-2)
#
# - Description:
#   FFCM-2: An optimized reaction model for combustion chemistry of species up to C4 (Cantera YAML format)
#
# - Authors:
#     Yue Zhang, Wendi Dong, Laurien A. Vandewalle, Rui Xu, Gregory P. Smith, Hai Wang
#
# - Date: 
#     July 2023
#
# - Contact:
#     Hai Wang: haiwang@stanford.edu
#
# - https://web.stanford.edu/group/haiwanglab/FFCM2/
#
# - How to cite:
# 
#   Y. Zhang, W. Dong, L. Vandewalle, R. Xu, G.P. Smith and H. Wang, Foundational Fuel Chemistry Model Version 2.0 (FFCM-2), https://web.stanford.edu/group/haiwanglab/FFCM2, 2023.
#
#  Bibtex
#  @Misc{ZDV2023,
#  author           = {Zhang, Yue and Dong, Wendi and Vandewalle, Laurien and Xu, Rui and Smith, Gregory and Wang, Hai},
#  title            = {Foundational {Fuel} {Chemistry} {Model} {Version} 2.0 ({FFCM}-2)},
#  year             = {2023},
#  modificationdate = {2023-06-28T19:14:11},
#  url              = {https://web.stanford.edu/group/haiwanglab/FFCM2/},
#  }
#
#***************************************************************************************

units: {length: cm, quantity: mol, activation-energy: cal/mol}

phases:
- name: gas
  thermo: ideal-gas
  elements: [H, O, He, Ar, N, C]
  species: [H, H2, O, O2, OH, H2O, HO2, H2O2, HE, AR, N2, C, CH, CH2, CH2(S),
    CH3, CH4, CO, CO2, HCO, CH2O, CH2OH, CH3O, CH3OH, C2H, C2H2, C2H3, C2H4,
    C2H5, C2H6, HCCO, CH2CO, CH2CHO, CH3CHO, CH3CO, H2CC, CH3O2, CH3OOH,
    C2H5O2, C2H5OOH, C2H2OH, C2H3OH, C2H4O, C2H5OH, C2H4OH, CH3CHOH, C3H8,
    NC3H7, IC3H7, C3H6, C3H5, CH3CCH2, AC3H4, PC3H4, C3H3, C2H5CHO, CH3COCH3,
    CH3COCH2, C2H3CHO, C3H5OH, NC3H7O2, NC3H7OOH, IC3H7O2, IC3H7OOH, C4H2,
    NC4H3, IC4H3, C4H4, NC4H5, IC4H5, C4H5-2, C4H6, C4H612, C4H6-2, C4H7,
    IC4H7, IC4H7-1, C4H81, C4H82, IC4H8, NC4H9, SC4H9, IC4H9, TC4H9, C4H10,
    IC4H10, H2C4O, CH2CHCHCHO, CH3CHCHCO, CH3CHCHCHO, C3H7CHO, IC3H7CHO,
    C2H5COCH3, C2H3COCH3, OH*, CH*]
  kinetics: gas
  reactions: all
  transport: mixture-averaged
  state:
    T: 300.0
    P: 1.01325e+05

species:
- name: H
  composition: {H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
  transport:
    model: gas
    geometry: atom
    diameter: 2.05
    well-depth: 145.0
- name: H2
  composition: {H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.34433112, 7.98052075e-03, -1.9478151e-05, 2.01572094e-08, -7.37611761e-12,
      -917.935173, 0.683010238]
    - [2.93286575, 8.26608026e-04, -1.46402364e-07, 1.54100414e-11, -6.888048e-16,
      -813.065581, -1.02432865]
  transport:
    model: gas
    geometry: linear
    diameter: 2.92
    well-depth: 38.0
    polarizability: 0.79
    rotational-relaxation: 280.0
- name: O
  composition: {O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.1682671, -3.27931884e-03, 6.64306396e-06, -6.12806624e-09, 2.11265971e-12,
      2.91222592e+04, 2.05193346]
    - [2.54363697, -2.73162486e-05, -4.1902952e-09, 4.95481845e-12, -4.79553694e-16,
      2.9226012e+04, 4.92229457]
  transport:
    model: gas
    geometry: atom
    diameter: 2.75
    well-depth: 80.0
- name: O2
  composition: {O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.78245636, -2.99673416e-03, 9.84730201e-06, -9.68129509e-09, 3.24372837e-12,
      -1063.94356, 3.65767573]
    - [3.66096065, 6.56365811e-04, -1.41149627e-07, 2.05797935e-11, -1.29913436e-15,
      -1215.97718, 3.41536279]
  transport:
    model: gas
    geometry: linear
    diameter: 3.458
    well-depth: 107.4
    polarizability: 1.6
    rotational-relaxation: 3.8
- name: OH
  composition: {H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.99198424, -2.40106655e-03, 4.61664033e-06, -3.87916306e-09, 1.36319502e-12,
      3368.89836, -0.103998477]
    - [2.83853033, 1.10741289e-03, -2.94000209e-07, 4.20698729e-11, -2.4228989e-15,
      3697.80808, 5.84494652]
  transport:
    model: gas
    geometry: linear
    diameter: 2.75
    well-depth: 80.0
- name: H2O
  composition: {H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.1986352, -2.0364017e-03, 6.5203416e-06, -5.4879269e-09, 1.771968e-12,
      -3.0293726e+04, -0.84900901]
    - [2.6770389, 2.9731816e-03, -7.7376889e-07, 9.4433514e-11, -4.2689991e-15,
      -2.9885894e+04, 6.88255]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 2.605
    well-depth: 572.4
    dipole: 1.844
    rotational-relaxation: 4.0
- name: HO2
  composition: {H: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 5000.0]
    data:
    - [4.30179807, -4.74912097e-03, 2.11582905e-05, -2.42763914e-08, 9.29225225e-12,
      264.018485, 3.7166622]
    - [4.17228741, 1.88117627e-03, -3.46277286e-07, 1.94657549e-11, 1.76256905e-16,
      31.0206839, 2.95767672]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.458
    well-depth: 107.4
    rotational-relaxation: 1.0
- name: H2O2
  composition: {H: 2, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.31515149, -8.47390622e-04, 1.76404323e-05, -2.26762944e-08, 9.08950158e-12,
      -1.77067437e+04, 3.27373319]
    - [4.57977305, 4.05326003e-03, -1.2984473e-06, 1.982114e-10, -1.13968792e-14,
      -1.80071775e+04, 0.664970694]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.458
    well-depth: 107.4
    rotational-relaxation: 3.8
- name: HE
  composition: {He: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 0.928723974]
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 0.928723974]
  transport:
    model: gas
    geometry: atom
    diameter: 2.576
    well-depth: 10.2
- name: AR
  composition: {Ar: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 4.37967491]
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 4.37967491]
  transport:
    model: gas
    geometry: atom
    diameter: 3.33
    well-depth: 136.5
- name: N2
  composition: {N: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.53100528, -1.23660988e-04, -5.02999433e-07, 2.43530612e-09, -1.40881235e-12,
      -1046.97628, 2.96747038]
    - [2.95257637, 1.3969004e-03, -4.92631603e-07, 7.86010195e-11, -4.60755204e-15,
      -923.948688, 5.87188762]
  transport:
    model: gas
    geometry: linear
    diameter: 3.621
    well-depth: 97.53
    polarizability: 1.76
    rotational-relaxation: 4.0
- name: C
  composition: {C: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5542395, -3.2153772e-04, 7.3379223e-07, -7.3223487e-10, 2.6652144e-13,
      8.5442681e+04, 4.5313085]
    - [2.605583, -1.9593434e-04, 1.0673722e-07, -1.642394e-11, 8.187058e-16,
      8.5411742e+04, 4.1923868]
  transport:
    model: gas
    geometry: atom
    diameter: 3.298
    well-depth: 71.4
- name: CH
  composition: {C: 1, H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.4897583, 3.243216e-04, -1.6899751e-06, 3.162842e-09, -1.4061803e-12,
      7.0612646e+04, 2.0842841]
    - [2.5209369, 1.7653639e-03, -4.614766e-07, 5.9289675e-11, -3.3474501e-15,
      7.0946769e+04, 7.4051829]
  transport:
    model: gas
    geometry: linear
    diameter: 2.75
    well-depth: 80.0
    rotational-relaxation: 1.0
- name: CH2
  composition: {C: 1, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.71757846, 1.2739126e-03, 2.17347251e-06, -3.488585e-09, 1.65208866e-12,
      4.58723866e+04, 1.75297945]
    - [3.14631886, 3.03671259e-03, -9.96474439e-07, 1.5048358e-10, -8.57335515e-15,
      4.60412605e+04, 4.72341711]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH2(S)
  composition: {C: 1, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.19331325, -2.33105184e-03, 8.15676451e-06, -6.62985981e-09, 1.93233199e-12,
      5.03662246e+04, -0.74673431]
    - [3.13501686, 2.89593926e-03, -8.1666809e-07, 1.13572697e-10, -6.36262835e-15,
      5.05040504e+04, 4.06030621]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH3
  composition: {C: 1, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.6571797, 2.1265979e-03, 5.4583883e-06, -6.6181003e-09, 2.4657074e-12,
      1.6422716e+04, 1.6735354]
    - [2.9781206, 5.797852e-03, -1.97558e-06, 3.072979e-10, -1.7917416e-14,
      1.6509513e+04, 4.7224799]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH4
  composition: {C: 1, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.14911468, -0.0136622009, 4.91453921e-05, -4.84246767e-08, 1.66603441e-11,
      -1.02465983e+04, -4.63848842]
    - [1.65326226, 0.0100263099, -3.31661238e-06, 5.36483138e-10, -3.14696758e-14,
      -1.00095936e+04, 9.90506283]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.746
    well-depth: 141.4
    polarizability: 2.6
    rotational-relaxation: 13.0
- name: CO
  composition: {C: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.5795335, -6.1035369e-04, 1.0168143e-06, 9.0700586e-10, -9.0442449e-13,
      -1.4344086e+04, 3.5084093]
    - [3.0484859, 1.3517281e-03, -4.8579405e-07, 7.8853644e-11, -4.6980746e-15,
      -1.4266117e+04, 6.0170977]
  transport:
    model: gas
    geometry: linear
    diameter: 3.65
    well-depth: 98.1
    polarizability: 1.95
    rotational-relaxation: 1.8
- name: CO2
  composition: {C: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.356813, 8.9841299e-03, -7.1220632e-06, 2.4573008e-09, -1.4288548e-13,
      -4.8371971e+04, 9.9009035]
    - [4.6365111, 2.7414569e-03, -9.9589759e-07, 1.6038666e-10, -9.1619857e-15,
      -4.9024904e+04, -1.9348955]
  transport:
    model: gas
    geometry: linear
    diameter: 3.763
    well-depth: 244.0
    polarizability: 2.65
    rotational-relaxation: 2.1
- name: HCO
  composition: {C: 1, H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.2375461, -3.32075257e-03, 1.40030264e-05, -1.34239995e-08, 4.37416208e-12,
      3872.41185, 3.30834869]
    - [3.92001542, 2.52279324e-03, -6.71004164e-07, 1.05615948e-10, -7.43798261e-15,
      3653.42928, 3.58077056]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
    rotational-relaxation: 2.0
- name: CH2O
  composition: {C: 1, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.79372312, -9.90833322e-03, 3.7321999e-05, -3.79285237e-08, 1.31772641e-11,
      -1.43791953e+04, 0.602798058]
    - [3.16952665, 6.1932056e-03, -2.25056366e-06, 3.6597566e-10, -2.20149458e-14,
      -1.45486831e+04, 6.04207898]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
    rotational-relaxation: 2.0
- name: CH2OH
  composition: {C: 1, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.47834367, -1.3507031e-03, 2.7848498e-05, -3.6486906e-08, 1.4790745e-11,
      -3500.7289, 3.309135]
    - [5.0931437, 5.9476126e-03, -2.0649746e-06, 3.23008173e-10, -1.88125902e-14,
      -4034.0964, -1.84691493]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.69
    well-depth: 417.0
    dipole: 1.7
    rotational-relaxation: 2.0
- name: CH3O
  composition: {C: 1, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.71180502, -2.80463306e-03, 3.76550971e-05, -4.73072089e-08, 1.8658842e-11,
      1295.6976, 6.57240864]
    - [4.75779238, 7.44142474e-03, -2.69705176e-06, 4.38090504e-10, -2.63537098e-14,
      378.11194, -1.96680028]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.69
    well-depth: 417.0
    dipole: 1.7
    rotational-relaxation: 2.0
- name: CH3OH
  composition: {C: 1, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.65851051, -0.0162983419, 6.91938156e-05, -7.58372926e-08, 2.8042755e-11,
      -2.56119736e+04, -0.897330508]
    - [3.52726795, 0.0103178783, -3.62892944e-06, 5.77448016e-10, -3.42182632e-14,
      -2.60028834e+04, 5.16758693]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.626
    well-depth: 481.8
    rotational-relaxation: 1.0
- name: C2H
  composition: {C: 2, H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.89867676, 0.0132988489, -2.80733327e-05, 2.89484755e-08, -1.07502351e-11,
      6.7061605e+04, 6.18547632]
    - [3.66270248, 3.82492252e-03, -1.366325e-06, 2.1345504e-10, -1.23216848e-14,
      6.7168379e+04, 3.92205792]
  transport:
    model: gas
    geometry: linear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: C2H2
  composition: {C: 2, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [0.808679682, 0.0233615762, -3.55172234e-05, 2.80152958e-08, -8.50075165e-12,
      2.63076808e+04, 13.9396761]
    - [4.65878489, 4.88396667e-03, -1.60828888e-06, 2.46974544e-10, -1.38605959e-14,
      2.56371042e+04, -3.99838194]
  transport:
    model: gas
    geometry: linear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: C2H3
  composition: {C: 2, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.36377642, 2.65765722e-04, 2.79620704e-05, -3.72986942e-08, 1.51590176e-11,
      3.44749589e+04, 7.91510092]
    - [4.15026763, 7.54021341e-03, -2.62997847e-06, 4.15974048e-10, -2.45407509e-14,
      3.3856638e+04, 1.72812235]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 1.0
- name: C2H4
  composition: {C: 2, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.95920063, -7.57051373e-03, 5.70989993e-05, -6.91588352e-08, 2.6988419e-11,
      5089.77598, 4.09730213]
    - [3.99182724, 0.0104833908, -3.71721342e-06, 5.94628366e-10, -3.53630386e-14,
      4268.65851, -0.269081762]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.971
    well-depth: 280.8
    rotational-relaxation: 1.5
- name: C2H5
  composition: {C: 2, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.24185905, -3.56905235e-03, 4.82667202e-05, -5.85401009e-08, 2.25804514e-11,
      1.29690344e+04, 4.44703782]
    - [4.32195633, 0.0123930542, -4.3968096e-06, 7.03519917e-10, -4.18435239e-14,
      1.21759475e+04, 0.171103809]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.302
    well-depth: 252.3
    rotational-relaxation: 1.5
- name: C2H6
  composition: {C: 2, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.29142572, -5.50154901e-03, 5.99438458e-05, -7.08466469e-08, 2.68685836e-11,
      -1.15222056e+04, 2.66678994]
    - [4.04666411, 0.0153538802, -5.47039485e-06, 8.77826544e-10, -5.23167531e-14,
      -1.24473499e+04, -0.968698313]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.302
    well-depth: 252.3
    rotational-relaxation: 1.5
- name: HCCO
  composition: {C: 2, H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.87607969, 0.0221205418, -3.58869325e-05, 3.05402541e-08, -1.01281069e-11,
      2.0163384e+04, 13.696829]
    - [5.91479333, 3.7140873e-03, -1.3013701e-06, 2.06473345e-10, -1.21476759e-14,
      1.93596301e+04, -5.50567269]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 2.5
    well-depth: 150.0
    rotational-relaxation: 1.0
- name: CH2CO
  composition: {C: 2, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.13241136, 0.0181319455, -1.74093315e-05, 9.3533604e-09, -2.01724844e-12,
      -7148.0852, 13.3807969]
    - [5.75871449, 6.35124053e-03, -2.25955361e-06, 3.62321512e-10, -2.15855515e-14,
      -8085.33464, -4.96490444]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: CH2CHO
  composition: {C: 2, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.66873956, 9.62329538e-03, 1.60617438e-05, -2.8768182e-08, 1.25030066e-11,
      564.138429, 12.5694476]
    - [5.91636535, 8.84650426e-03, -3.14954895e-06, 5.05413189e-10, -3.01304621e-14,
      -703.08992, -6.10649981]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: CH3CHO
  composition: {C: 2, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.7294595, -3.1932858e-03, 4.7534921e-05, -5.7458611e-08, 2.1931112e-11,
      -2.1572878e+04, 4.1030159]
    - [5.4041108, 0.011723059, -4.2263137e-06, 6.8372451e-10, -4.0984863e-14,
      -2.2593122e+04, -3.4807917]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: CH3CO
  composition: {C: 2, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.0358705, 8.7729487e-04, 3.071001e-05, -3.9247565e-08, 1.5296869e-11,
      -2682.0738, 7.8617682]
    - [5.3137165, 9.1737793e-03, -3.3220386e-06, 5.3947456e-10, -3.2452368e-14,
      -3645.0414, -1.6757558]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: H2CC
  composition: {C: 2, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.28154941, 6.9764265e-03, -2.38527914e-06, -1.21077631e-09, 9.82041734e-13,
      4.83191706e+04, 5.92035686]
    - [4.27807305, 4.75622626e-03, -1.63007378e-06, 2.5462268e-10, -1.48860086e-14,
      4.80140478e+04, 0.6399786]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: CH3O2
  composition: {C: 1, H: 3, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.97169544, -5.29356557e-03, 4.77334149e-05, -5.77065617e-08, 2.22219969e-11,
      -129.022161, 2.81501182]
    - [5.55530486, 9.12236137e-03, -3.23851661e-06, 5.18713798e-10, -3.08834151e-14,
      -1035.69402, -3.99158547]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.626
    well-depth: 481.8
    rotational-relaxation: 1.0
- name: CH3OOH
  composition: {C: 1, H: 4, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.90540897, 0.0174994735, 5.2824363e-06, -2.52827275e-08, 1.34368212e-11,
      -1.68894632e+04, 11.3741987]
    - [7.76538058, 8.61499712e-03, -2.98006935e-06, 4.68638071e-10, -2.75339255e-14,
      -1.82979984e+04, -14.3992663]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.626
    well-depth: 481.8
    rotational-relaxation: 1.0
- name: C2H5O2
  composition: {C: 2, H: 5, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.50099327, 6.87965342e-03, 4.74143971e-05, -6.92287127e-08, 2.87395324e-11,
      -5395.47911, 7.91490068]
    - [8.88872432, 0.0135833179, -4.91116949e-06, 7.92343362e-10, -4.73525704e-14,
      -7441.07388, -19.0789836]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.41
    well-depth: 470.6
    rotational-relaxation: 1.5
- name: C2H5OOH
  composition: {C: 2, H: 6, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.14672004, 9.78668137e-03, 4.91492257e-05, -7.42532076e-08, 3.11169441e-11,
      -2.20469219e+04, 9.84024999]
    - [9.58691079, 0.0148603589, -5.29787964e-06, 8.47317148e-10, -5.03436325e-14,
      -2.441659e+04, -22.8310676]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.41
    well-depth: 470.6
    rotational-relaxation: 1.5
- name: C2H2OH
  composition: {C: 2, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [0.081498282, 0.031640644, -3.4085361e-05, 1.8978838e-08, -4.1950165e-12,
      1.4357133e+04, 22.908977]
    - [5.7206843, 0.010704185, -5.0358494e-06, 1.1324499e-09, -1.0086621e-13,
      1.3145774e+04, -4.7081776]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.162
    well-depth: 224.7
    rotational-relaxation: 1.0
- name: C2H3OH
  composition: {C: 2, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.95966153, 0.0201744811, -1.09658218e-06, -1.62414813e-08, 9.1573655e-12,
      -1.6439337e+04, 14.3785378]
    - [7.20200781, 9.59749604e-03, -3.34348031e-06, 5.28604398e-10, -3.1183276e-14,
      -1.79990363e+04, -13.4267646]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: C2H4O
  composition: {C: 2, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.7590532, -9.441218e-03, 8.0309721e-05, -1.0080788e-07, 4.0039921e-11,
      -7560.8143, 7.8497475]
    - [5.4887641, 0.01204619, -4.3336931e-06, 7.0028311e-10, -4.1949088e-14,
      -9180.4251, -7.0799605]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: C2H5OH
  composition: {C: 2, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.8586957, -3.7401726e-03, 6.9555378e-05, -8.8654796e-08, 3.5168835e-11,
      -2.9996132e+04, 4.8018545]
    - [6.5624365, 0.015204222, -5.3896795e-06, 8.6225011e-10, -5.1289787e-14,
      -3.1525621e+04, -9.4730202]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.41
    well-depth: 470.6
    rotational-relaxation: 1.5
- name: C2H4OH
  composition: {C: 2, H: 5, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.20954137, 9.12964578e-03, 2.47462263e-05, -3.92945764e-08, 1.66541312e-11,
      -4915.11371, 8.30445413]
    - [7.01348674, 0.0120204391, -4.21992012e-06, 6.70675981e-10, -3.97135273e-14,
      -6161.61779, -8.62052409]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.41
    well-depth: 470.6
    rotational-relaxation: 1.5
- name: CH3CHOH
  composition: {C: 2, H: 5, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.2228325, 5.12174798e-03, 3.48386522e-05, -4.91943637e-08, 2.01183723e-11,
      -8356.22088, 8.016757]
    - [6.35842302, 0.0124356276, -4.33096839e-06, 6.84530381e-10, -4.03713238e-14,
      -9530.18581, -6.05106112]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.41
    well-depth: 470.6
    rotational-relaxation: 1.5
- name: C3H8
  composition: {C: 3, H: 8}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.21093013, 1.70886504e-03, 7.06530164e-05, -9.20060565e-08, 3.64618453e-11,
      -1.43810883e+04, 5.61004451]
    - [6.6691976, 0.0206108751, -7.36512349e-06, 1.18434262e-09, -7.0691463e-14,
      -1.62754066e+04, -13.1943379]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.982
    well-depth: 266.8
    rotational-relaxation: 1.0
- name: NC3H7
  composition: {C: 3, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.08211458, 5.23240341e-03, 5.13554466e-05, -6.99343598e-08, 2.81819493e-11,
      1.04074558e+04, 8.39534919]
    - [6.49636579, 0.0177337992, -6.24898046e-06, 9.95389495e-10, -5.9019977e-14,
      8859.73885, -8.5638971]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.982
    well-depth: 266.8
    rotational-relaxation: 1.0
- name: IC3H7
  composition: {C: 3, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.47421257, -8.42536682e-03, 8.04607759e-05, -9.49287824e-08, 3.59830971e-11,
      9049.39013, 3.40542323]
    - [5.30597255, 0.0189854588, -6.74315384e-06, 1.0799373e-09, -6.42785036e-14,
      7787.4891, -2.23233935]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.982
    well-depth: 266.8
    rotational-relaxation: 1.0
- name: C3H6
  composition: {C: 3, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.83464468, 3.29078952e-03, 5.05228001e-05, -6.66251176e-08, 2.63707473e-11,
      788.717123, 7.53408013]
    - [6.03870234, 0.0162963931, -5.821308e-06, 9.35936829e-10, -5.58603143e-14,
      -741.715057, -8.43825992]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.678
    well-depth: 298.9
    rotational-relaxation: 1.0
- name: C3H5
  composition: {C: 3, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.65533607, 0.016368875, 2.10544223e-05, -4.24018394e-08, 1.92638759e-11,
      1.88544047e+04, 16.1040987]
    - [6.74633155, 0.013107176, -4.60059113e-06, 7.3102951e-10, -4.32759674e-14,
      1.70241431e+04, -12.5248814]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: CH3CCH2
  composition: {C: 3, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 3000.0]
    data:
    - [1.7329209, 0.02239462, -5.1490611e-06, -6.7596466e-09, 3.8253211e-12,
      2.9040498e+04, 16.568878]
    - [5.4255528, 0.015511072, -5.667835e-06, 7.9224388e-10, -1.6878034e-14,
      2.7843027e+04, -3.3527184]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.982
    well-depth: 266.8
    rotational-relaxation: 1.0
- name: AC3H4
  composition: {C: 3, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.6130445, 0.012122575, 1.853988e-05, -3.4525149e-08, 1.5335079e-11,
      2.1541567e+04, 10.226139]
    - [6.3168722, 0.011133728, -3.9629378e-06, 6.3564238e-10, -3.787554e-14,
      2.0117495e+04, -10.995766]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: PC3H4
  composition: {C: 3, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.6803869, 0.015799651, 2.5070596e-06, -1.3657623e-08, 6.6154285e-12,
      2.0802374e+04, 9.8769351]
    - [6.02524, 0.011336542, -4.0223391e-06, 6.4376063e-10, -3.8299635e-14,
      1.9620942e+04, -8.6043785]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: C3H3
  composition: {C: 3, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.35110927, 0.0327411223, -4.73827135e-05, 3.76309808e-08, -1.18540923e-11,
      4.07604783e+04, 15.2058924]
    - [7.1422188, 7.61902005e-03, -2.6745995e-06, 4.24914801e-10, -2.51475415e-14,
      3.95634427e+04, -12.5848435]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: C2H5CHO
  composition: {C: 3, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.24529681, 6.68296706e-03, 4.93337933e-05, -6.71986124e-08, 2.67262347e-11,
      -2.46140007e+04, 6.9073856]
    - [7.4408569, 0.0177301764, -6.34081568e-06, 1.02040803e-09, -6.09461714e-14,
      -2.64722814e+04, -14.4195446]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.662
    well-depth: 435.2
    rotational-relaxation: 1.0
- name: CH3COCH3
  composition: {C: 3, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.5563892, -2.83863547e-03, 7.05722951e-05, -8.78130984e-08, 3.40290951e-11,
      -2.78325393e+04, 2.31960221]
    - [7.29796974, 0.0175656913, -6.31678065e-06, 1.02025553e-09, -6.10903592e-14,
      -2.95368927e+04, -12.7591704]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.86
    well-depth: 435.5
    rotational-relaxation: 1.0
- name: CH3COCH2
  composition: {C: 3, H: 5, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.70187196, 5.51653762e-03, 4.27505858e-05, -5.94680816e-08, 2.40685378e-11,
      -5928.45491, 7.1293259]
    - [7.54410697, 0.0143443222, -5.08381081e-06, 8.13200521e-10, -4.83673315e-14,
      -7486.72286, -11.4792587]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.86
    well-depth: 435.5
    rotational-relaxation: 1.0
- name: C2H3CHO
  composition: {C: 3, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.69868861, 4.99965957e-03, 4.38587397e-05, -6.128839e-08, 2.48508985e-11,
      -9718.6286, 7.29812046]
    - [8.20654919, 0.0128492916, -4.64285331e-06, 7.51738738e-10, -4.51298116e-14,
      -1.15149341e+04, -14.9881933]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.958
    well-depth: 428.8
    rotational-relaxation: 1.0
- name: C3H5OH
  composition: {C: 3, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.15011905, 0.0128538274, 4.28438434e-05, -6.67818707e-08, 2.80408237e-11,
      -1.66413668e+04, 13.5066359]
    - [8.72477114, 0.0163942712, -5.90852993e-06, 9.53262253e-10, -5.7031801e-14,
      -1.90496618e+04, -19.7198674]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.997
    well-depth: 481.5
    rotational-relaxation: 1.0
- name: NC3H7O2
  composition: {C: 3, H: 7, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [6.99488957, -7.50355088e-03, 1.01250579e-04, -1.25012534e-07, 4.84675978e-11,
      -8083.5424, -2.03740242]
    - [9.24489759, 0.0214800809, -7.69335773e-06, 1.2394516e-09, -7.40911693e-14,
      -1.03653795e+04, -22.0401438]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.997
    well-depth: 481.5
    rotational-relaxation: 1.0
- name: NC3H7OOH
  composition: {C: 3, H: 8, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [7.08977756, -4.86163264e-03, 1.03253531e-04, -1.33200956e-07, 5.30799252e-11,
      -2.48547556e+04, 1.74859215]
    - [10.4115631, 0.0213763889, -7.5581987e-06, 1.2020718e-09, -7.1179809e-14,
      -2.73288446e+04, -23.5428789]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.997
    well-depth: 481.5
    rotational-relaxation: 1.0
- name: IC3H7O2
  composition: {C: 3, H: 7, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.12005687, 0.0169176962, 5.01416359e-05, -8.05117092e-08, 3.39943315e-11,
      -1.0146094e+04, 10.0073971]
    - [11.9405543, 0.0183233057, -6.60253757e-06, 1.06426615e-09, -6.35772707e-14,
      -1.33370837e+04, -35.7257224]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.997
    well-depth: 481.5
    rotational-relaxation: 1.0
- name: IC3H7OOH
  composition: {C: 3, H: 8, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.00148276, 0.0248858762, 4.19631776e-05, -7.6607073e-08, 3.33976412e-11,
      -2.67958187e+04, 13.1195741]
    - [12.745437, 0.0199086003, -7.08133666e-06, 1.13614316e-09, -6.77390723e-14,
      -3.04456915e+04, -42.2378046]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.997
    well-depth: 481.5
    rotational-relaxation: 1.0
- name: C4H2
  composition: {C: 4, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [-0.502389168, 0.0525164044, -9.29945578e-05, 8.17206506e-08, -2.73537313e-11,
      5.38574848e+04, 20.6780532]
    - [8.65615648, 6.74465042e-03, -2.3686841e-06, 3.76553454e-10, -2.22995205e-14,
      5.22459295e+04, -21.8462806]
  transport:
    model: gas
    geometry: linear
    diameter: 4.72
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: NC4H3
  composition: {C: 4, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [0.554263934, 0.0386185425, -4.7081828e-05, 3.06240321e-08, -7.90588421e-12,
      6.3797491e+04, 21.0542043]
    - [8.44631306, 9.07291526e-03, -3.18681201e-06, 5.06725048e-10, -3.00149855e-14,
      6.20007365e+04, -17.7938854]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: IC4H3
  composition: {C: 4, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.3796417, 0.027049884, -2.90761572e-05, 1.83027765e-08, -4.81164203e-12,
      5.83688723e+04, 10.5464883]
    - [8.51181244, 9.03337808e-03, -3.17602594e-06, 5.05276458e-10, -2.99379699e-14,
      5.71046116e+04, -15.1017769]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H4
  composition: {C: 4, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.37368786, 0.0288801256, -1.46863874e-05, -3.91045446e-09, 4.78133572e-12,
      3.30633344e+04, 17.5941274]
    - [7.98456038, 0.0120558816, -4.23587475e-06, 6.7364614e-10, -3.99059864e-14,
      3.11993029e+04, -16.7958975]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: NC4H5
  composition: {C: 4, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.28605952, 0.0143352325, 2.78456642e-05, -4.84612551e-08, 2.10628469e-11,
      4.19222504e+04, 12.6653969]
    - [8.11183574, 0.014227637, -5.02419535e-06, 8.0081658e-10, -4.75459802e-14,
      4.00134524e+04, -15.2704514]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: IC4H5
  composition: {C: 4, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.00881066, 0.0250340684, 4.47930427e-06, -2.63989791e-08, 1.3443288e-11,
      3.62069792e+04, 15.9913722]
    - [8.587611, 0.0142683804, -5.04812095e-06, 8.06555355e-10, -4.79335634e-14,
      3.40836919e+04, -19.6196761]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H5-2
  composition: {C: 4, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.41575788, 0.0136823548, 1.7653317e-05, -3.06168262e-08, 1.27850098e-11,
      3.47871254e+04, 6.39669972]
    - [7.62618778, 0.0147321922, -5.22511622e-06, 8.36085367e-10, -4.97358383e-14,
      3.33816425e+04, -12.6664026]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H6
  composition: {C: 4, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.10599669, 5.05575563e-03, 5.83885454e-05, -8.05950198e-08, 3.27447711e-11,
      1.15092468e+04, 8.42978067]
    - [7.62637466, 0.0172523403, -6.09184911e-06, 9.70800102e-10, -5.76169721e-14,
      9553.06395, -14.8325259]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.72
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H612
  composition: {C: 4, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.90828336, 0.0179025349, 2.61486503e-05, -4.81598832e-08, 2.11295844e-11,
      1.75928783e+04, 12.3118106]
    - [8.13872997, 0.0168655431, -5.97324908e-06, 9.54915173e-10, -5.67693708e-14,
      1.55467985e+04, -17.7959041]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H6-2
  composition: {C: 4, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.39211846, 2.98346178e-03, 5.22542032e-05, -6.64726627e-08, 2.56305331e-11,
      1.55148209e+04, 1.71080366]
    - [7.26055302, 0.0180160845, -6.47062409e-06, 1.04411453e-09, -6.2474125e-14,
      1.39644246e+04, -12.9484347]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H7
  composition: {C: 4, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.54746808, 4.6377146e-03, 6.61340221e-05, -8.97456502e-08, 3.61716165e-11,
      1.43843217e+04, 7.30313471]
    - [8.08107449, 0.0195526544, -6.93149115e-06, 1.10889183e-09, -6.5958441e-14,
      1.22822959e+04, -16.7137903]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.72
    well-depth: 357.1
    rotational-relaxation: 1.0
- name: IC4H7
  composition: {C: 4, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.38739541, 0.0206784631, 2.89299685e-05, -5.37553477e-08, 2.35670326e-11,
      1.47584145e+04, 15.5529104]
    - [8.34970451, 0.0192508033, -6.81360221e-06, 1.08484853e-09, -6.42422082e-14,
      1.24406647e+04, -18.7060633]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.65
    well-depth: 355.0
    rotational-relaxation: 1.0
- name: IC4H7-1
  composition: {C: 4, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 5000.0]
    data:
    - [0.912464579, 0.0388654394, -2.57575714e-05, 9.07760026e-09, -1.33946902e-12,
      2.63701284e+04, 20.8634918]
    - [5.04034802, 0.0273112013, -1.36251185e-05, 3.39697382e-09, -3.40445735e-13,
      2.5195565e+04, -0.519118835]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.176
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H81
  composition: {C: 4, H: 8}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.13226136, 5.33862838e-03, 6.0292896e-05, -7.60364685e-08, 2.87324693e-11,
      -2167.18358, 3.8293681]
    - [7.86795262, 0.0224448843, -8.07705438e-06, 1.30179988e-09, -7.77958472e-14,
      -4238.5334, -16.5662549]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.65
    well-depth: 355.0
    rotational-relaxation: 1.0
- name: C4H82
  composition: {C: 4, H: 8}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.57278967, 3.76541017e-03, 6.52226708e-05, -8.30909522e-08, 3.20311342e-11,
      -3601.28327, 1.15381671]
    - [7.89114667, 0.0224970532, -8.12143779e-06, 1.31273568e-09, -7.84451632e-14,
      -5516.43171, -17.0275827]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.65
    well-depth: 355.0
    rotational-relaxation: 1.0
- name: IC4H8
  composition: {C: 4, H: 8}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.3061234, 0.0133377057, 5.65726066e-05, -8.46898088e-08, 3.52403438e-11,
      -4041.28388, 9.92304633]
    - [8.94232121, 0.0212900129, -7.61851464e-06, 1.22641473e-09, -7.32634442e-14,
      -6672.92929, -24.6775148]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.65
    well-depth: 355.0
    rotational-relaxation: 1.0
- name: NC4H9
  composition: {C: 4, H: 9}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.73737837, 9.69051565e-03, 6.63846383e-05, -9.24799302e-08, 3.74006099e-11,
      7573.82332, 4.91063455]
    - [8.97401527, 0.0239704154, -8.48703645e-06, 1.35644127e-09, -8.06234913e-14,
      5191.61526, -23.1075609]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.24
    well-depth: 352.0
    rotational-relaxation: 1.0
- name: SC4H9
  composition: {C: 4, H: 9}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.42089393, -9.1214687e-04, 8.84998581e-05, -1.12115531e-07, 4.38222782e-11,
      6289.27311, 5.04210029]
    - [7.72287211, 0.0243427284, -8.65476475e-06, 1.38712529e-09, -8.26084187e-14,
      4150.04489, -14.3949625]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.24
    well-depth: 352.0
    rotational-relaxation: 1.0
- name: IC4H9
  composition: {C: 4, H: 9}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.34476784, 0.023186965, 3.2826104e-05, -5.96398514e-08, 2.5898082e-11,
      6662.012, 9.68860372]
    - [9.61250942, 0.0228581786, -8.06391309e-06, 1.28556553e-09, -7.62730799e-14,
      4152.18608, -26.6485099]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.24
    well-depth: 352.0
    rotational-relaxation: 1.0
- name: TC4H9
  composition: {C: 4, H: 9}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [6.45910754, -0.010201593, 1.06310577e-04, -1.2571703e-07, 4.75543216e-11,
      4434.20391, 1.30648608]
    - [6.7255739, 0.0253649194, -9.05306262e-06, 1.4547462e-09, -8.67934112e-14,
      2574.30692, -8.89920414]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.24
    well-depth: 352.0
    rotational-relaxation: 1.0
- name: C4H10
  composition: {C: 4, H: 10}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [6.14474013, 1.64500242e-04, 9.67848789e-05, -1.25486208e-07, 4.97846257e-11,
      -1.75989467e+04, -1.08058878]
    - [9.44547835, 0.025785662, -9.23613194e-06, 1.48631762e-09, -8.87891206e-14,
      -2.01383773e+04, -26.3477585]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.206
    well-depth: 350.9
    rotational-relaxation: 1.0
- name: IC4H10
  composition: {C: 4, H: 10}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.4547914, 8.26058864e-03, 8.29886433e-05, -1.14647616e-07, 4.64569994e-11,
      -1.84593929e+04, 4.92740653]
    - [9.76991697, 0.0254997141, -9.14142587e-06, 1.47328201e-09, -8.80799697e-14,
      -2.14052667e+04, -30.032967]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.208
    well-depth: 355.7
    rotational-relaxation: 1.0
- name: H2C4O
  composition: {C: 4, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 5000.0]
    data:
    - [3.18119, 0.029840752, -3.2832409e-05, 2.0631813e-08, -5.4200598e-12,
      2.4125576e+04, 9.42101]
    - [8.4292183, 0.010502701, -4.2066836e-06, 7.1184902e-10, -3.5796602e-14,
      2.2907807e+04, -16.511997]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: CH2CHCHCHO
  composition: {C: 4, H: 5, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1392.0, 5000.0]
    data:
    - [1.74191343, 0.0397229536, -3.20061901e-05, 1.38227925e-08, -2.46272017e-12,
      -664.4281, 17.0762023]
    - [12.5514754, 0.0122521948, -4.22382101e-06, 6.59184896e-10, -3.83818826e-14,
      -4253.49795, -40.2864145]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: CH3CHCHCO
  composition: {C: 4, H: 5, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [6.24331617, 9.70875403e-03, 3.13675787e-05, -4.51741386e-08, 1.80108189e-11,
      5629.06522, 1.70466029]
    - [9.18017936, 0.0157953829, -5.67758392e-06, 9.12744142e-10, -5.43932619e-14,
      4088.59688, -16.9925107]
  transport:
    model: gas
    geometry: linear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: CH3CHCHCHO
  composition: {C: 4, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.53926205, 0.0118589315, 4.70236194e-05, -6.91988732e-08, 2.82492887e-11,
      -1.44330048e+04, 6.10898503]
    - [9.52747356, 0.0186044436, -6.67091878e-06, 1.07555931e-09, -6.43292845e-14,
      -1.68016775e+04, -24.5930087]
  transport:
    model: gas
    geometry: linear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C3H7CHO
  composition: {C: 4, H: 8, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.30068149, 5.00213349e-03, 8.12219686e-05, -1.0781591e-07, 4.25781054e-11,
      -2.71198341e+04, 4.93592991]
    - [10.2351219, 0.0232201057, -8.46144199e-06, 1.37589764e-09, -8.27046434e-14,
      -3.00345804e+04, -28.2583105]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.009
    well-depth: 464.2
    rotational-relaxation: 1.0
- name: IC3H7CHO
  composition: {C: 4, H: 8, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1391.0, 5000.0]
    data:
    - [-0.273021382, 0.0489696307, -3.12770049e-05, 1.00052945e-08, -1.27512074e-12,
      -2.76054737e+04, 28.3451139]
    - [13.7501656, 0.0183126722, -6.28572629e-06, 9.78250756e-10, -5.68538653e-14,
      -3.26936771e+04, -47.7270548]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.352
    well-depth: 436.4
    rotational-relaxation: 1.0
- name: C2H5COCH3
  composition: {C: 4, H: 8, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [6.61978185, 8.51847835e-03, 5.10322077e-05, -6.58433042e-08, 2.49110484e-11,
      -3.15251691e+04, -1.09485469]
    - [9.29655016, 0.0229172746, -8.22048591e-06, 1.32404838e-09, -7.9175198e-14,
      -3.34442311e+04, -20.4993263]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.413
    well-depth: 454.0
    rotational-relaxation: 1.0
- name: C2H3COCH3
  composition: {C: 4, H: 6, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.98852451, 0.0204971182, 3.5624658e-05, -6.38395109e-08, 2.75663362e-11,
      -1.57565701e+04, 13.6212503]
    - [11.23444, 0.0166857869, -5.99141532e-06, 9.66147739e-10, -5.78333791e-14,
      -1.89013763e+04, -33.4159921]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.413
    well-depth: 454.0
    rotational-relaxation: 1.0
- name: OH*
  composition: {H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.46084428, 5.01872172e-04, -2.00254474e-06, 3.18901984e-09, -1.35451838e-12,
      5.07349466e+04, 1.73976415]
    - [2.7558292, 1.39848756e-03, -4.19428493e-07, 6.33453282e-11, -3.56042218e-15,
      5.09751756e+04, 5.62581429]
  transport:
    model: gas
    geometry: linear
    diameter: 2.75
    well-depth: 80.0
- name: CH*
  composition: {C: 1, H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.47250101, 4.26443626e-04, -1.95181794e-06, 3.51755043e-09, -1.60436174e-12,
      1.04334869e+05, 1.44799533]
    - [2.78220752, 1.47246754e-03, -4.63436227e-07, 7.32736021e-11, -4.19705404e-15,
      1.0454706e+05, 5.17421018]
  transport:
    model: gas
    geometry: linear
    diameter: 2.75
    well-depth: 80.0

reactions:
- equation: H + O2 <=> O + OH  # Reaction 1
  rate-constant: {A: 1.0399e+14, b: 0.0, Ea: 1.531e+04}
- equation: H2 + O <=> H + OH  # Reaction 2
  duplicate: true
  rate-constant: {A: 3.649e+12, b: 0.0, Ea: 7950.0}
- equation: H2 + O <=> H + OH  # Reaction 3
  duplicate: true
  rate-constant: {A: 7.6025e+14, b: 0.0, Ea: 1.918e+04}
- equation: H2 + OH <=> H + H2O  # Reaction 4
  rate-constant: {A: 2.1578e+08, b: 1.51, Ea: 3437.0}
- equation: 2 OH <=> H2O + O  # Reaction 5
  rate-constant: {A: 3.35e+04, b: 2.42, Ea: -1928.0}
- equation: H2 + M <=> 2 H + M  # Reaction 6
  type: three-body
  rate-constant: {A: 3.8767e+19, b: -1.4, Ea: 1.0439e+05}
  efficiencies: {AR: 0.0, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.9, CO2: 3.8,
    H2: 2.5, H2O: 12.0, HE: 0.0}
- equation: H2 + AR <=> 2 H + AR  # Reaction 7
  rate-constant: {A: 5.84e+18, b: -1.1, Ea: 1.0439e+05}
- equation: H2 + HE <=> 2 H + HE  # Reaction 8
  rate-constant: {A: 5.84e+18, b: -1.1, Ea: 1.0439e+05}
- equation: 2 O + M <=> O2 + M  # Reaction 9
  type: three-body
  rate-constant: {A: 6.16e+15, b: -0.5, Ea: 0.0}
  efficiencies: {AR: 0.0, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.9, CO2: 3.8,
    H2: 2.5, H2O: 12.0, HE: 0.0}
- equation: 2 O + AR <=> O2 + AR  # Reaction 10
  rate-constant: {A: 1.89e+13, b: 0.0, Ea: -1788.0}
- equation: 2 O + HE <=> O2 + HE  # Reaction 11
  rate-constant: {A: 1.89e+13, b: 0.0, Ea: -1788.0}
- equation: H + O + M <=> OH + M  # Reaction 12
  type: three-body
  rate-constant: {A: 4.7124e+18, b: -1.0, Ea: 0.0}
  efficiencies: {AR: 0.75, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.9, CO2: 3.8,
    H2: 2.5, H2O: 12.0, HE: 0.75}
- equation: H2O + M <=> H + OH + M  # Reaction 13
  type: three-body
  rate-constant: {A: 5.903e+27, b: -3.32, Ea: 1.208e+05}
  efficiencies: {AR: 1.0, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, C3H8: 4.0,
    CH2O: 2.5, CH3OH: 3.0, CH4: 7.0, CO: 1.9, CO2: 3.8, H2: 3.0, H2O: 0.0,
    HE: 1.1, N2: 2.0, O2: 1.5}
- equation: H2O + H2O <=> H + OH + H2O  # Reaction 14
  rate-constant: {A: 1.01e+26, b: -2.44, Ea: 1.202e+05}
- equation: H + O2 (+M) <=> HO2 (+M)  # Reaction 15
  type: falloff
  low-P-rate-constant: {A: 7.2417e+20, b: -1.72, Ea: 525.0}
  high-P-rate-constant: {A: 5.2863e+12, b: 0.44, Ea: 0.0}
  Troe: {A: 0.5, T3: 30.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.6867116639685282, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.9, CO2: 2.98148670778874,
    H2: 2.0, H2O: 13.76974842661546, HE: 0.8, N2: 1.0, O2: 0.78}
- equation: H + HO2 <=> H2 + O2  # Reaction 16
  rate-constant: {A: 3.2729e+06, b: 2.09, Ea: -1455.0}
- equation: H + HO2 <=> 2 OH  # Reaction 17
  rate-constant: {A: 6.36e+13, b: 0.0, Ea: 300.0}
- equation: H + HO2 <=> H2O + O  # Reaction 18
  rate-constant: {A: 1.6131e+12, b: 0.0, Ea: 0.0}
- equation: HO2 + O <=> O2 + OH  # Reaction 19
  rate-constant: {A: 1.7208e+13, b: 0.0, Ea: -445.0}
- equation: HO2 + OH <=> H2O + O2  # Reaction 20
  duplicate: true
  rate-constant: {A: 7.6368e+12, b: 0.0, Ea: -1093.0}
- equation: HO2 + OH <=> H2O + O2  # Reaction 21
  duplicate: true
  rate-constant: {A: 4.5e+14, b: 0.0, Ea: 1.093e+04}
- equation: 2 HO2 <=> H2O2 + O2  # Reaction 22
  duplicate: true
  rate-constant: {A: 1.94e+11, b: 0.0, Ea: -1409.0}
- equation: 2 HO2 <=> H2O2 + O2  # Reaction 23
  duplicate: true
  rate-constant: {A: 1.03e+14, b: 0.0, Ea: 1.104e+04}
- equation: H2O2 (+M) <=> 2 OH (+M)  # Reaction 24
  type: falloff
  low-P-rate-constant: {A: 2.3968e+24, b: -2.3, Ea: 4.875e+04}
  high-P-rate-constant: {A: 1.9252e+12, b: 0.9, Ea: 4.875e+04}
  Troe: {A: 0.58, T3: 30.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.9859595379900199, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 1.6, H2: 3.7, H2O: 7.5,
    H2O2: 7.7, HE: 0.65, N2: 1.5, O2: 1.2}
- equation: H + H2O2 <=> H2O + OH  # Reaction 25
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 3970.0}
- equation: H + H2O2 <=> H2 + HO2  # Reaction 26
  rate-constant: {A: 4.82e+13, b: 0.0, Ea: 7950.0}
- equation: H2O2 + O <=> HO2 + OH  # Reaction 27
  rate-constant: {A: 9.63e+06, b: 2.0, Ea: 3970.0}
- equation: H2O2 + OH <=> H2O + HO2  # Reaction 28
  duplicate: true
  rate-constant: {A: 1.7611e+12, b: 0.0, Ea: 318.0}
- equation: H2O2 + OH <=> H2O + HO2  # Reaction 29
  duplicate: true
  rate-constant: {A: 7.631e+13, b: 0.0, Ea: 7270.0}
- equation: CO + O (+M) <=> CO2 (+M)  # Reaction 30
  type: falloff
  low-P-rate-constant: {A: 1.5888e+21, b: -2.1, Ea: 5500.0}
  high-P-rate-constant: {A: 1.2029e+13, b: -0.31, Ea: 6943.0}
  efficiencies: {AR: 0.87, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.9, CO2: 3.8,
    H2: 2.5, H2O: 12.0}
- equation: CO + O2 <=> CO2 + O  # Reaction 31
  rate-constant: {A: 2.0406e+12, b: 0.0, Ea: 4.77e+04}
- equation: CO + OH <=> CO2 + H  # Reaction 32
  duplicate: true
  rate-constant: {A: 6.7547e+04, b: 2.05, Ea: -356.0}
- equation: CO + OH <=> CO2 + H  # Reaction 33
  duplicate: true
  rate-constant: {A: 5.2148e+12, b: -0.66, Ea: 332.0}
- equation: CO + HO2 <=> CO2 + OH  # Reaction 34
  rate-constant: {A: 1.57e+05, b: 2.18, Ea: 1.7944e+04}
- equation: HCO + M <=> CO + H + M  # Reaction 35
  type: three-body
  rate-constant: {A: 5.3789e+17, b: -1.2, Ea: 1.7734e+04}
  efficiencies: {AR: 0.9683651587783325, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0,
    C2H6: 3.0, C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5,
    CO2: 2.0, H2O: 12.0, HE: 1.0}
- equation: H + HCO <=> CO + H2  # Reaction 36
  rate-constant: {A: 8.9578e+13, b: 0.0, Ea: 0.0}
- equation: HCO + O <=> CO + OH  # Reaction 37
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HCO + O <=> CO2 + H  # Reaction 38
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HCO + OH <=> CO + H2O  # Reaction 39
  rate-constant: {A: 1.08e+14, b: 0.0, Ea: 0.0}
- equation: HCO + O2 <=> CO + HO2  # Reaction 40
  rate-constant: {A: 5.9024e+06, b: 1.9, Ea: -1370.0}
- equation: HCO + HO2 => CO2 + H + OH  # Reaction 41
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: C + OH <=> CO + H  # Reaction 42
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: C + O2 <=> CO + O  # Reaction 43
  rate-constant: {A: 6.62e+13, b: 0.0, Ea: 636.0}
- equation: CH + H <=> C + H2  # Reaction 44
  rate-constant: {A: 1.1e+14, b: 0.0, Ea: 0.0}
- equation: CH + O <=> CO + H  # Reaction 45
  rate-constant: {A: 5.7e+13, b: 0.0, Ea: 0.0}
- equation: CH + OH <=> H + HCO  # Reaction 46
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH + H2 <=> CH2 + H  # Reaction 47
  rate-constant: {A: 1.2429e+14, b: 0.0, Ea: 3320.0}
- equation: CH + H2 (+M) <=> CH3 (+M)  # Reaction 48
  type: falloff
  low-P-rate-constant: {A: 2.43e+22, b: -1.6, Ea: 0.0}
  high-P-rate-constant: {A: 5.13e+13, b: 0.15, Ea: 0.0}
  Troe: {A: 0.514, T3: 152.0, T1: 2.285e+04, T2: 1.035e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH + H2O <=> CH2O + H  # Reaction 49
  rate-constant: {A: 3.9563e+12, b: 0.0, Ea: -884.0}
- equation: CH + O2 <=> HCO + O  # Reaction 50
  rate-constant: {A: 1.84e+08, b: 1.43, Ea: 1200.0}
- equation: CH + O2 <=> CO2 + H  # Reaction 51
  rate-constant: {A: 2.77e+08, b: 1.43, Ea: 1200.0}
- equation: CH + O2 <=> CO + OH  # Reaction 52
  rate-constant: {A: 1.84e+08, b: 1.43, Ea: 1200.0}
- equation: CH + O2 => CO + H + O  # Reaction 53
  rate-constant: {A: 2.77e+08, b: 1.43, Ea: 1200.0}
- equation: CH + CO (+M) <=> HCCO (+M)  # Reaction 54
  type: falloff
  low-P-rate-constant: {A: 3.26e+24, b: -2.5, Ea: 0.0}
  high-P-rate-constant: {A: 1.02e+15, b: -0.4, Ea: 0.0}
  Troe: {A: 0.4, T3: 30.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH + CO2 <=> CO + HCO  # Reaction 55
  rate-constant: {A: 6.38e+07, b: 1.51, Ea: -715.0}
- equation: CH2 + H (+M) <=> CH3 (+M)  # Reaction 56
  type: falloff
  low-P-rate-constant: {A: 1.39e+34, b: -5.04, Ea: 7400.0}
  high-P-rate-constant: {A: 2.13e+13, b: 0.32, Ea: 0.0}
  Troe: {A: 0.405, T3: 258.0, T1: 2811.0, T2: 9908.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH2 + O => CO + 2 H  # Reaction 57
  rate-constant: {A: 8.7587e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + OH <=> CH2O + H  # Reaction 58
  rate-constant: {A: 3.3016e+13, b: 0.12, Ea: -162.0}
- equation: CH2 + OH <=> CH + H2O  # Reaction 59
  rate-constant: {A: 8.63e+05, b: 2.02, Ea: 6776.0}
- equation: CH2 + HO2 <=> CH2O + OH  # Reaction 60
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + H2 <=> CH3 + H  # Reaction 61
  rate-constant: {A: 3.7908e+05, b: 2.3, Ea: 7351.0}
- equation: CH2 + O2 => CO + H + OH  # Reaction 62
  rate-constant: {A: 2.516e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 => CO2 + 2 H  # Reaction 63
  rate-constant: {A: 1.6707e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CH2O + O  # Reaction 64
  rate-constant: {A: 1.57e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CO2 + H2  # Reaction 65
  rate-constant: {A: 1.83e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CO + H2O  # Reaction 66
  rate-constant: {A: 5.2e+11, b: 0.0, Ea: 1000.0}
- equation: C + CH2 <=> C2H + H  # Reaction 67
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: CH + CH2 <=> C2H2 + H  # Reaction 68
  rate-constant: {A: 4.0e+13, b: 0.0, Ea: 0.0}
- equation: 2 CH2 => C2H2 + 2 H  # Reaction 69
  rate-constant: {A: 2.0e+14, b: 0.0, Ea: 1.0989e+04}
- equation: 2 CH2 <=> H2 + H2CC  # Reaction 70
  rate-constant: {A: 1.6e+15, b: 0.0, Ea: 1.1944e+04}
- equation: CH2(S) + N2 <=> CH2 + N2  # Reaction 71
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 471.0}
- equation: AR + CH2(S) <=> AR + CH2  # Reaction 72
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 600.0}
- equation: CH2(S) + HE <=> CH2 + HE  # Reaction 73
  rate-constant: {A: 6.62e+12, b: 0.0, Ea: 755.0}
- equation: CH2(S) + H <=> CH + H2  # Reaction 74
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + O => CO + 2 H  # Reaction 75
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + OH <=> CH2O + H  # Reaction 76
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + H2 <=> CH3 + H  # Reaction 77
  rate-constant: {A: 6.8e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + O2 <=> CH2 + O2  # Reaction 78
  rate-constant: {A: 3.13e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + H2O (+M) <=> CH3OH (+M)  # Reaction 79
  type: falloff
  low-P-rate-constant: {A: 1.734e+41, b: -7.19, Ea: 5777.0}
  high-P-rate-constant: {A: 3.0345e+12, b: 0.05, Ea: -1897.0}
  Troe: {A: 0.992, T3: 943.0, T1: 4.731e+04, T2: 4.711e+04}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH2(S) + H2O <=> CH2 + H2O  # Reaction 80
  rate-constant: {A: 1.51e+13, b: 0.0, Ea: -431.0}
- equation: CH2(S) + H2O <=> CH2O + H2  # Reaction 81
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.36e+22, b: -3.33, Ea: 3950.0}
  - {P: 1.0 atm, A: 4.8e+23, b: -3.63, Ea: 5220.0}
  - {P: 3.0 atm, A: 6.85e+23, b: -3.66, Ea: 5820.0}
  - {P: 10.0 atm, A: 1.53e+24, b: -3.73, Ea: 6820.0}
  - {P: 30.0 atm, A: 8.75e+23, b: -3.62, Ea: 7655.0}
  - {P: 100.0 atm, A: 1.27e+22, b: -3.06, Ea: 7950.0}
- equation: CH2(S) + H2O2 <=> CH3O + OH  # Reaction 82
  rate-constant: {A: 1.29e+14, b: -0.14, Ea: 0.0}
- equation: CH2(S) + CO <=> CH2 + CO  # Reaction 83
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CO2 <=> CH2 + CO2  # Reaction 84
  rate-constant: {A: 1.33e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CO2 <=> CH2O + CO  # Reaction 85
  rate-constant: {A: 6.62e+12, b: 0.0, Ea: 0.0}
- equation: H + HCO (+M) <=> CH2O (+M)  # Reaction 86
  type: falloff
  low-P-rate-constant: {A: 4.0439e+34, b: -5.53, Ea: 6128.0}
  high-P-rate-constant: {A: 1.7951e+14, b: -0.03, Ea: -142.0}
  Troe: {A: 0.782, T3: 271.0, T1: 2755.0, T2: 6570.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH2O (+M) <=> CO + H2 (+M)  # Reaction 87
  type: falloff
  low-P-rate-constant: {A: 4.4e+38, b: -6.1, Ea: 9.4e+04}
  high-P-rate-constant: {A: 3.7e+13, b: 0.0, Ea: 7.198e+04}
  Troe: {A: 0.932, T3: 197.0, T1: 1540.0, T2: 1.03e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH2O + H <=> H2 + HCO  # Reaction 88
  rate-constant: {A: 5.3963e+12, b: 0.36, Ea: 4609.0}
- equation: CH2O + H => CO + H2 + H  # Reaction 89
  rate-constant: {A: 1.7316e+13, b: 0.58, Ea: 1.4395e+04}
- equation: CH2O + O <=> HCO + OH  # Reaction 90
  rate-constant: {A: 7.2986e+15, b: -0.697, Ea: 5201.8}
- equation: CH2O + O => CO + H + OH  # Reaction 91
  rate-constant: {A: 2.7101e+21, b: -1.903, Ea: 2.2676e+04}
- equation: CH2O + OH <=> H2O + HCO  # Reaction 92
  rate-constant: {A: 1.2126e+10, b: 0.975, Ea: 24.66}
- equation: CH2O + OH => CO + H + H2O  # Reaction 93
  rate-constant: {A: 4.0551e+11, b: 0.692, Ea: 9370.9}
- equation: CH2O + O2 <=> HCO + HO2  # Reaction 94
  rate-constant: {A: 3.149e+05, b: 2.5, Ea: 3.646e+04}
- equation: CH2O + HO2 <=> H2O2 + HCO  # Reaction 95
  rate-constant: {A: 4.9957e+04, b: 2.5, Ea: 1.021e+04}
- equation: CH + CH2O <=> CH2CO + H  # Reaction 96
  rate-constant: {A: 9.64e+13, b: 0.0, Ea: -517.0}
- equation: CH2 + CH2O <=> CH3 + HCO  # Reaction 97
  rate-constant: {A: 0.074, b: 4.21, Ea: 1120.0}
- equation: CH2(S) + CH2O <=> CH3 + HCO  # Reaction 98
  rate-constant: {A: 1.33e+13, b: 0.0, Ea: -550.0}
- equation: C2H + CH2O <=> C2H2 + HCO  # Reaction 99
  rate-constant: {A: 5400.0, b: 2.81, Ea: 5862.0}
- equation: C2H3 + CH2O <=> C2H4 + HCO  # Reaction 100
  rate-constant: {A: 5400.0, b: 2.81, Ea: 5862.0}
- equation: CH3 + H (+M) <=> CH4 (+M)  # Reaction 101
  type: falloff
  low-P-rate-constant: {A: 1.2779e+36, b: -5.57, Ea: 3818.0}
  high-P-rate-constant: {A: 2.1231e+14, b: 0.0, Ea: 0.0}
  Troe: {A: 0.37, T3: 3315.0, T1: 61.0, T2: 9.0e+04}
  efficiencies: {AR: 0.7411522103103376, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0,
    C2H6: 3.0, C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5,
    CO2: 2.0, H2: 2.0, H2O: 5.56253976195153, HE: 0.7}
- equation: CH3 + O <=> CH2O + H  # Reaction 102
  rate-constant: {A: 5.7625e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + O => CO + H + H2  # Reaction 103
  rate-constant: {A: 2.31e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + OH (+M) <=> CH3OH (+M)  # Reaction 104
  type: falloff
  low-P-rate-constant: {A: 7.24e+36, b: -6.0, Ea: 3226.0}
  high-P-rate-constant: {A: 6.21e+13, b: -0.02, Ea: -33.0}
  Troe: {A: 0.185, T3: 156.0, T1: 1675.0, T2: 4530.0}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH3 + OH <=> CH2 + H2O  # Reaction 105
  rate-constant: {A: 4.29e+04, b: 2.57, Ea: 3998.0}
- equation: CH3 + OH <=> CH2(S) + H2O  # Reaction 106
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 5.1997e+16, b: -1.12, Ea: 1620.0}
  - {P: 1.0 atm, A: 8.691e+16, b: -1.16, Ea: 2765.0}
  - {P: 3.0 atm, A: 1.0622e+16, b: -0.87, Ea: 3100.0}
  - {P: 10.0 atm, A: 1.4856e+14, b: -0.31, Ea: 3170.0}
  - {P: 30.0 atm, A: 4.1004e+11, b: 0.44, Ea: 2880.0}
  - {P: 100.0 atm, A: 7.2871e+10, b: 0.66, Ea: 3793.0}
- equation: CH3 + OH <=> CH2O + H2  # Reaction 107
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.9441e+11, b: 0.14, Ea: -483.0}
  - {P: 1.0 atm, A: 1.439e+13, b: -0.27, Ea: 1284.0}
  - {P: 3.0 atm, A: 8.9754e+13, b: -0.47, Ea: 2446.0}
  - {P: 10.0 atm, A: 1.6309e+14, b: -0.51, Ea: 3615.0}
  - {P: 30.0 atm, A: 1.066e+13, b: -0.14, Ea: 4100.0}
  - {P: 100.0 atm, A: 1.9614e+10, b: 0.68, Ea: 3960.0}
- equation: CH3 + HO2 <=> CH4 + O2  # Reaction 108
  rate-constant: {A: 8.4356e+04, b: 2.23, Ea: -3022.0}
- equation: CH3 + HO2 <=> CH3O + OH  # Reaction 109
  rate-constant: {A: 7.619e+12, b: 0.0, Ea: -590.0}
- equation: CH3 + O2 <=> CH3O + O  # Reaction 110
  rate-constant: {A: 8.2587e+12, b: 0.0, Ea: 2.8297e+04}
- equation: CH3 + O2 <=> CH2O + OH  # Reaction 111
  rate-constant: {A: 117.18, b: 2.86, Ea: 9768.0}
- equation: C + CH3 <=> C2H2 + H  # Reaction 112
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: CH + CH3 <=> C2H3 + H  # Reaction 113
  rate-constant: {A: 3.7169e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + CH3 <=> C2H4 + H  # Reaction 114
  rate-constant: {A: 1.127e+14, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CH3 <=> C2H4 + H  # Reaction 115
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: -497.0}
- equation: 2 CH3 (+M) <=> C2H6 (+M)  # Reaction 116
  type: falloff
  low-P-rate-constant: {A: 1.7034e+50, b: -9.67, Ea: 6220.0}
  high-P-rate-constant: {A: 2.0402e+16, b: -0.97, Ea: 620.0}
  Troe: {A: 0.532, T3: 151.0, T1: 1038.0, T2: 4970.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: 2 CH3 <=> C2H5 + H  # Reaction 117
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 9.3694e+12, b: 0.07, Ea: 1.1135e+04}
  - {P: 1.0 atm, A: 3.1455e+12, b: 0.23, Ea: 1.2e+04}
  - {P: 3.0 atm, A: 1.7534e+11, b: 0.6, Ea: 1.22e+04}
  - {P: 10.0 atm, A: 7.1342e+08, b: 1.29, Ea: 1.2e+04}
  - {P: 30.0 atm, A: 7.2814e+05, b: 2.19, Ea: 1.14e+04}
  - {P: 100.0 atm, A: 133.85, b: 3.18, Ea: 1.05e+04}
- equation: CH3 + HCO <=> CH4 + CO  # Reaction 118
  rate-constant: {A: 2.62e+13, b: 0.0, Ea: 0.0}
- equation: CH2O + CH3 <=> CH4 + HCO  # Reaction 119
  rate-constant: {A: 34.78, b: 3.36, Ea: 4310.0}
- equation: CH3O (+M) <=> CH2O + H (+M)  # Reaction 120
  type: falloff
  low-P-rate-constant: {A: 6.02e+16, b: -0.55, Ea: 1.802e+04}
  high-P-rate-constant: {A: 1.13e+10, b: 1.21, Ea: 2.408e+04}
  Troe: {A: 0.341, T3: 28.0, T1: 1000.0, T2: 2339.0}
  efficiencies: {AR: 0.85, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.67}
- equation: CH3O + H (+M) <=> CH3OH (+M)  # Reaction 121
  type: falloff
  low-P-rate-constant: {A: 6.7e+40, b: -7.38, Ea: 9177.0}
  high-P-rate-constant: {A: 2.44e+11, b: 0.76, Ea: 0.0}
  Troe: {A: 0.684, T3: 3.705e+04, T1: 4.149e+04, T2: 3980.0}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH3O + H <=> CH2OH + H  # Reaction 122
  rate-constant: {A: 1.29e+07, b: 1.82, Ea: -703.0}
- equation: CH3O + H <=> CH2O + H2  # Reaction 123
  rate-constant: {A: 3.79e+13, b: 0.0, Ea: 596.0}
- equation: CH3O + H <=> CH3 + OH  # Reaction 124
  rate-constant: {A: 3.88e+14, b: -0.26, Ea: -26.0}
- equation: CH3O + H <=> CH2(S) + H2O  # Reaction 125
  rate-constant: {A: 1.97e+11, b: 0.41, Ea: 243.0}
- equation: CH3O + O <=> CH2O + OH  # Reaction 126
  rate-constant: {A: 3.78e+12, b: 0.0, Ea: 0.0}
- equation: CH3O + OH <=> CH2O + H2O  # Reaction 127
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: CH3O + HO2 <=> CH2O + H2O2  # Reaction 128
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: CH3O + HO2 <=> CH3OH + O2  # Reaction 129
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: CH3O + O2 <=> CH2O + HO2  # Reaction 130
  rate-constant: {A: 6.32e+10, b: 0.0, Ea: 2603.0}
- equation: CH3 + CH3O <=> CH2O + CH4  # Reaction 131
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: CH3O + CO <=> CH3 + CO2  # Reaction 132
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 1.1e+04}
- equation: CH2OH (+M) <=> CH2O + H (+M)  # Reaction 133
  type: falloff
  low-P-rate-constant: {A: 3.0577e+13, b: 0.18, Ea: 1.723e+04}
  high-P-rate-constant: {A: 7.4868e+10, b: 0.81, Ea: 3.958e+04}
  Troe: {A: 1.0e-03, T3: 50.0, T1: 600.0, T2: 2780.0}
  efficiencies: {AR: 0.85, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.67}
- equation: CH2OH + H (+M) <=> CH3OH (+M)  # Reaction 134
  type: falloff
  low-P-rate-constant: {A: 1.34e+41, b: -7.38, Ea: 9177.0}
  high-P-rate-constant: {A: 6.67e+10, b: 0.96, Ea: 0.0}
  Troe: {A: 0.684, T3: 3.705e+04, T1: 4.149e+04, T2: 3980.0}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH2OH + H <=> CH2O + H2  # Reaction 135
  rate-constant: {A: 2.44e+13, b: 0.0, Ea: 0.0}
- equation: CH2OH + H <=> CH3 + OH  # Reaction 136
  rate-constant: {A: 1.9176e+13, b: 0.2, Ea: -241.0}
- equation: CH2OH + H <=> CH2(S) + H2O  # Reaction 137
  rate-constant: {A: 1.28e+11, b: 0.52, Ea: 215.0}
- equation: CH2OH + O <=> CH2O + OH  # Reaction 138
  rate-constant: {A: 9.03e+13, b: 0.0, Ea: 0.0}
- equation: CH2OH + OH <=> CH2O + H2O  # Reaction 139
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: CH2OH + HO2 <=> CH2O + H2O2  # Reaction 140
  rate-constant: {A: 1.21e+13, b: 0.0, Ea: 0.0}
- equation: CH2OH + O2 <=> CH2O + HO2  # Reaction 141
  rate-constant: {A: 7.23e+13, b: 0.0, Ea: 3736.0}
- equation: CH2OH + CH3 <=> CH2O + CH4  # Reaction 142
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: CH4 + H <=> CH3 + H2  # Reaction 143
  rate-constant: {A: 6.9485e+05, b: 2.5, Ea: 9588.0}
- equation: CH4 + O <=> CH3 + OH  # Reaction 144
  rate-constant: {A: 6.93e+08, b: 1.56, Ea: 8485.0}
- equation: CH4 + OH <=> CH3 + H2O  # Reaction 145
  rate-constant: {A: 1.0e+06, b: 2.18, Ea: 2446.0}
- equation: CH4 + HO2 <=> CH3 + H2O2  # Reaction 146
  rate-constant: {A: 3.9686e+04, b: 2.5, Ea: 2.1e+04}
- equation: CH + CH4 <=> C2H4 + H  # Reaction 147
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: -397.0}
- equation: CH2 + CH4 <=> 2 CH3  # Reaction 148
  rate-constant: {A: 2.46e+06, b: 2.0, Ea: 8270.0}
- equation: CH2(S) + CH4 <=> 2 CH3  # Reaction 149
  rate-constant: {A: 1.87e+13, b: 0.0, Ea: -497.0}
- equation: C2H + CH4 <=> C2H2 + CH3  # Reaction 150
  rate-constant: {A: 1.3e+13, b: 0.0, Ea: 600.0}
- equation: CH3OH + H <=> CH2OH + H2  # Reaction 151
  rate-constant: {A: 2.0965e+06, b: 2.35, Ea: 5912.0}
- equation: CH3OH + H <=> CH3O + H2  # Reaction 152
  rate-constant: {A: 5.1302e+06, b: 2.15, Ea: 1.1134e+04}
- equation: CH3OH + O <=> CH2OH + OH  # Reaction 153
  rate-constant: {A: 2.47e+13, b: 0.0, Ea: 5306.0}
- equation: CH3OH + O <=> CH3O + OH  # Reaction 154
  rate-constant: {A: 8.2e+12, b: 0.0, Ea: 9040.0}
- equation: CH3OH + OH <=> CH2OH + H2O  # Reaction 155
  rate-constant: {A: 1.42e+05, b: 2.37, Ea: -965.2}
- equation: CH3OH + OH <=> CH3O + H2O  # Reaction 156
  rate-constant: {A: 1.5076e+04, b: 2.7, Ea: 53.3}
- equation: CH3OH + O2 <=> CH2OH + HO2  # Reaction 157
  rate-constant: {A: 3.9681e+05, b: 2.27, Ea: 4.276e+04}
- equation: CH3OH + HO2 <=> CH2OH + H2O2  # Reaction 158
  rate-constant: {A: 5.8074e-05, b: 5.16, Ea: 1.016e+04}
- equation: CH3OH + HO2 <=> CH3O + H2O2  # Reaction 159
  rate-constant: {A: 0.288, b: 4.03, Ea: 1.817e+04}
- equation: CH + CH3OH <=> CH2O + CH3  # Reaction 160
  rate-constant: {A: 9.04e+18, b: -1.93, Ea: 0.0}
- equation: CH2 + CH3OH <=> CH2OH + CH3  # Reaction 161
  rate-constant: {A: 3.54e-04, b: 4.19, Ea: 3600.0}
- equation: CH2 + CH3OH <=> CH3 + CH3O  # Reaction 162
  rate-constant: {A: 1.37e-04, b: 4.26, Ea: 5630.0}
- equation: CH2(S) + CH3OH <=> CH3 + CH3O  # Reaction 163
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -550.0}
- equation: CH2(S) + CH3OH <=> CH2OH + CH3  # Reaction 164
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: -550.0}
- equation: CH3 + CH3OH <=> CH2OH + CH4  # Reaction 165
  rate-constant: {A: 332.0, b: 3.03, Ea: 8720.0}
- equation: CH3 + CH3OH <=> CH3O + CH4  # Reaction 166
  rate-constant: {A: 1.07e+04, b: 2.27, Ea: 8710.0}
- equation: C2H + CH3OH <=> C2H2 + CH2OH  # Reaction 167
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 0.0}
- equation: C2H + CH3OH <=> C2H2 + CH3O  # Reaction 168
  rate-constant: {A: 1.2e+12, b: 0.0, Ea: 0.0}
- equation: C2H3 + CH3OH <=> C2H4 + CH2OH  # Reaction 169
  rate-constant: {A: 32.0, b: 3.2, Ea: 7175.0}
- equation: C2H3 + CH3OH <=> C2H4 + CH3O  # Reaction 170
  rate-constant: {A: 14.5, b: 3.1, Ea: 6940.0}
- equation: CH3 + O2 (+M) <=> CH3O2 (+M)  # Reaction 171
  type: falloff
  low-P-rate-constant: {A: 5.8e+25, b: -3.3, Ea: 0.0}
  high-P-rate-constant: {A: 7.83e+08, b: 1.2, Ea: 0.0}
  Troe: {A: 0.487, T3: 30.0, T1: 2594.0, T2: 6266.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: 2 CH3O2 => 2 CH3O + O2  # Reaction 172
  rate-constant: {A: 5.38e+13, b: -0.89, Ea: 863.0}
- equation: 2 CH3O2 => CH2O + CH3OH + O2  # Reaction 173
  rate-constant: {A: 1.11e+11, b: -0.49, Ea: -1768.0}
- equation: CH3OOH (+M) <=> CH3O + OH (+M)  # Reaction 174
  type: falloff
  low-P-rate-constant: {A: 3.89e+42, b: -7.5, Ea: 4.676e+04}
  high-P-rate-constant: {A: 4.05e+19, b: -1.15, Ea: 4.426e+04}
  Troe: {A: 0.838, T3: 3.656e+04, T1: 499.0, T2: 9990.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH3O2 + H <=> CH3O + OH  # Reaction 175
  rate-constant: {A: 9.64e+13, b: 0.0, Ea: 0.0}
- equation: CH3O2 + O <=> CH3O + O2  # Reaction 176
  rate-constant: {A: 1.22e+13, b: 0.0, Ea: -445.0}
- equation: CH3O2 + OH <=> CH3O + HO2  # Reaction 177
  rate-constant: {A: 5.11e+15, b: -0.81, Ea: 0.0}
- equation: CH3O2 + O2 => CO + H2O + HO2  # Reaction 178
  rate-constant: {A: 467.0, b: 2.9, Ea: 4.147e+04}
- equation: CH3O2 + O2 => CH2O + OH + O2  # Reaction 179
  rate-constant: {A: 1.9747e+13, b: 0.0, Ea: 1.742e+04}
- equation: CH3O2 + HO2 <=> CH3OOH + O2  # Reaction 180
  rate-constant: {A: 2.28e+11, b: 0.0, Ea: -1490.0}
- equation: CH3O2 + HO2 => CH2O + H2O + O2  # Reaction 181
  rate-constant: {A: 2.53e+10, b: 0.0, Ea: -1490.0}
- equation: CH3O2 + CO <=> CH3O + CO2  # Reaction 182
  rate-constant: {A: 1.57e+05, b: 2.18, Ea: 1.794e+04}
- equation: CH3 + CH3O2 <=> 2 CH3O  # Reaction 183
  rate-constant: {A: 4.7253e+12, b: 0.0, Ea: -1410.0}
- equation: CH3O2 + CH4 <=> CH3 + CH3OOH  # Reaction 184
  rate-constant: {A: 1.81e+11, b: 0.0, Ea: 1.848e+04}
- equation: C2H3 + CH3O2 <=> C2H2 + CH3OOH  # Reaction 185
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: C2H3 + CH3O2 <=> CH2CHO + CH3O  # Reaction 186
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: C2H4 + CH3O2 <=> C2H4O + CH3O  # Reaction 187
  rate-constant: {A: 3.79e+12, b: 0.0, Ea: 1.7865e+04}
- equation: CH3OOH + H <=> CH3O2 + H2  # Reaction 188
  rate-constant: {A: 8.77e+10, b: 0.0, Ea: 1860.0}
- equation: CH3OOH + H <=> CH3O + H2O  # Reaction 189
  rate-constant: {A: 7.25e+10, b: 0.0, Ea: 1860.0}
- equation: CH3OOH + H => CH2O + H2 + OH  # Reaction 190
  rate-constant: {A: 8.43e+09, b: 0.0, Ea: 1860.0}
- equation: CH3OOH + O <=> CH3O2 + OH  # Reaction 191
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 4890.0}
- equation: CH3OOH + O => CH2O + 2 OH  # Reaction 192
  rate-constant: {A: 2.27e+13, b: 0.0, Ea: 4890.0}
- equation: CH3OOH + O2 => CH2O + HO2 + OH  # Reaction 193
  rate-constant: {A: 3.58e+05, b: 2.27, Ea: 4.276e+04}
- equation: CH3OOH + OH <=> CH3O2 + H2O  # Reaction 194
  rate-constant: {A: 1.07e+12, b: 0.0, Ea: -437.0}
- equation: CH3OOH + OH => CH2O + H2O + OH  # Reaction 195
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: -258.0}
- equation: CH3OOH + HO2 <=> CH3O2 + H2O2  # Reaction 196
  rate-constant: {A: 4.11e+04, b: 2.5, Ea: 1.0206e+04}
- equation: CH3 + CH3OOH => CH2O + CH4 + OH  # Reaction 197
  rate-constant: {A: 332.0, b: 3.03, Ea: 8720.0}
- equation: C2H + O <=> CH + CO  # Reaction 198
  rate-constant: {A: 5.4e+13, b: 0.0, Ea: 0.0}
- equation: C2H + O2 <=> CO + HCO  # Reaction 199
  rate-constant: {A: 1.63e+14, b: -0.35, Ea: 0.0}
- equation: H + HCCO <=> CH2(S) + CO  # Reaction 200
  rate-constant: {A: 1.32e+14, b: 0.0, Ea: 0.0}
- equation: C2H + OH <=> H + HCCO  # Reaction 201
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: HCCO + O => 2 CO + H  # Reaction 202
  rate-constant: {A: 1.73e+14, b: -0.11, Ea: 0.0}
- equation: HCCO + O <=> CH + CO2  # Reaction 203
  rate-constant: {A: 2.95e+13, b: 0.0, Ea: 1113.0}
- equation: HCCO + O2 => CO + CO2 + H  # Reaction 204
  rate-constant: {A: 2.1074e+12, b: 0.0, Ea: 854.0}
- equation: HCCO + OH => CH2O + CO  # Reaction 205
  rate-constant: {A: 1.2316e+16, b: -0.59, Ea: 145.0}
- equation: HCCO + OH => CO + H + HCO  # Reaction 206
  rate-constant: {A: 5.6978e+13, b: 0.13, Ea: -215.0}
- equation: CH + HCCO <=> C2H2 + CO  # Reaction 207
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + HCCO <=> C2H3 + CO  # Reaction 208
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: 2 HCCO => C2H2 + 2 CO  # Reaction 209
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H2 (+M) <=> H2CC (+M)  # Reaction 210
  type: falloff
  low-P-rate-constant: {A: 3.0795e+15, b: -0.64, Ea: 4.97e+04}
  high-P-rate-constant: {A: 1.0055e+15, b: -0.52, Ea: 5.075e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H + H2 <=> C2H2 + H  # Reaction 211
  rate-constant: {A: 1.9438e+06, b: 2.32, Ea: 882.0}
- equation: C2H + H (+M) <=> C2H2 (+M)  # Reaction 212
  type: falloff
  low-P-rate-constant: {A: 3.75e+33, b: -4.8, Ea: 1900.0}
  high-P-rate-constant: {A: 2.25e+13, b: 0.32, Ea: 0.0}
  Troe: {A: 0.646, T3: 13.2, T1: 1315.0, T2: 5566.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H2 + O <=> H + HCCO  # Reaction 213
  rate-constant: {A: 9.6504e+08, b: 1.4, Ea: 2206.0}
- equation: C2H2 + O <=> CH2 + CO  # Reaction 214
  rate-constant: {A: 1.9961e+08, b: 1.4, Ea: 2206.0}
- equation: C2H2 + OH <=> CH2CO + H  # Reaction 215
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.025 atm, A: 1.7405e+04, b: 2.28, Ea: -292.0}
  - {P: 0.1 atm, A: 3.4581e+05, b: 1.92, Ea: 598.0}
  - {P: 1.0 atm, A: 8.6222e+06, b: 1.55, Ea: 2106.0}
  - {P: 10.0 atm, A: 5.8398e+06, b: 1.65, Ea: 3400.0}
  - {P: 100.0 atm, A: 1.6718e+04, b: 2.45, Ea: 4477.0}
- equation: C2H2 + OH <=> C2H + H2O  # Reaction 216
  rate-constant: {A: 2.63e+06, b: 2.14, Ea: 1.706e+04}
- equation: C2H2 + OH <=> CH3 + CO  # Reaction 217
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.025 atm, A: 4.37e+06, b: 1.4, Ea: 227.0}
  - {P: 0.1 atm, A: 7.65e+07, b: 1.05, Ea: 1115.0}
  - {P: 1.0 atm, A: 1.28e+09, b: 0.73, Ea: 2580.0}
  - {P: 10.0 atm, A: 4.31e+08, b: 0.92, Ea: 3736.0}
  - {P: 100.0 atm, A: 8.25e+05, b: 1.77, Ea: 4700.0}
- equation: C2H2 + HO2 <=> CH2CO + OH  # Reaction 218
  rate-constant: {A: 7.75e+06, b: 1.6, Ea: 1.53e+04}
- equation: C2H2 + HO2 => H + HCCO + OH  # Reaction 219
  rate-constant: {A: 2.1672e+07, b: 1.6, Ea: 1.53e+04}
- equation: H + H2CC <=> C2H2 + H  # Reaction 220
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: H2CC + OH <=> CH2CO + H  # Reaction 221
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: H2CC + O2 <=> 2 HCO  # Reaction 222
  rate-constant: {A: 6.0722e+12, b: 0.0, Ea: 0.0}
- equation: CH2 + CO (+M) <=> CH2CO (+M)  # Reaction 223
  type: falloff
  low-P-rate-constant: {A: 2.9246e+33, b: -5.11, Ea: 7095.0}
  high-P-rate-constant: {A: 8.8063e+11, b: 0.5, Ea: 4510.0}
  Troe: {A: 0.591, T3: 275.0, T1: 1226.0, T2: 5185.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH2CO + H <=> H2 + HCCO  # Reaction 224
  rate-constant: {A: 4.2e+07, b: 1.9, Ea: 1.185e+04}
- equation: CH2CO + H <=> CH3 + CO  # Reaction 225
  rate-constant: {A: 6.4437e+08, b: 1.45, Ea: 2780.0}
- equation: CH2CO + O <=> HCCO + OH  # Reaction 226
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 1.03e+04}
- equation: CH2CO + O <=> CH2 + CO2  # Reaction 227
  rate-constant: {A: 1.08e+12, b: 0.0, Ea: 1351.0}
- equation: CH2CO + O <=> 2 HCO  # Reaction 228
  rate-constant: {A: 3.61e+11, b: 0.0, Ea: 1351.0}
- equation: CH2CO + O <=> CH2O + CO  # Reaction 229
  rate-constant: {A: 3.2638e+11, b: 0.0, Ea: 1351.0}
- equation: CH2CO + OH <=> H2O + HCCO  # Reaction 230
  rate-constant: {A: 1.4854e+04, b: 2.74, Ea: 2220.0}
- equation: CH2CO + OH <=> CH3 + CO2  # Reaction 231
  rate-constant: {A: 6.2568e+11, b: 0.0, Ea: -1013.0}
- equation: CH2CO + OH <=> CH2OH + CO  # Reaction 232
  rate-constant: {A: 1.8261e+12, b: 0.0, Ea: -1013.0}
- equation: CH + CH2CO <=> C2H3 + CO  # Reaction 233
  rate-constant: {A: 1.45e+14, b: 0.0, Ea: 0.0}
- equation: C2H2 + H (+M) <=> C2H3 (+M)  # Reaction 234
  type: falloff
  low-P-rate-constant: {A: 2.7551e+27, b: -3.38, Ea: 847.0}
  high-P-rate-constant: {A: 4.2047e+08, b: 1.64, Ea: 2096.0}
  Troe: {A: 0.215, T3: 10.7, T1: 1043.0, T2: 2341.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H3 + H <=> C2H2 + H2  # Reaction 235
  rate-constant: {A: 1.21e+12, b: 0.0, Ea: 0.0}
- equation: C2H3 + H <=> H2 + H2CC  # Reaction 236
  rate-constant: {A: 6.9378e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + O <=> CH2CO + H  # Reaction 237
  rate-constant: {A: 3.3016e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> C2H2 + H2O  # Reaction 238
  rate-constant: {A: 2.2672e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> CH3 + HCO  # Reaction 239
  rate-constant: {A: 1.7585e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> CH3CO + H  # Reaction 240
  rate-constant: {A: 1.14e+12, b: 0.0, Ea: 1400.0}
- equation: C2H3 + OH <=> CH2CHO + H  # Reaction 241
  rate-constant: {A: 4.18e+13, b: 0.0, Ea: 2870.0}
- equation: C2H3 + OH <=> CH4 + CO  # Reaction 242
  rate-constant: {A: 2.86e+11, b: 0.0, Ea: 1120.0}
- equation: C2H3 + O2 <=> CH2CHO + O  # Reaction 243
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.5283e+11, b: 0.32, Ea: 360.0}
  - {P: 1.0 atm, A: 1.1147e+12, b: 0.08, Ea: 1020.0}
  - {P: 3.16 atm, A: 2.5351e+12, b: -0.02, Ea: 1530.0}
  - {P: 10.0 atm, A: 9.7089e+12, b: -0.16, Ea: 2460.0}
  - {P: 31.6 atm, A: 7.7312e+12, b: -0.1, Ea: 3340.0}
  - {P: 100.0 atm, A: 2.9846e+11, b: 0.34, Ea: 3750.0}
- equation: C2H3 + O2 <=> C2H2 + HO2  # Reaction 244
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 4340.0, b: 2.3, Ea: 590.0}
  - {P: 1.0 atm, A: 5.6e+04, b: 1.99, Ea: 1362.0}
  - {P: 3.16 atm, A: 9.41e+04, b: 1.94, Ea: 1720.0}
  - {P: 10.0 atm, A: 1.13e+06, b: 1.65, Ea: 2820.0}
  - {P: 31.6 atm, A: 5.0e+06, b: 1.49, Ea: 3975.0}
  - {P: 100.0 atm, A: 1.57e+06, b: 1.67, Ea: 4820.0}
- equation: C2H3 + O2 <=> CH2O + HCO  # Reaction 245
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 4.5325e+16, b: -1.55, Ea: 1000.0}
  - {P: 1.0 atm, A: 1.7664e+17, b: -1.71, Ea: 1391.0}
  - {P: 3.16 atm, A: 4.5713e+17, b: -1.82, Ea: 1890.0}
  - {P: 10.0 atm, A: 9.7056e+17, b: -1.89, Ea: 2745.0}
  - {P: 31.6 atm, A: 1.7567e+17, b: -1.64, Ea: 3360.0}
  - {P: 100.0 atm, A: 6.658e+14, b: -0.92, Ea: 3300.0}
- equation: C2H3 + O2 => CH2O + CO + H  # Reaction 246
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 8.7056e+16, b: -1.55, Ea: 1000.0}
  - {P: 1.0 atm, A: 3.3944e+17, b: -1.71, Ea: 1391.0}
  - {P: 3.16 atm, A: 8.7855e+17, b: -1.82, Ea: 1890.0}
  - {P: 10.0 atm, A: 1.8689e+18, b: -1.89, Ea: 2745.0}
  - {P: 31.6 atm, A: 3.3704e+17, b: -1.64, Ea: 3360.0}
  - {P: 100.0 atm, A: 1.2779e+15, b: -0.92, Ea: 3300.0}
- equation: C2H3 + O2 => CO + H2 + HCO  # Reaction 247
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 6.56e+12, b: -0.47, Ea: 45.0}
  - {P: 1.0 atm, A: 1.0e+13, b: -0.51, Ea: 236.0}
  - {P: 3.16 atm, A: 6.32e+13, b: -0.73, Ea: 965.0}
  - {P: 10.0 atm, A: 2.34e+14, b: -0.88, Ea: 1916.0}
  - {P: 31.6 atm, A: 5.36e+13, b: -0.65, Ea: 2600.0}
  - {P: 100.0 atm, A: 6.62e+11, b: -0.07, Ea: 2840.0}
- equation: C2H3 + O2 => H + HCCO + OH  # Reaction 248
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.16e+10, b: 0.28, Ea: 805.0}
  - {P: 1.0 atm, A: 1.74e+11, b: -0.05, Ea: 1691.0}
  - {P: 3.16 atm, A: 9.4e+11, b: -0.24, Ea: 2454.0}
  - {P: 10.0 atm, A: 1.78e+13, b: -0.58, Ea: 3875.0}
  - {P: 31.6 atm, A: 8.8e+13, b: -0.74, Ea: 5400.0}
  - {P: 100.0 atm, A: 6.34e+13, b: -0.65, Ea: 6870.0}
- equation: C2H3 + O2 <=> CH2CO + OH  # Reaction 249
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.9e+09, b: 0.28, Ea: 805.0}
  - {P: 1.0 atm, A: 5.8e+10, b: -0.05, Ea: 1691.0}
  - {P: 3.16 atm, A: 3.12e+11, b: -0.24, Ea: 2454.0}
  - {P: 10.0 atm, A: 5.9e+12, b: -0.58, Ea: 3875.0}
  - {P: 31.6 atm, A: 2.9e+13, b: -0.74, Ea: 5400.0}
  - {P: 100.0 atm, A: 2.11e+13, b: -0.65, Ea: 6870.0}
- equation: C2H3 + HO2 <=> CH2CHO + OH  # Reaction 250
  rate-constant: {A: 3.1762e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + CH3 <=> C2H2 + CH4  # Reaction 251
  rate-constant: {A: 1.0119e+13, b: 0.0, Ea: -765.0}
- equation: CH2CHO (+M) <=> CH2CO + H (+M)  # Reaction 252
  type: falloff
  low-P-rate-constant: {A: 1.5904e+29, b: -3.79, Ea: 4.358e+04}
  high-P-rate-constant: {A: 9.3208e+14, b: -0.15, Ea: 4.561e+04}
  Troe: {A: 0.796, T3: 100.0, T1: 5.0e+04, T2: 3.42e+04}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH2CHO (+M) <=> CH3 + CO (+M)  # Reaction 253
  type: falloff
  low-P-rate-constant: {A: 2.8858e+27, b: -3.18, Ea: 3.344e+04}
  high-P-rate-constant: {A: 3.6134e+12, b: 0.29, Ea: 4.033e+04}
  Troe: {A: 0.211, T3: 199.0, T1: 2032.0, T2: 1.117e+05}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH2CHO + H + M <=> CH3CHO + M  # Reaction 254
  type: three-body
  rate-constant: {A: 4.88e+14, b: -7.12, Ea: 0.0}
- equation: CH2CHO + H <=> CH3 + HCO  # Reaction 255
  rate-constant: {A: 6.1283e+14, b: 0.0, Ea: 716.0}
- equation: CH2CHO + H <=> CH2CO + H2  # Reaction 256
  rate-constant: {A: 1.1804e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + H <=> CH3CO + H  # Reaction 257
  rate-constant: {A: 1.93e+13, b: 0.0, Ea: 2300.0}
- equation: CH2CHO + H <=> CH4 + CO  # Reaction 258
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 2160.0}
- equation: CH2CHO + O => CH2 + CO2 + H  # Reaction 259
  rate-constant: {A: 1.4929e+14, b: 0.0, Ea: 0.0}
- equation: CH2CHO + OH <=> CH2CO + H2O  # Reaction 260
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + OH <=> CH2OH + HCO  # Reaction 261
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + O2 => CH2O + CO + OH  # Reaction 262
  rate-constant: {A: 2.5728e+10, b: 0.0, Ea: 0.0}
- equation: CH2CHO + HO2 => CH3 + CO2 + OH  # Reaction 263
  rate-constant: {A: 2.8205e+13, b: 0.0, Ea: 0.0}
- equation: CH3CO (+M) <=> CH3 + CO (+M)  # Reaction 264
  type: falloff
  low-P-rate-constant: {A: 5.65e+18, b: -0.97, Ea: 1.458e+04}
  high-P-rate-constant: {A: 1.07e+12, b: 0.63, Ea: 1.69e+04}
  Troe: {A: 0.36, T3: 122.0, T1: 5.0e+04, T2: 1.694e+04}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH3CO + H + M <=> CH3CHO + M  # Reaction 265
  type: three-body
  rate-constant: {A: 3.49e+14, b: -9.17, Ea: 0.0}
- equation: CH3CO + H <=> CH3 + HCO  # Reaction 266
  rate-constant: {A: 4.54e+14, b: 0.0, Ea: 1960.0}
- equation: CH3CO + H <=> CH4 + CO  # Reaction 267
  rate-constant: {A: 4.93e+12, b: 0.0, Ea: 3740.0}
- equation: CH3CO + O <=> CH2CO + OH  # Reaction 268
  rate-constant: {A: 5.27e+13, b: 0.0, Ea: 0.0}
- equation: CH3CO + O <=> CH3 + CO2  # Reaction 269
  rate-constant: {A: 1.58e+14, b: 0.0, Ea: 0.0}
- equation: CH3CO + OH <=> CH2CO + H2O  # Reaction 270
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: CH3CO + OH => CH3 + CO + OH  # Reaction 271
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3CO + HO2 => CH3 + CO2 + OH  # Reaction 272
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3CO + O2 <=> CH2CO + HO2  # Reaction 273
  rate-constant: {A: 2.3e+10, b: 0.0, Ea: 0.0}
- equation: CH3 + CH3CO <=> CH2CO + CH4  # Reaction 274
  rate-constant: {A: 6.08e+12, b: 0.0, Ea: 0.0}
- equation: C2H2 + OH (+M) <=> C2H2OH (+M)  # Reaction 275
  type: falloff
  low-P-rate-constant: {A: 7.2e+33, b: -5.39, Ea: 3927.0}
  high-P-rate-constant: {A: 1.07e+08, b: 1.57, Ea: 250.0}
  Troe: {A: 1.7, T3: 11.6, T1: 514.0, T2: 2165.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H2OH + H <=> CH2CO + H2  # Reaction 276
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H2OH + H <=> CH2CHO + H  # Reaction 277
  rate-constant: {A: 2.96e+14, b: 0.0, Ea: 2920.0}
- equation: C2H2OH + H <=> CH3CO + H  # Reaction 278
  rate-constant: {A: 8.07e+12, b: 0.0, Ea: 1450.0}
- equation: C2H2OH + H <=> CH3 + HCO  # Reaction 279
  rate-constant: {A: 1.16e+14, b: 0.0, Ea: 0.0}
- equation: C2H2OH + H <=> CH4 + CO  # Reaction 280
  rate-constant: {A: 2.03e+12, b: 0.0, Ea: 1170.0}
- equation: C2H2OH + O => CH2O + CO + H  # Reaction 281
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H2OH + OH <=> CH2CO + H2O  # Reaction 282
  rate-constant: {A: 1.05e+13, b: 0.0, Ea: 0.0}
- equation: C2H2OH + O2 => CO + H2O + HCO  # Reaction 283
  rate-constant: {A: 1.7701e+12, b: 0.0, Ea: 0.0}
- equation: C2H2OH + O2 => CH2O + HCO + O  # Reaction 284
  rate-constant: {A: 8.0108e+11, b: 0.0, Ea: 0.0}
- equation: C2H2OH + HO2 => CH2O + CO + H + OH  # Reaction 285
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H2OH + CH3 <=> CH2CO + CH4  # Reaction 286
  rate-constant: {A: 4.5e+12, b: 0.0, Ea: -765.0}
- equation: C2H3 + H (+M) <=> C2H4 (+M)  # Reaction 287
  type: falloff
  low-P-rate-constant: {A: 1.4e+30, b: -3.86, Ea: 3320.0}
  high-P-rate-constant: {A: 3.88e+13, b: 0.2, Ea: 0.0}
  Troe: {A: 0.782, T3: 207.5, T1: 2663.0, T2: 6095.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H4 (+M) <=> H2 + H2CC (+M)  # Reaction 288
  type: falloff
  low-P-rate-constant: {A: 1.1184e+17, b: 0.0, Ea: 7.508e+04}
  high-P-rate-constant: {A: 2.5101e+15, b: 0.0, Ea: 8.623e+04}
  Troe: {A: 0.25, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H4 + H <=> C2H3 + H2  # Reaction 289
  rate-constant: {A: 243.59, b: 3.62, Ea: 1.127e+04}
- equation: C2H4 + O <=> CH3 + HCO  # Reaction 290
  rate-constant: {A: 6.5439e+17, b: -1.717, Ea: 2891.6}
- equation: C2H4 + O <=> CH3CO + H  # Reaction 291
  rate-constant: {A: 8.655e+12, b: -0.484, Ea: 1956.8}
- equation: C2H4 + O <=> CH2CHO + H  # Reaction 292
  rate-constant: {A: 9.2886e+09, b: 0.948, Ea: 1723.5}
- equation: C2H4 + O <=> CH2 + CH2O  # Reaction 293
  rate-constant: {A: 5.768e+06, b: 1.991, Ea: 2857.9}
- equation: C2H4 + O <=> CH2CO + H2  # Reaction 294
  rate-constant: {A: 1.123e+17, b: -1.831, Ea: 3177.6}
- equation: C2H4 + OH <=> C2H3 + H2O  # Reaction 295
  rate-constant: {A: 1.9394e+04, b: 2.75, Ea: 2216.0}
- equation: C2H4 + OH <=> CH2O + CH3  # Reaction 296
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 555.0, b: 2.36, Ea: -181.0}
  - {P: 1.0 atm, A: 1.78e+05, b: 1.68, Ea: 2060.0}
  - {P: 10.0 atm, A: 2.37e+09, b: 0.56, Ea: 6007.0}
  - {P: 100.0 atm, A: 2.76e+13, b: -0.5, Ea: 1.1456e+04}
- equation: C2H4 + OH <=> CH3CHO + H  # Reaction 297
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 0.4, b: 3.54, Ea: 1882.0}
  - {P: 1.0 atm, A: 0.0238, b: 3.91, Ea: 1723.0}
  - {P: 10.0 atm, A: 8.25e+08, b: 1.01, Ea: 1.051e+04}
  - {P: 100.0 atm, A: 6.8e+09, b: 0.81, Ea: 1.387e+04}
- equation: C2H4 + OH <=> C2H3OH + H  # Reaction 298
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.52e+04, b: 2.56, Ea: 4240.0}
  - {P: 1.0 atm, A: 3.19e+05, b: 2.19, Ea: 5256.0}
  - {P: 10.0 atm, A: 1.94e+08, b: 1.43, Ea: 7830.0}
  - {P: 100.0 atm, A: 8.55e+10, b: 0.75, Ea: 1.149e+04}
- equation: C2H4 + O2 <=> C2H3 + HO2  # Reaction 299
  rate-constant: {A: 7.5353e+13, b: 0.0, Ea: 6.001e+04}
- equation: C2H4 + HO2 <=> C2H4O + OH  # Reaction 300
  rate-constant: {A: 4.257e+12, b: 0.0, Ea: 1.7865e+04}
- equation: C2H4 + CH3 <=> C2H3 + CH4  # Reaction 301
  rate-constant: {A: 6.997e+07, b: 1.56, Ea: 1.663e+04}
- equation: CH3CHO (+M) <=> CH4 + CO (+M)  # Reaction 302
  type: falloff
  low-P-rate-constant: {A: 2.29e+58, b: -11.3, Ea: 9.592e+04}
  high-P-rate-constant: {A: 5.44e+21, b: -1.74, Ea: 8.636e+04}
  SRI: {A: 0.138, B: -670.0, C: 1.0e-03, D: 1.0, E: 0.0}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH3CHO (+M) <=> CH3 + HCO (+M)  # Reaction 303
  type: falloff
  low-P-rate-constant: {A: 8.9205e+58, b: -11.3, Ea: 9.592e+04}
  high-P-rate-constant: {A: 2.1253e+22, b: -1.74, Ea: 8.636e+04}
  SRI: {A: 0.138, B: -670.0, C: 1.0e-03, D: 1.0, E: 0.0}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0, C3H6: 4.0,
    C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0,
    H2O: 6.0}
- equation: CH3CHO + H <=> CH2CHO + H2  # Reaction 304
  rate-constant: {A: 2.05e+09, b: 1.16, Ea: 2405.0}
- equation: CH3CHO + H <=> CH3CO + H2  # Reaction 305
  rate-constant: {A: 2.05e+09, b: 1.16, Ea: 2405.0}
- equation: CH3CHO + O <=> CH2CHO + OH  # Reaction 306
  rate-constant: {A: 2.92e+12, b: 0.0, Ea: 1808.0}
- equation: CH3CHO + O <=> CH3CO + OH  # Reaction 307
  rate-constant: {A: 2.92e+12, b: 0.0, Ea: 1808.0}
- equation: CH3CHO + OH <=> CH3CO + H2O  # Reaction 308
  rate-constant: {A: 2.69e+08, b: 1.35, Ea: -1574.0}
- equation: CH3CHO + O2 <=> CH3CO + HO2  # Reaction 309
  rate-constant: {A: 1.2e+05, b: 2.5, Ea: 3.756e+04}
- equation: CH3CHO + HO2 <=> CH3CO + H2O2  # Reaction 310
  rate-constant: {A: 4.1e+04, b: 2.5, Ea: 1.02e+04}
- equation: CH3 + CH3CHO <=> CH3CO + CH4  # Reaction 311
  rate-constant: {A: 2.72e+06, b: 1.77, Ea: 5920.0}
- equation: C2H3OH <=> CH3CHO  # Reaction 312
  rate-constant: {A: 4.42e+42, b: -9.09, Ea: 6.7076e+04}
- equation: CH2CHO + H + M <=> C2H3OH + M  # Reaction 313
  type: three-body
  rate-constant: {A: 3.48e+15, b: -4.88, Ea: 0.0}
- equation: CH3CO + H + M <=> C2H3OH + M  # Reaction 314
  type: three-body
  rate-constant: {A: 9.81e+13, b: -7.84, Ea: 0.0}
- equation: CH3 + HCO (+M) <=> C2H3OH (+M)  # Reaction 315
  type: falloff
  low-P-rate-constant: {A: 3.47e+24, b: -3.23, Ea: -9240.0}
  high-P-rate-constant: {A: 7.45e+11, b: 0.0, Ea: -422.0}
  Troe: {A: 0.5, T3: 1.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H3OH + H <=> CH2CHO + H2  # Reaction 316
  rate-constant: {A: 0.0117, b: 4.28, Ea: 3279.0}
- equation: C2H3OH + H <=> C2H2OH + H2  # Reaction 317
  rate-constant: {A: 3.71e+07, b: 2.02, Ea: 1.4308e+04}
- equation: C2H3OH + O <=> CH2CHO + OH  # Reaction 318
  rate-constant: {A: 1.88e+06, b: 1.9, Ea: -860.0}
- equation: C2H3OH + OH <=> CH2CHO + H2O  # Reaction 319
  rate-constant: {A: 3.33e+09, b: 1.1, Ea: 540.5}
- equation: C2H3OH + O2 <=> CH2CHO + HO2  # Reaction 320
  rate-constant: {A: 5.31e+11, b: 0.21, Ea: 3.983e+04}
- equation: C2H3OH + HO2 <=> CH2CHO + H2O2  # Reaction 321
  rate-constant: {A: 9000.0, b: 2.5, Ea: 1.05e+04}
- equation: C2H3OH + HO2 <=> CH3CHO + HO2  # Reaction 322
  rate-constant: {A: 4.28e+07, b: 0.79, Ea: 7105.0}
- equation: C2H3OH + HO2 => CH2OH + HCO + OH  # Reaction 323
  rate-constant: {A: 7350.0, b: 2.5, Ea: 1.0992e+04}
- equation: C2H3OH + CH3 <=> CH2CHO + CH4  # Reaction 324
  rate-constant: {A: 2.03e-08, b: 5.9, Ea: 1052.0}
- equation: C2H3OH + CH3O2 <=> CH2CHO + CH3OOH  # Reaction 325
  rate-constant: {A: 3400.0, b: 2.5, Ea: 8922.0}
- equation: C2H4O <=> CH3 + HCO  # Reaction 326
  rate-constant: {A: 1.9976e+13, b: 0.4, Ea: 6.188e+04}
- equation: C2H4O <=> CH3CHO  # Reaction 327
  rate-constant: {A: 3.18e+12, b: -0.76, Ea: 4.642e+04}
- equation: C2H4O <=> CH3CO + H  # Reaction 328
  rate-constant: {A: 2.43e+13, b: 0.25, Ea: 6.531e+04}
- equation: C2H4O <=> CH4 + CO  # Reaction 329
  rate-constant: {A: 1.07e+13, b: 0.11, Ea: 6.378e+04}
- equation: C2H4O + H <=> CH2CHO + H2  # Reaction 330
  rate-constant: {A: 4.26e+13, b: 0.0, Ea: 9200.0}
- equation: C2H4O + O <=> CH2CHO + OH  # Reaction 331
  rate-constant: {A: 1.89e+12, b: 0.0, Ea: 5250.0}
- equation: C2H4O + O2 <=> CH2CHO + HO2  # Reaction 332
  rate-constant: {A: 4.9e+05, b: 2.5, Ea: 5.226e+04}
- equation: C2H4O + OH <=> CH2CHO + H2O  # Reaction 333
  rate-constant: {A: 6.62e+12, b: 0.0, Ea: 2900.0}
- equation: C2H4O + HO2 <=> CH2CHO + H2O2  # Reaction 334
  rate-constant: {A: 8.2e+04, b: 2.5, Ea: 2.035e+04}
- equation: C2H4O + CH3 <=> CH2CHO + CH4  # Reaction 335
  rate-constant: {A: 1.07e+12, b: 0.0, Ea: 1.182e+04}
- equation: C2H4 + H (+M) <=> C2H5 (+M)  # Reaction 336
  type: falloff
  low-P-rate-constant: {A: 1.9169e+39, b: -6.64, Ea: 5769.0}
  high-P-rate-constant: {A: 9.0557e+08, b: 1.46, Ea: 1355.0}
  Troe: {A: 0.594, T3: 2722.0, T1: 165.8, T2: 7396.0}
  efficiencies: {AR: 0.5670256032158684, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0,
    C2H6: 3.0, C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5,
    CO2: 2.0, H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5 + H <=> C2H4 + H2  # Reaction 337
  rate-constant: {A: 1.81e+12, b: 0.0, Ea: 0.0}
- equation: C2H5 + O <=> CH2O + CH3  # Reaction 338
  rate-constant: {A: 5.0647e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + O <=> CH3CHO + H  # Reaction 339
  rate-constant: {A: 6.8347e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + O <=> C2H4 + OH  # Reaction 340
  rate-constant: {A: 3.1936e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + OH <=> C2H4 + H2O  # Reaction 341
  rate-constant: {A: 1.605e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + OH <=> CH2OH + CH3  # Reaction 342
  rate-constant: {A: 1.6977e+15, b: -0.61, Ea: -76.0}
- equation: C2H5 + O2 <=> C2H4 + HO2  # Reaction 343
  rate-constant: {A: 1.5359e+07, b: 1.09, Ea: -1975.0}
- equation: C2H5 + HO2 <=> C2H4 + H2O2  # Reaction 344
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + HO2 => CH2O + CH3 + OH  # Reaction 345
  rate-constant: {A: 3.1e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + CH3 <=> C2H4 + CH4  # Reaction 346
  rate-constant: {A: 9.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + CH2O <=> C2H6 + HCO  # Reaction 347
  rate-constant: {A: 5500.0, b: 2.81, Ea: 5860.0}
- equation: C2H5 + CH3OH <=> C2H6 + CH2OH  # Reaction 348
  rate-constant: {A: 32.0, b: 3.2, Ea: 7175.0}
- equation: C2H5 + H (+M) <=> C2H6 (+M)  # Reaction 349
  type: falloff
  low-P-rate-constant: {A: 2.1198e+41, b: -7.08, Ea: 6685.0}
  high-P-rate-constant: {A: 5.5499e+17, b: -0.99, Ea: 1580.0}
  Troe: {A: 0.842, T3: 125.0, T1: 2219.0, T2: 6882.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H6 + H <=> C2H5 + H2  # Reaction 350
  rate-constant: {A: 1.2441e+08, b: 1.9, Ea: 7530.0}
- equation: C2H6 + O <=> C2H5 + OH  # Reaction 351
  rate-constant: {A: 1.5897e+05, b: 2.8, Ea: 5803.0}
- equation: C2H6 + O2 <=> C2H5 + HO2  # Reaction 352
  rate-constant: {A: 7.29e+05, b: 2.5, Ea: 4.916e+04}
- equation: C2H6 + OH <=> C2H5 + H2O  # Reaction 353
  rate-constant: {A: 9.15e+06, b: 2.0, Ea: 994.0}
- equation: C2H6 + HO2 <=> C2H5 + H2O2  # Reaction 354
  rate-constant: {A: 1.1305e+05, b: 2.5, Ea: 1.685e+04}
- equation: C2H6 + CH <=> C2H4 + CH3  # Reaction 355
  rate-constant: {A: 1.08e+14, b: 0.0, Ea: -262.0}
- equation: C2H6 + CH2(S) <=> C2H5 + CH3  # Reaction 356
  rate-constant: {A: 3.3e+13, b: 0.0, Ea: -660.0}
- equation: C2H6 + CH3 <=> C2H5 + CH4  # Reaction 357
  rate-constant: {A: 0.51226, b: 4.0, Ea: 8287.0}
- equation: CH3CHOH <=> CH3CHO + H  # Reaction 358
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 1.0273e+14, b: -1.61, Ea: 2.8844e+04}
  - {P: 1.0 atm, A: 9.5619e+27, b: -5.19, Ea: 3.5577e+04}
  - {P: 100.0 atm, A: 6.2714e+27, b: -4.67, Ea: 3.7685e+04}
- equation: CH3CHOH <=> C2H3OH + H  # Reaction 359
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 5.0905e+21, b: -3.23, Ea: 3.6572e+04}
  - {P: 1.0 atm, A: 2.293e+28, b: -5.08, Ea: 3.938e+04}
  - {P: 100.0 atm, A: 1.3987e+30, b: -5.17, Ea: 4.1916e+04}
- equation: CH3CHOH <=> CH2O + CH3  # Reaction 360
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 5.92e+11, b: -1.04, Ea: 2.874e+04}
  - {P: 1.0 atm, A: 1.14e+22, b: -3.59, Ea: 3.4663e+04}
  - {P: 100.0 atm, A: 4.36e+23, b: -3.55, Ea: 3.856e+04}
- equation: CH3CHOH + H <=> CH3CHO + H2  # Reaction 361
  rate-constant: {A: 4.3195e+13, b: 0.0, Ea: 0.0}
- equation: CH3CHOH + H <=> CH2OH + CH3  # Reaction 362
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 0.0}
- equation: CH3CHOH + O <=> CH3CHO + OH  # Reaction 363
  rate-constant: {A: 1.9e+14, b: 0.0, Ea: 0.0}
- equation: CH3CHOH + O2 <=> CH3CHO + HO2  # Reaction 364
  rate-constant: {A: 5.6553e+17, b: -1.64, Ea: 839.0}
- equation: CH3CHOH + OH <=> CH3CHO + H2O  # Reaction 365
  rate-constant: {A: 2.2699e+13, b: 0.0, Ea: 0.0}
- equation: CH3CHOH + HO2 <=> CH3CHO + H2O2  # Reaction 366
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + CH3CHOH <=> CH3CHO + CH4  # Reaction 367
  rate-constant: {A: 2.0419e+13, b: 0.0, Ea: 0.0}
- equation: C2H4 + OH <=> C2H4OH  # Reaction 368
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.39e+35, b: -7.72, Ea: 4822.0}
  - {P: 1.0 atm, A: 4.5e+35, b: -7.54, Ea: 6380.0}
  - {P: 10.0 atm, A: 6.9e+31, b: -6.1, Ea: 6293.0}
  - {P: 100.0 atm, A: 1.24e+24, b: -3.57, Ea: 4150.0}
- equation: C2H4OH + H <=> C2H3OH + H2  # Reaction 369
  rate-constant: {A: 4.734e+13, b: 0.0, Ea: 0.0}
- equation: C2H4OH + H <=> CH2OH + CH3  # Reaction 370
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 0.0}
- equation: C2H4OH + O <=> C2H3OH + OH  # Reaction 371
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H4OH + O <=> CH2O + CH2OH  # Reaction 372
  rate-constant: {A: 4.42e+13, b: 0.0, Ea: 0.0}
- equation: C2H4OH + O2 <=> C2H3OH + HO2  # Reaction 373
  rate-constant: {A: 1.6814e+12, b: 0.0, Ea: 0.0}
- equation: C2H4OH + OH <=> C2H3OH + H2O  # Reaction 374
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H4OH + HO2 <=> C2H3OH + H2O2  # Reaction 375
  rate-constant: {A: 2.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H4OH + HO2 => CH2O + CH2OH + OH  # Reaction 376
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: C2H4OH + CH3 <=> C2H3OH + CH4  # Reaction 377
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H5OH (+M) <=> C2H4 + H2O (+M)  # Reaction 378
  type: falloff
  low-P-rate-constant: {A: 3.1003e+64, b: -13.22, Ea: 8.368e+04}
  high-P-rate-constant: {A: 4.2519e+20, b: -2.06, Ea: 6.947e+04}
  Troe: {A: -2.148, T3: 5845.0, T1: 3.03e+04, T2: 6583.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5 + OH (+M) <=> C2H5OH (+M)  # Reaction 379
  type: falloff
  low-P-rate-constant: {A: 5.3e+59, b: -12.72, Ea: 1.524e+04}
  high-P-rate-constant: {A: 1.6e+15, b: -0.61, Ea: -76.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH2OH + CH3 (+M) <=> C2H5OH (+M)  # Reaction 380
  type: falloff
  low-P-rate-constant: {A: 8.1366e+60, b: -12.8, Ea: 1.714e+04}
  high-P-rate-constant: {A: 2.1198e+14, b: -0.19, Ea: 45.5}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5OH + H <=> CH3CHOH + H2  # Reaction 381
  rate-constant: {A: 8.207e+04, b: 2.68, Ea: 2915.0}
- equation: C2H5OH + H <=> C2H4OH + H2  # Reaction 382
  rate-constant: {A: 5.31e+04, b: 2.81, Ea: 7496.0}
- equation: C2H5OH + H => CH2O + CH3 + H2  # Reaction 383
  rate-constant: {A: 945.0, b: 3.14, Ea: 8702.0}
- equation: C2H5OH + O <=> CH3CHOH + OH  # Reaction 384
  rate-constant: {A: 1.45e+05, b: 2.47, Ea: 876.0}
- equation: C2H5OH + O <=> C2H4OH + OH  # Reaction 385
  rate-constant: {A: 970.0, b: 3.23, Ea: 4660.0}
- equation: C2H5OH + O => CH2O + CH3 + OH  # Reaction 386
  rate-constant: {A: 1.46e-03, b: 4.73, Ea: 1727.0}
- equation: C2H5OH + O2 <=> CH3CHOH + HO2  # Reaction 387
  rate-constant: {A: 2.4e+05, b: 2.5, Ea: 4.29e+04}
- equation: C2H5OH + O2 <=> C2H4OH + HO2  # Reaction 388
  rate-constant: {A: 3.6e+05, b: 2.5, Ea: 4.95e+04}
- equation: C2H5OH + OH <=> CH3CHOH + H2O  # Reaction 389
  rate-constant: {A: 6.37e+10, b: 0.49, Ea: -109.0}
- equation: C2H5OH + OH <=> C2H4OH + H2O  # Reaction 390
  rate-constant: {A: 1.38e+11, b: 0.39, Ea: 434.0}
- equation: C2H5OH + OH => CH2O + CH3 + H2O  # Reaction 391
  rate-constant: {A: 1.93e+10, b: 0.69, Ea: 1525.0}
- equation: C2H5OH + HO2 <=> CH3CHOH + H2O2  # Reaction 392
  rate-constant: {A: 8131.4, b: 2.55, Ea: 1.075e+04}
- equation: C2H5OH + HO2 <=> C2H4OH + H2O2  # Reaction 393
  rate-constant: {A: 1.23e+04, b: 2.55, Ea: 1.575e+04}
- equation: C2H5OH + CH3 <=> CH3CHOH + CH4  # Reaction 394
  rate-constant: {A: 19.9, b: 3.37, Ea: 7630.0}
- equation: C2H5OH + CH3 <=> C2H4OH + CH4  # Reaction 395
  rate-constant: {A: 330.0, b: 3.3, Ea: 1.229e+04}
- equation: C2H5OH + CH3 => CH2O + CH4 + CH3  # Reaction 396
  rate-constant: {A: 2.04, b: 3.57, Ea: 7720.0}
- equation: C2H5 + O2 (+M) <=> C2H5O2 (+M)  # Reaction 397
  type: falloff
  low-P-rate-constant: {A: 8.49e+29, b: -4.29, Ea: 220.0}
  high-P-rate-constant: {A: 2.02e+10, b: 0.98, Ea: -64.0}
  Troe: {A: 0.897, T3: 0.0, T1: 601.0, T2: 1.0e+05}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5O2 (+M) <=> C2H4 + HO2 (+M)  # Reaction 398
  type: falloff
  low-P-rate-constant: {A: 8.31e+21, b: -0.65, Ea: 2.289e+04}
  high-P-rate-constant: {A: 7.14e+04, b: 2.32, Ea: 2.796e+04}
  Troe: {A: 1.0, T3: 0.0, T1: 106.0, T2: 1.0e+05}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5O2 + H => CH2O + CH3 + OH  # Reaction 399
  rate-constant: {A: 9.64e+13, b: 0.0, Ea: 0.0}
- equation: C2H5O2 + O => CH2O + CH3 + O2  # Reaction 400
  rate-constant: {A: 1.22e+13, b: 0.0, Ea: -445.0}
- equation: C2H5O2 + OH => CH2O + CH3 + HO2  # Reaction 401
  rate-constant: {A: 1.69e+14, b: 0.0, Ea: 0.0}
- equation: C2H5O2 + O2 => CH2CHO + HO2 + OH  # Reaction 402
  rate-constant: {A: 2.4e+05, b: 2.5, Ea: 2.45e+04}
- equation: C2H5O2 + HO2 <=> C2H5OOH + O2  # Reaction 403
  rate-constant: {A: 4.5e+11, b: 0.0, Ea: -1391.0}
- equation: C2H5O2 + CO => CH2O + CH3 + CO2  # Reaction 404
  rate-constant: {A: 1.57e+05, b: 2.18, Ea: 1.794e+04}
- equation: C2H5O2 + CH3 => CH2O + CH3O + CH3  # Reaction 405
  rate-constant: {A: 5.06e+12, b: 0.0, Ea: -1411.0}
- equation: C2H5O2 + CH4 <=> C2H5OOH + CH3  # Reaction 406
  rate-constant: {A: 4.7e+04, b: 2.5, Ea: 2.1e+04}
- equation: 2 C2H5O2 => 2 CH2O + 2 CH3 + O2  # Reaction 407
  rate-constant: {A: 2.85e+11, b: -0.27, Ea: 408.0}
- equation: C2H5O2 + CH3O2 => CH2O + CH3 + CH3O + O2  # Reaction 408
  rate-constant: {A: 1.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H5OOH (+M) => CH2O + CH3 + OH (+M)  # Reaction 409
  type: falloff
  low-P-rate-constant: {A: 2.42e+17, b: 0.0, Ea: 3.106e+04}
  high-P-rate-constant: {A: 3.41e+16, b: 0.0, Ea: 4.372e+04}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H5OOH + H => CH3CHO + H2 + OH  # Reaction 410
  rate-constant: {A: 6.48e+10, b: 0.0, Ea: 1860.0}
- equation: C2H5OOH + H <=> C2H5O2 + H2  # Reaction 411
  rate-constant: {A: 4.32e+10, b: 0.0, Ea: 1860.0}
- equation: C2H5OOH + H => CH2O + CH3 + H2O  # Reaction 412
  rate-constant: {A: 1.2e+10, b: 0.0, Ea: 1860.0}
- equation: C2H5OOH + O => CH3CHO + 2 OH  # Reaction 413
  rate-constant: {A: 1.61e+13, b: 0.0, Ea: 4750.0}
- equation: C2H5OOH + O <=> C2H5O2 + OH  # Reaction 414
  rate-constant: {A: 8.65e+12, b: 0.0, Ea: 4750.0}
- equation: C2H5OOH + OH => CH3CHO + H2O + OH  # Reaction 415
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: -258.0}
- equation: C2H5OOH + OH <=> C2H5O2 + H2O  # Reaction 416
  rate-constant: {A: 1.08e+12, b: 0.0, Ea: -437.0}
- equation: C2H5OOH + HO2 <=> C2H5O2 + H2O2  # Reaction 417
  rate-constant: {A: 4.11e+04, b: 2.5, Ea: 1.0206e+04}
- equation: C2H + CH3 <=> C3H3 + H  # Reaction 418
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: C2H2 + CH2 <=> C3H3 + H  # Reaction 419
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 6620.0}
- equation: C2H2 + CH2(S) <=> C3H3 + H  # Reaction 420
  rate-constant: {A: 1.84e+14, b: -0.39, Ea: 0.0}
- equation: C2H2 + HCCO <=> C3H3 + CO  # Reaction 421
  rate-constant: {A: 1.0e+10, b: 0.0, Ea: 0.0}
- equation: C3H3 + O <=> C2H + CH2O  # Reaction 422
  rate-constant: {A: 1.39e+14, b: 0.0, Ea: 0.0}
- equation: C3H3 + O2 <=> CH2CO + HCO  # Reaction 423
  rate-constant: {A: 1.7639e+05, b: 1.7, Ea: 1500.0}
- equation: C3H3 + OH <=> C2H3 + HCO  # Reaction 424
  rate-constant: {A: 8.6349e+13, b: 0.0, Ea: 0.0}
- equation: C3H3 + OH <=> C2H4 + CO  # Reaction 425
  rate-constant: {A: 2.515e+13, b: 0.0, Ea: 0.0}
- equation: C3H3 + HO2 => C2H3 + CO + OH  # Reaction 426
  rate-constant: {A: 6.8278e+13, b: 0.0, Ea: 2734.0}
- equation: C3H3 + HO2 <=> O2 + PC3H4  # Reaction 427
  rate-constant: {A: 2.8467e+12, b: 0.0, Ea: 0.0}
- equation: C3H3 + HO2 <=> AC3H4 + O2  # Reaction 428
  rate-constant: {A: 1.4591e+12, b: 0.0, Ea: 0.0}
- equation: C3H3 + HCO <=> AC3H4 + CO  # Reaction 429
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 0.0}
- equation: C3H3 + HCO <=> CO + PC3H4  # Reaction 430
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 0.0}
- equation: C2H + C2H5 <=> C3H3 + CH3  # Reaction 431
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: 2 C2H3 <=> C3H3 + CH3  # Reaction 432
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 8.46e+30, b: -5.35, Ea: 6330.0}
  - {P: 1.0 atm, A: 9.41e+26, b: -4.14, Ea: 6640.0}
  - {P: 10.0 atm, A: 5.92e+19, b: -1.98, Ea: 6260.0}
  - {P: 50.0 atm, A: 6.03e+12, b: 0.1, Ea: 5640.0}
- equation: C3H3 + H <=> AC3H4  # Reaction 433
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.039 atm, A: 3.3407e+36, b: -7.41, Ea: 6337.0}
  - {P: 1.0 atm, A: 3.114e+29, b: -5.0, Ea: 4711.0}
  - {P: 10.0 atm, A: 8.5241e+23, b: -3.2, Ea: 3255.0}
  - {P: 100.0 atm, A: 3.3111e+20, b: -2.05, Ea: 2405.0}
- equation: C2H2 + CH3 <=> AC3H4 + H  # Reaction 434
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.4e+09, b: 0.91, Ea: 2.07e+04}
  - {P: 1.0 atm, A: 5.14e+09, b: 0.86, Ea: 2.2153e+04}
  - {P: 10.0 atm, A: 5.1e+11, b: 0.35, Ea: 2.5e+04}
  - {P: 100.0 atm, A: 7.3e+12, b: 0.11, Ea: 2.85e+04}
- equation: C2H4 + CH <=> AC3H4 + H  # Reaction 435
  rate-constant: {A: 3.7222e+13, b: 0.0, Ea: 0.0}
- equation: AC3H4 + H <=> C3H3 + H2  # Reaction 436
  rate-constant: {A: 5841.4, b: 3.1, Ea: 5522.0}
- equation: AC3H4 + O <=> C2H4 + CO  # Reaction 437
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + O <=> C2H2 + CH2O  # Reaction 438
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + O <=> C2H3 + HCO  # Reaction 439
  rate-constant: {A: 1.2e+12, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + OH <=> CH2CO + CH3  # Reaction 440
  rate-constant: {A: 3.12e+12, b: 0.0, Ea: -397.0}
- equation: AC3H4 + OH <=> C3H3 + H2O  # Reaction 441
  rate-constant: {A: 5.3e+06, b: 2.0, Ea: 2000.0}
- equation: AC3H4 + HO2 => C2H4 + CO + OH  # Reaction 442
  rate-constant: {A: 7.6e+12, b: 0.0, Ea: 1.8e+04}
- equation: AC3H4 + HO2 <=> C3H3 + H2O2  # Reaction 443
  rate-constant: {A: 2.7e+04, b: 2.5, Ea: 1.234e+04}
- equation: AC3H4 + CH3 <=> C3H3 + CH4  # Reaction 444
  rate-constant: {A: 1501.0, b: 2.97, Ea: 7922.0}
- equation: AC3H4 + C2H <=> C2H2 + C3H3  # Reaction 445
  rate-constant: {A: 4.8e+06, b: 2.0, Ea: -440.0}
- equation: AC3H4 + C2H3 <=> C2H4 + C3H3  # Reaction 446
  rate-constant: {A: 4.8e+06, b: 2.18, Ea: 3100.0}
- equation: AC3H4 + C3H5 <=> C3H3 + C3H6  # Reaction 447
  rate-constant: {A: 2580.0, b: 3.06, Ea: 2.6383e+04}
- equation: AC3H4 <=> PC3H4  # Reaction 448
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.039 atm, A: 6.917e+53, b: -12.18, Ea: 8.4276e+04}
  - {P: 1.0 atm, A: 8.9015e+39, b: -7.8, Ea: 7.8446e+04}
  - {P: 10.0 atm, A: 5.4946e+48, b: -10.0, Ea: 8.8685e+04}
  - {P: 100.0 atm, A: 1.0668e+41, b: -7.57, Ea: 8.572e+04}
- equation: C3H3 + H <=> PC3H4  # Reaction 449
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.039 atm, A: 3.7331e+36, b: -7.36, Ea: 6039.0}
  - {P: 1.0 atm, A: 8.1656e+29, b: -5.06, Ea: 4861.0}
  - {P: 10.0 atm, A: 1.1004e+24, b: -3.15, Ea: 3261.0}
  - {P: 100.0 atm, A: 1.3369e+18, b: -1.25, Ea: 1492.0}
- equation: C2H4 + CH <=> H + PC3H4  # Reaction 450
  rate-constant: {A: 3.795e+13, b: 0.0, Ea: 0.0}
- equation: H + PC3H4 <=> AC3H4 + H  # Reaction 451
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.5054e+15, b: -0.26, Ea: 7600.0}
  - {P: 1.0 atm, A: 6.8299e+17, b: -0.91, Ea: 1.0079e+04}
  - {P: 2.0 atm, A: 1.6339e+18, b: -1.0, Ea: 1.0756e+04}
  - {P: 5.0 atm, A: 2.1023e+18, b: -1.01, Ea: 1.1523e+04}
  - {P: 10.0 atm, A: 3.3768e+22, b: -2.18, Ea: 1.48e+04}
  - {P: 100.0 atm, A: 6.9715e+27, b: -3.58, Ea: 2.12e+04}
- equation: H + PC3H4 <=> C3H3 + H2  # Reaction 452
  rate-constant: {A: 1.2e+14, b: 0.0, Ea: 9817.0}
- equation: C2H2 + CH3 <=> H + PC3H4  # Reaction 453
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 4.071e+06, b: 1.86, Ea: 1.16e+04}
  - {P: 1.0 atm, A: 2.316e+09, b: 1.1, Ea: 1.3644e+04}
  - {P: 10.0 atm, A: 9.9514e+11, b: 0.39, Ea: 1.62e+04}
  - {P: 100.0 atm, A: 1.8998e+12, b: 0.37, Ea: 1.81e+04}
- equation: O + PC3H4 <=> C3H3 + OH  # Reaction 454
  rate-constant: {A: 7.65e+08, b: 1.5, Ea: 8600.0}
- equation: O + PC3H4 <=> CH3 + HCCO  # Reaction 455
  rate-constant: {A: 7.6766e+12, b: 0.0, Ea: 2250.0}
- equation: O + PC3H4 <=> C2H4 + CO  # Reaction 456
  rate-constant: {A: 8.9547e+12, b: 0.0, Ea: 2250.0}
- equation: OH + PC3H4 <=> C3H3 + H2O  # Reaction 457
  rate-constant: {A: 1.0e+06, b: 2.0, Ea: 100.0}
- equation: OH + PC3H4 <=> CH2CO + CH3  # Reaction 458
  rate-constant: {A: 1.56e+12, b: 0.0, Ea: -397.0}
- equation: HO2 + PC3H4 => C2H4 + CO + OH  # Reaction 459
  rate-constant: {A: 1.5e+07, b: 1.6, Ea: 1.53e+04}
- equation: HO2 + PC3H4 <=> C3H3 + H2O2  # Reaction 460
  rate-constant: {A: 2.897e+04, b: 2.5, Ea: 1.234e+04}
- equation: CH3 + PC3H4 <=> C3H3 + CH4  # Reaction 461
  rate-constant: {A: 65.8, b: 3.24, Ea: 7761.0}
- equation: C2H + PC3H4 <=> C2H2 + C3H3  # Reaction 462
  rate-constant: {A: 3.6e+06, b: 2.0, Ea: -1192.0}
- equation: C2H3 + PC3H4 <=> C2H4 + C3H3  # Reaction 463
  rate-constant: {A: 3080.0, b: 2.72, Ea: 3142.0}
- equation: C3H3 + PC3H4 <=> AC3H4 + C3H3  # Reaction 464
  rate-constant: {A: 6.14e+06, b: 1.74, Ea: 1.045e+04}
- equation: C3H5 + PC3H4 <=> C3H3 + C3H6  # Reaction 465
  rate-constant: {A: 316.0, b: 3.22, Ea: 1.7402e+04}
- equation: C3H3 + OH => C2H3CHO  # Reaction 466
  rate-constant: {A: 8.4844e+12, b: 0.0, Ea: 0.0}
- equation: C2H3 + HCO <=> C2H3CHO  # Reaction 467
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: C2H3CHO + H => C2H3 + CO + H2  # Reaction 468
  rate-constant: {A: 2.05e+09, b: 1.16, Ea: 2405.0}
- equation: C2H3CHO + H <=> C2H4 + HCO  # Reaction 469
  rate-constant: {A: 5.1883e+13, b: 0.0, Ea: 4135.0}
- equation: C2H3CHO + O <=> CH2CHO + HCO  # Reaction 470
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: 2405.0}
- equation: C2H3CHO + O => C2H3 + CO + OH  # Reaction 471
  rate-constant: {A: 2.9e+12, b: 0.0, Ea: 1880.0}
- equation: C2H3CHO + OH => C2H3 + CO + H2O  # Reaction 472
  rate-constant: {A: 5.94e+06, b: 1.98, Ea: -1635.0}
- equation: C2H3CHO + OH <=> C2H3OH + HCO  # Reaction 473
  rate-constant: {A: 1.6e+12, b: 0.0, Ea: -660.0}
- equation: C2H3CHO + O2 => C2H3 + CO + HO2  # Reaction 474
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 4.07e+04}
- equation: C2H3CHO + HO2 => C2H3 + CO + H2O2  # Reaction 475
  rate-constant: {A: 3.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H3CHO + HO2 => CH2CHO + HCO + OH  # Reaction 476
  rate-constant: {A: 1.05e+12, b: 0.0, Ea: 1.42e+04}
- equation: C2H3CHO + CH3 => C2H3 + CH4 + CO  # Reaction 477
  rate-constant: {A: 2.9312e+06, b: 1.78, Ea: 5911.0}
- equation: C2H3CHO + CH3O => C2H3 + CH3OH + CO  # Reaction 478
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 3300.0}
- equation: C2H3CHO + CH3O2 => C2H3 + CH3OOH + CO  # Reaction 479
  rate-constant: {A: 3.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H3CHO + C2H3 => C2H4 + CO + C2H3  # Reaction 480
  rate-constant: {A: 1.74e+12, b: 0.0, Ea: 8440.0}
- equation: C2H3CHO + C3H3 => C2H3 + CO + PC3H4  # Reaction 481
  rate-constant: {A: 6.3e+07, b: 1.8, Ea: 1.82e+04}
- equation: C2H3CHO + C3H5 => C2H3 + C3H6 + CO  # Reaction 482
  rate-constant: {A: 6.3e+07, b: 1.8, Ea: 1.82e+04}
- equation: C2H2 + CH3 <=> C3H5  # Reaction 483
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 8.2e+53, b: -13.32, Ea: 3.32e+04}
  - {P: 1.0 atm, A: 2.68e+53, b: -12.82, Ea: 3.573e+04}
  - {P: 10.0 atm, A: 4.4e+49, b: -11.4, Ea: 3.67e+04}
  - {P: 100.0 atm, A: 3.8e+44, b: -9.63, Ea: 3.76e+04}
- equation: AC3H4 + H <=> C3H5  # Reaction 484
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.0509e+62, b: -14.67, Ea: 2.6e+04}
  - {P: 1.0 atm, A: 1.6622e+59, b: -13.54, Ea: 2.6949e+04}
  - {P: 10.0 atm, A: 2.6246e+52, b: -11.3, Ea: 2.54e+04}
  - {P: 100.0 atm, A: 7.5456e+41, b: -8.06, Ea: 2.13e+04}
- equation: H + PC3H4 <=> C3H5  # Reaction 485
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.1e+60, b: -14.56, Ea: 2.81e+04}
  - {P: 1.0 atm, A: 4.91e+60, b: -14.37, Ea: 3.1644e+04}
  - {P: 10.0 atm, A: 2.2e+59, b: -13.61, Ea: 3.49e+04}
  - {P: 100.0 atm, A: 1.6e+55, b: -12.07, Ea: 3.75e+04}
- equation: C2H3 + CH3 <=> C3H5 + H  # Reaction 486
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.1139e+18, b: -1.34, Ea: 3677.0}
  - {P: 1.0 atm, A: 6.4273e+13, b: -0.07, Ea: 3640.0}
  - {P: 10.0 atm, A: 3.1151e+06, b: 2.07, Ea: 2323.0}
  - {P: 100.0 atm, A: 3.9431e-03, b: 4.63, Ea: 129.0}
- equation: C2H4 + CH2 <=> C3H5 + H  # Reaction 487
  rate-constant: {A: 3.8741e+13, b: 0.0, Ea: 6000.0}
- equation: C2H4 + CH2(S) <=> C3H5 + H  # Reaction 488
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.13e+18, b: -1.43, Ea: 1213.0}
  - {P: 1.0 atm, A: 7.4e+16, b: -1.04, Ea: 2330.0}
  - {P: 10.0 atm, A: 2.0e+11, b: 0.63, Ea: 2000.0}
  - {P: 100.0 atm, A: 18.3, b: 3.55, Ea: -34.0}
- equation: C2H3 + C2H5 <=> C3H5 + CH3  # Reaction 489
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.4549e+13, b: 0.0, Ea: 0.0}
  - {P: 1.0 atm, A: 2.0389e+17, b: -1.15, Ea: 3370.0}
  - {P: 10.0 atm, A: 1.8796e+23, b: -2.75, Ea: 9420.0}
  - {P: 100.0 atm, A: 2.8672e+23, b: -2.67, Ea: 1.338e+04}
- equation: C3H5 + H <=> AC3H4 + H2  # Reaction 490
  rate-constant: {A: 1230.0, b: 3.04, Ea: 2582.0}
- equation: C3H5 + O <=> C2H3CHO + H  # Reaction 491
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C3H5 + O2 <=> AC3H4 + HO2  # Reaction 492
  rate-constant: {A: 2.06e+04, b: 2.19, Ea: 1.76e+04}
- equation: C3H5 + O2 <=> CH2O + CH3CO  # Reaction 493
  rate-constant: {A: 3.08e+09, b: 0.37, Ea: 1.69e+04}
- equation: C3H5 + O2 <=> C2H3CHO + OH  # Reaction 494
  rate-constant: {A: 1.27e+14, b: -0.61, Ea: 2.1815e+04}
- equation: C3H5 + OH => C2H3CHO + 2 H  # Reaction 495
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 5.3e+37, b: -6.71, Ea: 2.9306e+04}
  - {P: 1.0 atm, A: 4.2e+32, b: -5.16, Ea: 3.0126e+04}
  - {P: 10.0 atm, A: 1.6e+20, b: -1.56, Ea: 2.633e+04}
  - {P: 100.0 atm, A: 1.38e+15, b: -0.06, Ea: 2.68e+04}
- equation: C3H5 + OH <=> AC3H4 + H2O  # Reaction 496
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 0.0}
- equation: C3H5 + HO2 => C2H3CHO + H + OH  # Reaction 497
  rate-constant: {A: 5.4041e+13, b: 0.0, Ea: 2734.0}
- equation: C3H5 + HCO <=> C3H6 + CO  # Reaction 498
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C3H5 + CH3 <=> AC3H4 + CH4  # Reaction 499
  rate-constant: {A: 3.0e+12, b: -0.32, Ea: -131.0}
- equation: C3H5 + CH3O2 => C2H3CHO + CH3O + H  # Reaction 500
  rate-constant: {A: 4.38e+13, b: 0.0, Ea: 2734.0}
- equation: C2H3 + C3H5 <=> AC3H4 + C2H4  # Reaction 501
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 0.0}
- equation: C2H5 + C3H5 <=> AC3H4 + C2H6  # Reaction 502
  rate-constant: {A: 9.64e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + C3H5 <=> C2H4 + C3H6  # Reaction 503
  rate-constant: {A: 2.59e+12, b: 0.0, Ea: 0.0}
- equation: 2 AC3H4 <=> C3H3 + C3H5  # Reaction 504
  rate-constant: {A: 5.0e+14, b: 0.0, Ea: 6.4747e+04}
- equation: 2 C3H5 <=> AC3H4 + C3H6  # Reaction 505
  rate-constant: {A: 8.43e+10, b: 0.0, Ea: -262.0}
- equation: AC3H4 + H <=> CH3CCH2  # Reaction 506
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 9.2e+38, b: -8.65, Ea: 7000.0}
  - {P: 1.0 atm, A: 9.46e+42, b: -9.43, Ea: 1.119e+04}
  - {P: 2.0 atm, A: 8.47e+43, b: -9.59, Ea: 1.2462e+04}
  - {P: 5.0 atm, A: 6.98e+44, b: -9.7, Ea: 1.4032e+04}
  - {P: 10.0 atm, A: 1.5e+45, b: -9.69, Ea: 1.51e+04}
  - {P: 100.0 atm, A: 1.8e+43, b: -8.78, Ea: 1.68e+04}
- equation: H + PC3H4 <=> CH3CCH2  # Reaction 507
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 4.6e+44, b: -10.21, Ea: 1.02e+04}
  - {P: 1.0 atm, A: 1.66e+47, b: -10.58, Ea: 1.369e+04}
  - {P: 2.0 atm, A: 5.04e+47, b: -10.61, Ea: 1.4707e+04}
  - {P: 5.0 atm, A: 9.62e+47, b: -10.55, Ea: 1.591e+04}
  - {P: 10.0 atm, A: 7.0e+47, b: -10.4, Ea: 1.66e+04}
  - {P: 100.0 atm, A: 3.2e+44, b: -9.11, Ea: 1.74e+04}
- equation: CH3CCH2 <=> C3H5  # Reaction 508
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 7.094e+58, b: -15.4, Ea: 5.5856e+04}
  - {P: 1.0 atm, A: 1.284e+56, b: -14.06, Ea: 5.6324e+04}
  - {P: 2.0 atm, A: 8.731e+54, b: -13.57, Ea: 5.6405e+04}
  - {P: 5.0 atm, A: 8.84e+52, b: -12.79, Ea: 5.6339e+04}
  - {P: 10.0 atm, A: 1.164e+51, b: -12.1, Ea: 5.6156e+04}
  - {P: 100.0 atm, A: 5.093e+42, b: -9.25, Ea: 5.4456e+04}
- equation: CH3CCH2 + H <=> C3H5 + H  # Reaction 509
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + H <=> H2 + PC3H4  # Reaction 510
  rate-constant: {A: 3.34e+12, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + O <=> CH2CO + CH3  # Reaction 511
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + OH <=> AC3H4 + H2O  # Reaction 512
  rate-constant: {A: 5.6787e+12, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + OH <=> CH2CO + CH3 + H  # Reaction 513
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + O2 <=> CH2O + CH3CO  # Reaction 514
  rate-constant: {A: 9.03e+22, b: -3.21, Ea: 4295.9}
- equation: CH3CCH2 + HO2 <=> CH2CO + CH3 + OH  # Reaction 515
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3CCH2 + HCO <=> C3H6 + CO  # Reaction 516
  rate-constant: {A: 9.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + CH3CCH2 <=> H + IC4H7  # Reaction 517
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 4.12e+29, b: -4.95, Ea: 8000.0}
  - {P: 0.01 atm, A: 5.73e+15, b: -0.77, Ea: 1195.9}
  - {P: 0.1 atm, A: 4.86e+30, b: -5.03, Ea: 1.13e+04}
  - {P: 0.1 atm, A: 2.06e+13, b: -0.074, Ea: 1428.7}
  - {P: 1.0 atm, A: 5.3e+29, b: -4.57, Ea: 1.44e+04}
  - {P: 1.0 atm, A: 4.48e+10, b: 0.6, Ea: 1421.6}
  - {P: 10.0 atm, A: 1.32e+30, b: -4.54, Ea: 1.93e+04}
  - {P: 10.0 atm, A: 4.1e+06, b: 1.71, Ea: 1056.9}
  - {P: 100.0 atm, A: 5.16e+28, b: -4.03, Ea: 2.38e+04}
  - {P: 100.0 atm, A: 0.137, b: 3.91, Ea: -353.55}
- equation: CH3 + CH3CCH2 <=> CH4 + PC3H4  # Reaction 518
  rate-constant: {A: 1.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H3 + CH3 (+M) <=> C3H6 (+M)  # Reaction 519
  type: falloff
  low-P-rate-constant: {A: 4.996e+58, b: -11.94, Ea: 9770.0}
  high-P-rate-constant: {A: 2.9251e+13, b: 0.0, Ea: 0.0}
  Troe: {A: 0.175, T3: 1341.0, T1: 6.0e+04, T2: 1.014e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C3H5 + H (+M) <=> C3H6 (+M)  # Reaction 520
  type: falloff
  low-P-rate-constant: {A: 1.2418e+60, b: -12.0, Ea: 5968.0}
  high-P-rate-constant: {A: 1.8673e+14, b: 0.0, Ea: 0.0}
  Troe: {A: 0.02, T3: 1097.0, T1: 1097.0, T2: 6860.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H4 + CH2(S) <=> C3H6  # Reaction 521
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.27e+44, b: -10.14, Ea: 7600.0}
  - {P: 1.0 atm, A: 4.65e+39, b: -8.31, Ea: 6974.0}
  - {P: 10.0 atm, A: 7.43e+31, b: -5.74, Ea: 5160.0}
  - {P: 100.0 atm, A: 2.48e+24, b: -3.35, Ea: 3517.0}
- equation: C2H4 + CH2(S) <=> C2H3 + CH3  # Reaction 522
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 5.3e+13, b: -0.09, Ea: 1123.0}
  - {P: 1.0 atm, A: 1.5e+13, b: 0.12, Ea: 3000.0}
  - {P: 10.0 atm, A: 5.17e+09, b: 1.19, Ea: 3780.0}
  - {P: 100.0 atm, A: 4.5e+05, b: 2.43, Ea: 4790.0}
- equation: C3H6 + H <=> C3H5 + H2  # Reaction 523
  rate-constant: {A: 1.169e+06, b: 2.31, Ea: 4674.0}
- equation: C3H6 + H <=> CH3CCH2 + H2  # Reaction 524
  rate-constant: {A: 149.8, b: 3.381, Ea: 8909.5}
- equation: C3H6 + H <=> C2H4 + CH3  # Reaction 525
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 1.5347e+09, b: 1.35, Ea: 2542.0}
  - {P: 0.039 atm, A: 7.8527e+10, b: 0.87, Ea: 3600.0}
  - {P: 1.0 atm, A: 2.6608e+12, b: 0.47, Ea: 5431.0}
  - {P: 10.0 atm, A: 1.1859e+17, b: -0.79, Ea: 9750.0}
  - {P: 100.0 atm, A: 2.6508e+18, b: -1.09, Ea: 1.318e+04}
- equation: C3H6 + O <=> C2H5 + HCO  # Reaction 526
  rate-constant: {A: 9.0e+05, b: 2.15, Ea: -795.0}
- equation: C3H6 + O <=> CH2CHO + CH3  # Reaction 527
  rate-constant: {A: 1.01e+06, b: 2.15, Ea: -795.0}
- equation: C3H6 + O => C2H3CHO + 2 H  # Reaction 528
  rate-constant: {A: 1.66e+06, b: 2.15, Ea: -795.0}
- equation: C3H6 + O <=> C3H5 + OH  # Reaction 529
  rate-constant: {A: 1.75e+11, b: 0.7, Ea: 5882.0}
- equation: C3H6 + O <=> CH3CCH2 + OH  # Reaction 530
  rate-constant: {A: 6.0e+10, b: 0.7, Ea: 7630.0}
- equation: C3H6 + O2 <=> C3H5 + HO2  # Reaction 531
  rate-constant: {A: 5.5172e+29, b: -4.412, Ea: 5.4372e+04}
- equation: C3H6 + OH <=> C3H5 + H2O  # Reaction 532
  rate-constant: {A: 1.9064e+06, b: 2.23, Ea: 1073.0}
- equation: C3H6 + OH <=> CH3CCH2 + H2O  # Reaction 533
  rate-constant: {A: 3.449e+04, b: 2.535, Ea: 1502.5}
- equation: C3H6 + HO2 <=> C3H5 + H2O2  # Reaction 534
  rate-constant: {A: 2.7e+04, b: 2.5, Ea: 1.234e+04}
- equation: C3H6 + HO2 <=> CH3CCH2 + H2O2  # Reaction 535
  rate-constant: {A: 1.56e+04, b: 2.82, Ea: 2.4428e+04}
- equation: C3H6 + HO2 => CH2CHO + CH3 + OH  # Reaction 536
  rate-constant: {A: 1.03e+12, b: 0.0, Ea: 1.42e+04}
- equation: C3H6 + CH3 <=> C3H5 + CH4  # Reaction 537
  rate-constant: {A: 49.61, b: 3.27, Ea: 7152.0}
- equation: C3H6 + CH3 <=> CH3CCH2 + CH4  # Reaction 538
  rate-constant: {A: 0.84, b: 3.5, Ea: 1.166e+04}
- equation: C3H6 + CH3O2 <=> C3H5 + CH3OOH  # Reaction 539
  rate-constant: {A: 19.4, b: 3.64, Ea: 1.71e+04}
- equation: C2H5 + C3H6 <=> C2H6 + C3H5  # Reaction 540
  rate-constant: {A: 16.9, b: 3.38, Ea: 7598.0}
- equation: C2H5O2 + C3H6 <=> C2H5OOH + C3H5  # Reaction 541
  rate-constant: {A: 19.4, b: 3.64, Ea: 1.71e+04}
- equation: C3H5 + OH <=> C3H5OH  # Reaction 542
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 0.0}
- equation: C3H5OH + H => C2H3CHO + H2 + H  # Reaction 543
  rate-constant: {A: 4.27e+13, b: 0.0, Ea: 8283.0}
- equation: C3H5OH + H <=> C2H4 + CH2OH  # Reaction 544
  rate-constant: {A: 4.8e+13, b: 0.0, Ea: 4135.0}
- equation: C3H5OH + O <=> CH2CHO + CH2OH  # Reaction 545
  rate-constant: {A: 1.01e+06, b: 2.15, Ea: -795.0}
- equation: C3H5OH + O => C2H3CHO + H + OH  # Reaction 546
  rate-constant: {A: 3.49e+11, b: 0.7, Ea: 5884.0}
- equation: C3H5OH + O2 => C2H3CHO + H + HO2  # Reaction 547
  rate-constant: {A: 7200.0, b: 2.5, Ea: 3.573e+04}
- equation: C3H5OH + OH => C2H3CHO + H + H2O  # Reaction 548
  rate-constant: {A: 1.29e+06, b: 2.23, Ea: 1073.0}
- equation: C3H5OH + HO2 => C2H3CHO + H + H2O2  # Reaction 549
  rate-constant: {A: 1.8e+04, b: 2.5, Ea: 1.234e+04}
- equation: C3H5OH + HO2 => CH2CHO + CH2OH + OH  # Reaction 550
  rate-constant: {A: 1.05e+12, b: 0.0, Ea: 1.42e+04}
- equation: C3H5OH + CH3 => C2H3CHO + CH4 + H  # Reaction 551
  rate-constant: {A: 2.4e+11, b: 0.0, Ea: 8030.0}
- equation: C3H6 + H <=> IC3H7  # Reaction 552
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 1.1188e+38, b: -8.8, Ea: 6113.0}
  - {P: 0.039 atm, A: 1.1577e+40, b: -8.93, Ea: 8340.0}
  - {P: 1.0 atm, A: 6.6931e+37, b: -7.85, Ea: 8914.0}
  - {P: 10.0 atm, A: 2.1792e+34, b: -6.55, Ea: 8600.0}
  - {P: 100.0 atm, A: 2.1889e+29, b: -4.84, Ea: 7580.0}
- equation: H + IC3H7 <=> C3H6 + H2  # Reaction 553
  rate-constant: {A: 3.61e+12, b: 0.0, Ea: 0.0}
- equation: H + IC3H7 <=> C2H5 + CH3  # Reaction 554
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 4.51e+29, b: -4.49, Ea: 1.3643e+04}
  - {P: 1.0 atm, A: 1.4e+28, b: -3.94, Ea: 1.5916e+04}
  - {P: 10.0 atm, A: 4.0e+24, b: -2.83, Ea: 1.7542e+04}
  - {P: 100.0 atm, A: 2.1e-05, b: 5.6, Ea: 3590.0}
- equation: IC3H7 + O <=> CH3COCH3 + H  # Reaction 555
  rate-constant: {A: 4.82e+13, b: 0.0, Ea: 0.0}
- equation: IC3H7 + O <=> CH3 + CH3CHO  # Reaction 556
  rate-constant: {A: 4.82e+13, b: 0.0, Ea: 0.0}
- equation: IC3H7 + O2 <=> C3H6 + HO2  # Reaction 557
  rate-constant: {A: 3.1817e+10, b: 0.0, Ea: -2146.0}
- equation: IC3H7 + OH <=> C3H6 + H2O  # Reaction 558
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + IC3H7 => CH3 + CH3CHO + OH  # Reaction 559
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: CH3 + IC3H7 <=> C3H6 + CH4  # Reaction 560
  rate-constant: {A: 9.41e+10, b: 0.68, Ea: 0.0}
- equation: CH3O2 + IC3H7 => CH3 + CH3CHO + CH3O  # Reaction 561
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: C3H6 + IC3H7 <=> C3H5 + C3H8  # Reaction 562
  rate-constant: {A: 1.95, b: 3.54, Ea: 6030.0}
- equation: C2H4 + CH3 <=> NC3H7  # Reaction 563
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 2.4428e+44, b: -11.23, Ea: 1.512e+04}
  - {P: 0.039 atm, A: 8.5906e+39, b: -9.88, Ea: 1.3165e+04}
  - {P: 1.0 atm, A: 2.2674e+37, b: -8.17, Ea: 1.5605e+04}
  - {P: 10.0 atm, A: 5.5167e+30, b: -5.91, Ea: 1.422e+04}
  - {P: 100.0 atm, A: 3.9739e+22, b: -3.28, Ea: 1.21e+04}
- equation: C3H6 + H <=> NC3H7  # Reaction 564
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.001 atm, A: 2.6e+27, b: -6.16, Ea: 4230.0}
  - {P: 0.039 atm, A: 8.64e+32, b: -7.22, Ea: 6374.0}
  - {P: 1.0 atm, A: 1.69e+37, b: -7.99, Ea: 9280.0}
  - {P: 10.0 atm, A: 7.68e+31, b: -6.03, Ea: 8700.0}
  - {P: 100.0 atm, A: 5.48e+22, b: -2.95, Ea: 6300.0}
- equation: H + NC3H7 <=> C3H6 + H2  # Reaction 565
  rate-constant: {A: 1.81e+12, b: 0.0, Ea: 0.0}
- equation: H + NC3H7 <=> C2H5 + CH3  # Reaction 566
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.39e+27, b: -3.79, Ea: 1.0895e+04}
  - {P: 1.0 atm, A: 3.7e+24, b: -2.92, Ea: 1.2505e+04}
  - {P: 10.0 atm, A: 3.1e+27, b: -3.59, Ea: 1.9059e+04}
  - {P: 100.0 atm, A: 1.2e-10, b: 7.19, Ea: 0.0}
- equation: NC3H7 + O <=> C2H5CHO + H  # Reaction 567
  rate-constant: {A: 8.26e+13, b: 0.0, Ea: 0.0}
- equation: NC3H7 + O <=> C2H5 + CH2O  # Reaction 568
  rate-constant: {A: 1.38e+13, b: 0.0, Ea: 0.0}
- equation: NC3H7 + O2 <=> C3H6 + HO2  # Reaction 569
  rate-constant: {A: 3.61e+10, b: 0.0, Ea: 0.0}
- equation: NC3H7 + OH <=> C3H6 + H2O  # Reaction 570
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + NC3H7 => C2H5 + CH2O + OH  # Reaction 571
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: CH3 + NC3H7 <=> C3H6 + CH4  # Reaction 572
  rate-constant: {A: 1.15e+13, b: -0.32, Ea: 0.0}
- equation: CH3O2 + NC3H7 => C2H5 + CH2O + CH3O  # Reaction 573
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: C3H6 + NC3H7 <=> C3H5 + C3H8  # Reaction 574
  rate-constant: {A: 5.84, b: 3.38, Ea: 7598.0}
- equation: CH3COCH3 <=> CH3 + CH3CO  # Reaction 575
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.9968e+58, b: -12.8, Ea: 1.0003e+05}
  - {P: 1.0 atm, A: 1.276e+42, b: -7.66, Ea: 9.4661e+04}
  - {P: 10.0 atm, A: 2.1039e+33, b: -4.99, Ea: 9.0916e+04}
  - {P: 100.0 atm, A: 9.1559e+28, b: -3.67, Ea: 8.9023e+04}
- equation: CH3COCH3 + H => CH3 + CH3CHO  # Reaction 576
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 7270.0}
- equation: CH3COCH3 + H <=> CH3COCH2 + H2  # Reaction 577
  rate-constant: {A: 1.0907e+06, b: 2.43, Ea: 5160.0}
- equation: CH3COCH3 + O <=> CH3COCH2 + OH  # Reaction 578
  rate-constant: {A: 5.13e+11, b: 0.21, Ea: 4890.0}
- equation: CH3COCH2 + O2 => CH2CO + CH2O + OH  # Reaction 579
  rate-constant: {A: 1.4153e+11, b: 0.0, Ea: -1100.0}
- equation: CH3COCH3 + O2 <=> CH3COCH2 + HO2  # Reaction 580
  rate-constant: {A: 9.2514e+05, b: 2.5, Ea: 4.33e+04}
- equation: CH3COCH3 + OH <=> CH3COCH2 + H2O  # Reaction 581
  rate-constant: {A: 2.95e+13, b: 0.0, Ea: 4565.0}
- equation: CH3COCH3 + HO2 <=> CH3COCH2 + H2O2  # Reaction 582
  rate-constant: {A: 1.3576e+05, b: 2.5, Ea: 1.157e+04}
- equation: CH3 + CH3COCH3 <=> CH3COCH2 + CH4  # Reaction 583
  rate-constant: {A: 3.47e+11, b: 0.0, Ea: 9678.0}
- equation: CH3COCH3 + CH3O <=> CH3COCH2 + CH3OH  # Reaction 584
  rate-constant: {A: 4.34e+11, b: 0.0, Ea: 6460.0}
- equation: CH3COCH3 + CH3O2 <=> CH3COCH2 + CH3OOH  # Reaction 585
  rate-constant: {A: 1.7e+13, b: 0.0, Ea: 2.046e+04}
- equation: CH2CO + CH3 (+M) <=> CH3COCH2 (+M)  # Reaction 586
  type: falloff
  low-P-rate-constant: {A: 2.3706e+45, b: -8.84, Ea: 1.285e+04}
  high-P-rate-constant: {A: 1.2917e+04, b: 2.48, Ea: 6130.0}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: CH3COCH2 + H <=> CH3 + CH3CO  # Reaction 587
  rate-constant: {A: 4.54e+14, b: 0.0, Ea: 716.0}
- equation: C2H3 + CH3COCH3 <=> C2H4 + CH3COCH2  # Reaction 588
  rate-constant: {A: 601.0, b: 3.3, Ea: 1.05e+04}
- equation: C2H5 + CH3COCH3 <=> C2H6 + CH3COCH2  # Reaction 589
  rate-constant: {A: 0.9, b: 3.65, Ea: 9141.0}
- equation: C3H3 + CH3COCH3 <=> CH3COCH2 + PC3H4  # Reaction 590
  rate-constant: {A: 235.0, b: 3.3, Ea: 1.99e+04}
- equation: C3H5 + CH3COCH3 <=> C3H6 + CH3COCH2  # Reaction 591
  rate-constant: {A: 235.0, b: 3.3, Ea: 1.99e+04}
- equation: C2H5 + HCO <=> C2H5CHO  # Reaction 592
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + CH3 <=> C2H5CHO  # Reaction 593
  rate-constant: {A: 4.9e+14, b: -0.5, Ea: 0.0}
- equation: C2H5CHO + H => C2H5 + CH2O  # Reaction 594
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 6260.0}
- equation: C2H5CHO + H => C2H5 + CO + H2  # Reaction 595
  rate-constant: {A: 4.1e+09, b: 1.16, Ea: 2405.0}
- equation: C2H5CHO + O => C2H5 + CO + OH  # Reaction 596
  rate-constant: {A: 7.8e+12, b: 0.0, Ea: 1730.0}
- equation: C2H5CHO + O2 => C2H5 + CO + HO2  # Reaction 597
  rate-constant: {A: 9.4359e+12, b: 0.0, Ea: 4.07e+04}
- equation: C2H5CHO + OH => C2H5 + CO + H2O  # Reaction 598
  rate-constant: {A: 5.94e+06, b: 1.98, Ea: -1635.0}
- equation: C2H5CHO + HO2 => C2H5 + CO + H2O2  # Reaction 599
  rate-constant: {A: 1.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H5CHO + CH3 => C2H5 + CH4 + CO  # Reaction 600
  rate-constant: {A: 2.61e+06, b: 1.78, Ea: 5911.0}
- equation: C2H5CHO + CH3O => C2H5 + CH3OH + CO  # Reaction 601
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 3300.0}
- equation: C2H5CHO + CH3O2 => C2H5 + CH3OOH + CO  # Reaction 602
  rate-constant: {A: 3.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H3 + C2H5CHO => C2H4 + C2H5 + CO  # Reaction 603
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: C2H5CHO + C2H5 => C2H6 + CO + C2H5  # Reaction 604
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 8000.0}
- equation: C2H5CHO + C2H5O2 => C2H5 + C2H5OOH + CO  # Reaction 605
  rate-constant: {A: 3.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H5CHO + C3H3 => C2H5 + CO + PC3H4  # Reaction 606
  rate-constant: {A: 6.3e+07, b: 1.8, Ea: 1.82e+04}
- equation: C2H5CHO + C3H5 => C2H5 + C3H6 + CO  # Reaction 607
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: C2H5CHO + NC3H7 => C2H5 + C3H8 + CO  # Reaction 608
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: C2H5CHO + IC3H7 => C2H5 + C3H8 + CO  # Reaction 609
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: C3H8 (+M) <=> C2H5 + CH3 (+M)  # Reaction 610
  type: falloff
  low-P-rate-constant: {A: 6.5284e+74, b: -15.74, Ea: 9.871e+04}
  high-P-rate-constant: {A: 1.4932e+37, b: -5.84, Ea: 9.738e+04}
  Troe: {A: 0.31, T3: 50.0, T1: 3000.0, T2: 9000.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + NC3H7 <=> C3H8  # Reaction 611
  rate-constant: {A: 8.1363e+13, b: 0.0, Ea: 0.0}
- equation: H + IC3H7 <=> C3H8  # Reaction 612
  rate-constant: {A: 8.4179e+13, b: 0.0, Ea: 0.0}
- equation: C3H8 + H <=> H2 + IC3H7  # Reaction 613
  rate-constant: {A: 9.6934e+05, b: 2.4, Ea: 4471.0}
- equation: C3H8 + H <=> H2 + NC3H7  # Reaction 614
  rate-constant: {A: 1.0905e+06, b: 2.54, Ea: 6757.0}
- equation: C3H8 + O <=> IC3H7 + OH  # Reaction 615
  rate-constant: {A: 5.49e+05, b: 2.5, Ea: 3140.0}
- equation: C3H8 + O <=> NC3H7 + OH  # Reaction 616
  rate-constant: {A: 3.71e+06, b: 2.4, Ea: 5505.0}
- equation: C3H8 + O2 <=> HO2 + IC3H7  # Reaction 617
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 4.964e+04}
- equation: C3H8 + O2 <=> HO2 + NC3H7  # Reaction 618
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 5.229e+04}
- equation: C3H8 + OH <=> H2O + NC3H7  # Reaction 619
  rate-constant: {A: 3.16e+07, b: 1.8, Ea: 934.0}
- equation: C3H8 + OH <=> H2O + IC3H7  # Reaction 620
  rate-constant: {A: 6.3801e+06, b: 1.9, Ea: -159.0}
- equation: C3H8 + HO2 <=> H2O2 + IC3H7  # Reaction 621
  rate-constant: {A: 63.2, b: 3.37, Ea: 1.372e+04}
- equation: C3H8 + HO2 <=> H2O2 + NC3H7  # Reaction 622
  rate-constant: {A: 40.8, b: 3.59, Ea: 1.716e+04}
- equation: C3H8 + CH3 <=> CH4 + IC3H7  # Reaction 623
  rate-constant: {A: 6.4e+04, b: 2.17, Ea: 7520.0}
- equation: C3H8 + CH3 <=> CH4 + NC3H7  # Reaction 624
  rate-constant: {A: 0.904, b: 3.65, Ea: 7154.0}
- equation: C3H8 + CH3O <=> CH3OH + NC3H7  # Reaction 625
  rate-constant: {A: 3.0e+11, b: 0.0, Ea: 7000.0}
- equation: C3H8 + CH3O <=> CH3OH + IC3H7  # Reaction 626
  rate-constant: {A: 3.0e+11, b: 0.0, Ea: 7000.0}
- equation: C3H8 + CH3O2 <=> CH3OOH + NC3H7  # Reaction 627
  rate-constant: {A: 1.39, b: 3.97, Ea: 1.828e+04}
- equation: C3H8 + CH3O2 <=> CH3OOH + IC3H7  # Reaction 628
  rate-constant: {A: 10.2, b: 3.58, Ea: 1.481e+04}
- equation: C2H3 + C3H8 <=> C2H4 + IC3H7  # Reaction 629
  rate-constant: {A: 244.0, b: 3.03, Ea: 4644.0}
- equation: C2H3 + C3H8 <=> C2H4 + NC3H7  # Reaction 630
  rate-constant: {A: 731.0, b: 3.03, Ea: 6144.0}
- equation: C2H5 + C3H8 <=> C2H6 + IC3H7  # Reaction 631
  rate-constant: {A: 284.0, b: 3.04, Ea: 1.0066e+04}
- equation: C2H5 + C3H8 <=> C2H6 + NC3H7  # Reaction 632
  rate-constant: {A: 158.0, b: 3.18, Ea: 1.2307e+04}
- equation: C2H5O2 + C3H8 <=> C2H5OOH + NC3H7  # Reaction 633
  rate-constant: {A: 1.39, b: 3.97, Ea: 1.828e+04}
- equation: C2H5O2 + C3H8 <=> C2H5OOH + IC3H7  # Reaction 634
  rate-constant: {A: 10.2, b: 3.58, Ea: 1.481e+04}
- equation: C3H8 + IC3H7 <=> C3H8 + NC3H7  # Reaction 635
  rate-constant: {A: 3.16e+10, b: 0.0, Ea: 1.29e+04}
- equation: NC3H7OOH (+M) => C2H5 + CH2O + OH (+M)  # Reaction 636
  type: falloff
  low-P-rate-constant: {A: 8.73e+67, b: -14.68, Ea: 5.225e+04}
  high-P-rate-constant: {A: 3.41e+16, b: 0.0, Ea: 4.041e+04}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: NC3H7OOH + O <=> NC3H7O2 + OH  # Reaction 637
  rate-constant: {A: 8.65e+12, b: 0.0, Ea: 4750.0}
- equation: NC3H7OOH + O => C2H5CHO + 2 OH  # Reaction 638
  rate-constant: {A: 1.61e+13, b: 0.0, Ea: 4750.0}
- equation: NC3H7OOH + OH <=> H2O + NC3H7O2  # Reaction 639
  rate-constant: {A: 1.08e+12, b: 0.0, Ea: -437.0}
- equation: NC3H7OOH + OH => C2H5CHO + H2O + OH  # Reaction 640
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: -258.0}
- equation: IC3H7OOH (+M) => CH3 + CH3CHO + OH (+M)  # Reaction 641
  type: falloff
  low-P-rate-constant: {A: 2.68e+68, b: -14.75, Ea: 5.42e+04}
  high-P-rate-constant: {A: 3.41e+16, b: 0.0, Ea: 4.231e+04}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: IC3H7OOH + O <=> IC3H7O2 + OH  # Reaction 642
  rate-constant: {A: 8.65e+12, b: 0.0, Ea: 4750.0}
- equation: IC3H7OOH + O => CH3COCH3 + 2 OH  # Reaction 643
  rate-constant: {A: 1.61e+13, b: 0.0, Ea: 4750.0}
- equation: IC3H7OOH + OH <=> H2O + IC3H7O2  # Reaction 644
  rate-constant: {A: 1.08e+12, b: 0.0, Ea: -437.0}
- equation: IC3H7OOH + OH => CH3COCH3 + H2O + OH  # Reaction 645
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: -258.0}
- equation: NC3H7 + O2 <=> NC3H7O2  # Reaction 646
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.04 atm, A: 6.9e+62, b: -16.57, Ea: 1.281e+04}
  - {P: 1.0 atm, A: 6.6e+52, b: -13.07, Ea: 1.103e+04}
  - {P: 10.0 atm, A: 3.72e+42, b: -9.67, Ea: 8523.0}
  - {P: 100.0 atm, A: 1.47e+28, b: -5.13, Ea: 4090.0}
- equation: NC3H7O2 => C2H4 + CH2O + OH  # Reaction 647
  duplicate: true
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 2.685e+04}
- equation: NC3H7O2 => C2H4 + CH2O + OH  # Reaction 648
  duplicate: true
  rate-constant: {A: 1.12e+11, b: 0.0, Ea: 2.44e+04}
- equation: H + NC3H7O2 => C2H5 + CH2O + OH  # Reaction 649
  rate-constant: {A: 9.64e+13, b: 0.0, Ea: 0.0}
- equation: H2 + NC3H7O2 <=> H + NC3H7OOH  # Reaction 650
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 2.603e+04}
- equation: NC3H7O2 + O => C2H5 + CH2O + O2  # Reaction 651
  rate-constant: {A: 1.22e+13, b: 0.0, Ea: -445.0}
- equation: NC3H7O2 + OH => C2H5 + CH2O + HO2  # Reaction 652
  rate-constant: {A: 1.69e+14, b: 0.0, Ea: 0.0}
- equation: HO2 + NC3H7O2 <=> NC3H7OOH + O2  # Reaction 653
  rate-constant: {A: 1.75e+10, b: 0.0, Ea: -3275.0}
- equation: CH2O + NC3H7O2 <=> HCO + NC3H7OOH  # Reaction 654
  rate-constant: {A: 5.6e+12, b: 0.0, Ea: 1.36e+04}
- equation: CH3 + NC3H7O2 => C2H5 + CH2O + CH3O  # Reaction 655
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: CH3O2 + NC3H7O2 => C2H5 + CH2O + CH3O + O2  # Reaction 656
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: CH4 + NC3H7O2 <=> CH3 + NC3H7OOH  # Reaction 657
  rate-constant: {A: 1.12e+13, b: 0.0, Ea: 2.464e+04}
- equation: C2H4 + NC3H7O2 <=> C2H3 + NC3H7OOH  # Reaction 658
  rate-constant: {A: 1.13e+13, b: 0.0, Ea: 3.043e+04}
- equation: C2H5 + NC3H7O2 => C2H5 + 2 CH2O + CH3  # Reaction 659
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: C2H5O2 + NC3H7O2 => C2H5 + 2 CH2O + CH3 + O2  # Reaction 660
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: C2H6 + NC3H7O2 <=> C2H5 + NC3H7OOH  # Reaction 661
  rate-constant: {A: 1.7e+13, b: 0.0, Ea: 2.046e+04}
- equation: C3H5 + NC3H7O2 => C2H3CHO + C2H5 + CH2O + H  # Reaction 662
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: C3H6 + NC3H7O2 <=> C3H5 + NC3H7OOH  # Reaction 663
  rate-constant: {A: 3.24e+11, b: 0.0, Ea: 1.49e+04}
- equation: IC3H7 + NC3H7O2 => C2H5 + CH2O + CH3 + CH3CHO  # Reaction 664
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: NC3H7 + NC3H7O2 => 2 C2H5 + 2 CH2O  # Reaction 665
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: 2 NC3H7O2 => 2 C2H5 + 2 CH2O + O2  # Reaction 666
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: C3H8 + NC3H7O2 <=> NC3H7 + NC3H7OOH  # Reaction 667
  rate-constant: {A: 1.7e+13, b: 0.0, Ea: 2.046e+04}
- equation: C3H8 + NC3H7O2 <=> IC3H7 + NC3H7OOH  # Reaction 668
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 1.7e+04}
- equation: IC3H7 + O2 <=> IC3H7O2  # Reaction 669
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.04 atm, A: 2.76e+67, b: -18.17, Ea: 1.2907e+04}
  - {P: 1.0 atm, A: 1.22e+63, b: -16.33, Ea: 1.3114e+04}
  - {P: 10.0 atm, A: 2.33e+56, b: -13.97, Ea: 1.194e+04}
  - {P: 100.0 atm, A: 5.73e+44, b: -10.21, Ea: 8750.0}
- equation: IC3H7O2 => CH2CHO + CH3 + OH  # Reaction 670
  rate-constant: {A: 1.6566e+12, b: 0.0, Ea: 2.94e+04}
- equation: H + IC3H7O2 => CH3 + CH3CHO + OH  # Reaction 671
  rate-constant: {A: 9.64e+13, b: 0.0, Ea: 0.0}
- equation: H2 + IC3H7O2 <=> H + IC3H7OOH  # Reaction 672
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 2.603e+04}
- equation: IC3H7O2 + O => CH3 + CH3CHO + O2  # Reaction 673
  rate-constant: {A: 1.22e+13, b: 0.0, Ea: -445.0}
- equation: IC3H7O2 + OH => CH3 + CH3CHO + HO2  # Reaction 674
  rate-constant: {A: 1.69e+14, b: 0.0, Ea: 0.0}
- equation: HO2 + IC3H7O2 <=> IC3H7OOH + O2  # Reaction 675
  rate-constant: {A: 1.75e+10, b: 0.0, Ea: -3275.0}
- equation: IC3H7O2 + CH3 => CH3CHO + CH3O + CH3  # Reaction 676
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: CH4 + IC3H7O2 <=> CH3 + IC3H7OOH  # Reaction 677
  rate-constant: {A: 1.12e+13, b: 0.0, Ea: 2.464e+04}
- equation: CH3O2 + IC3H7O2 => CH3 + CH3CHO + CH3O + O2  # Reaction 678
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: C2H4 + IC3H7O2 <=> C2H3 + IC3H7OOH  # Reaction 679
  rate-constant: {A: 1.13e+13, b: 0.0, Ea: 3.043e+04}
- equation: C2H5O2 + IC3H7O2 => CH2O + 2 CH3 + CH3CHO + O2  # Reaction 680
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: C2H6 + IC3H7O2 <=> C2H5 + IC3H7OOH  # Reaction 681
  rate-constant: {A: 1.7e+13, b: 0.0, Ea: 2.046e+04}
- equation: C3H5 + IC3H7O2 => C2H3CHO + CH3 + CH3CHO + H  # Reaction 682
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: C3H6 + IC3H7O2 <=> C3H5 + IC3H7OOH  # Reaction 683
  rate-constant: {A: 3.24e+11, b: 0.0, Ea: 1.49e+04}
- equation: IC3H7 + IC3H7O2 => 2 CH3 + 2 CH3CHO  # Reaction 684
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: IC3H7O2 + NC3H7 => C2H5 + CH2O + CH3 + CH3CHO  # Reaction 685
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1000.0}
- equation: IC3H7O2 + NC3H7O2 => C2H5 + CH2O + CH3 + CH3CHO + O2  # Reaction 686
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: 2 IC3H7O2 => 2 CH3 + 2 CH3CHO + O2  # Reaction 687
  rate-constant: {A: 1.4e+16, b: -1.61, Ea: 1860.0}
- equation: C3H8 + IC3H7O2 <=> IC3H7OOH + NC3H7  # Reaction 688
  rate-constant: {A: 1.7e+13, b: 0.0, Ea: 2.046e+04}
- equation: C3H8 + IC3H7O2 <=> IC3H7 + IC3H7OOH  # Reaction 689
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 1.7e+04}
- equation: C2H + C2H2 <=> C4H2 + H  # Reaction 690
  rate-constant: {A: 9.6e+13, b: 0.0, Ea: 0.0}
- equation: C4H2 + O <=> H2C4O  # Reaction 691
  rate-constant: {A: 4.1325e+13, b: 0.0, Ea: 1967.0}
- equation: C4H2 + OH <=> H + H2C4O  # Reaction 692
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: -410.0}
- equation: C4H2 + HO2 <=> H2C4O + OH  # Reaction 693
  rate-constant: {A: 6.0e+07, b: 1.6, Ea: 1.53e+04}
- equation: H + H2C4O <=> C2H2 + HCCO  # Reaction 694
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 3000.0}
- equation: H2C4O + O <=> 2 HCCO  # Reaction 695
  rate-constant: {A: 2.25e+13, b: 0.0, Ea: 1967.0}
- equation: H2C4O + OH <=> CH2CO + HCCO  # Reaction 696
  rate-constant: {A: 1.0e+07, b: 2.0, Ea: 2000.0}
- equation: H2C4O + HO2 => 2 HCCO + OH  # Reaction 697
  rate-constant: {A: 3.0e+07, b: 1.6, Ea: 1.53e+04}
- equation: CH3 + H2C4O <=> HCCO + PC3H4  # Reaction 698
  rate-constant: {A: 4.5e+06, b: 1.86, Ea: 1.16e+04}
- equation: C2H + C2H2 (+M) <=> NC4H3 (+M)  # Reaction 699
  type: falloff
  low-P-rate-constant: {A: 1.24e+31, b: -4.72, Ea: 1871.0}
  high-P-rate-constant: {A: 8.3e+10, b: 0.9, Ea: -363.0}
  Troe: {A: 1.0, T3: 100.0, T1: 5613.0, T2: 1.339e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C4H2 + H <=> NC4H3  # Reaction 700
  rate-constant: {A: 1.1e+42, b: -8.72, Ea: 1.53e+04}
- equation: H + NC4H3 <=> H + IC4H3  # Reaction 701
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.47e+17, b: -0.77, Ea: 3820.0}
  - {P: 1.0 atm, A: 1.27e+18, b: -0.91, Ea: 5650.0}
  - {P: 10.0 atm, A: 7.28e+13, b: 0.41, Ea: 5660.0}
  - {P: 100.0 atm, A: 8.92e+23, b: -2.42, Ea: 1.352e+04}
- equation: H + NC4H3 <=> C2H2 + H2CC  # Reaction 702
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 8.63e+24, b: -3.5, Ea: 4580.0}
  - {P: 1.0 atm, A: 9.17e+23, b: -3.15, Ea: 5820.0}
  - {P: 10.0 atm, A: 3.6e+18, b: -1.49, Ea: 5510.0}
  - {P: 100.0 atm, A: 6.0e+25, b: -3.51, Ea: 1.184e+04}
- equation: H + NC4H3 <=> C4H4  # Reaction 703
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.07e+54, b: -13.28, Ea: 1.052e+04}
  - {P: 1.0 atm, A: 2.32e+46, b: -10.36, Ea: 9290.0}
  - {P: 10.0 atm, A: 1.56e+37, b: -7.28, Ea: 7170.0}
  - {P: 100.0 atm, A: 6.21e+30, b: -5.2, Ea: 5450.0}
- equation: H + NC4H3 <=> C4H2 + H2  # Reaction 704
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: NC4H3 + OH <=> C4H2 + H2O  # Reaction 705
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 0.0}
- equation: NC4H3 + O <=> C2H2 + HCCO  # Reaction 706
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + NC4H3 => C2H2 + HCCO + OH  # Reaction 707
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + NC4H3 <=> C4H2 + CH4  # Reaction 708
  rate-constant: {A: 4.5e+12, b: 0.0, Ea: -765.0}
- equation: CH4 + NC4H3 <=> C4H4 + CH3  # Reaction 709
  rate-constant: {A: 1.62e+07, b: 1.59, Ea: 1.1406e+04}
- equation: NC4H3 <=> IC4H3  # Reaction 710
  rate-constant: {A: 4.1e+43, b: -9.49, Ea: 5.3e+04}
- equation: C2H + C2H2 (+M) <=> IC4H3 (+M)  # Reaction 711
  type: falloff
  low-P-rate-constant: {A: 1.24e+31, b: -4.72, Ea: 1871.0}
  high-P-rate-constant: {A: 8.3e+10, b: 0.9, Ea: -363.0}
  Troe: {A: 1.0, T3: 100.0, T1: 5613.0, T2: 1.339e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C4H2 + H <=> IC4H3  # Reaction 712
  rate-constant: {A: 1.1e+30, b: -4.92, Ea: 1.08e+04}
- equation: H + IC4H3 <=> C2H2 + H2CC  # Reaction 713
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 5.88e+26, b: -3.95, Ea: 7700.0}
  - {P: 1.0 atm, A: 2.51e+20, b: -2.02, Ea: 6890.0}
  - {P: 10.0 atm, A: 3.36e+28, b: -4.28, Ea: 1.462e+04}
  - {P: 100.0 atm, A: 2.5e+34, b: -5.86, Ea: 2.176e+04}
- equation: C3H3 + CH <=> H + IC4H3  # Reaction 714
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: H + IC4H3 <=> C4H2 + H2  # Reaction 715
  rate-constant: {A: 4.975e+13, b: 0.0, Ea: 0.0}
- equation: IC4H3 + OH <=> C4H2 + H2O  # Reaction 716
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 0.0}
- equation: IC4H3 + O2 <=> CH2CO + HCCO  # Reaction 717
  rate-constant: {A: 7.86e+16, b: -1.8, Ea: 0.0}
- equation: IC4H3 + O <=> H2CC + HCCO  # Reaction 718
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H3 => H2CC + HCCO + OH  # Reaction 719
  rate-constant: {A: 3.2229e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + IC4H3 <=> C4H2 + CH4  # Reaction 720
  rate-constant: {A: 7.5063e+12, b: 0.0, Ea: -765.0}
- equation: CH4 + IC4H3 <=> C4H4 + CH3  # Reaction 721
  rate-constant: {A: 3.4888e+07, b: 1.59, Ea: 1.1406e+04}
- equation: C2H2 + H2CC (+M) <=> C4H4 (+M)  # Reaction 722
  type: falloff
  low-P-rate-constant: {A: 1.4e+60, b: -12.6, Ea: 1.132e+04}
  high-P-rate-constant: {A: 3.5e+05, b: 2.06, Ea: 1500.0}
  Troe: {A: 0.98, T3: 56.0, T1: 580.0, T2: 4164.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H3 <=> C4H4  # Reaction 723
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.4e+44, b: -9.77, Ea: 8974.0}
  - {P: 1.0 atm, A: 2.88e+36, b: -7.13, Ea: 7080.0}
  - {P: 10.0 atm, A: 7.38e+28, b: -4.67, Ea: 5000.0}
  - {P: 100.0 atm, A: 1.54e+24, b: -3.17, Ea: 3640.0}
- equation: C4H4 + H <=> H2 + NC4H3  # Reaction 724
  rate-constant: {A: 6.65e+05, b: 2.53, Ea: 1.224e+04}
- equation: C4H4 + H <=> H2 + IC4H3  # Reaction 725
  rate-constant: {A: 3.33e+05, b: 2.53, Ea: 9240.0}
- equation: C2H2 + C2H3 <=> C4H4 + H  # Reaction 726
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.026 atm, A: 5.3075e+14, b: -0.71, Ea: 6700.0}
  - {P: 1.0 atm, A: 2.123e+18, b: -1.68, Ea: 1.06e+04}
  - {P: 10.0 atm, A: 5.2014e+16, b: -1.13, Ea: 1.18e+04}
  - {P: 100.0 atm, A: 6.1142e+20, b: -2.26, Ea: 1.525e+04}
- equation: C2H + C2H4 <=> C4H4 + H  # Reaction 727
  rate-constant: {A: 8.43e+13, b: 0.0, Ea: 0.0}
- equation: C3H3 + CH2 <=> C4H4 + H  # Reaction 728
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: C4H4 + O <=> C3H3 + HCO  # Reaction 729
  rate-constant: {A: 6.0e+08, b: 1.45, Ea: -860.0}
- equation: C4H4 + OH <=> H2O + NC4H3  # Reaction 730
  rate-constant: {A: 3.1e+07, b: 2.0, Ea: 3430.0}
- equation: C4H4 + OH <=> H2O + IC4H3  # Reaction 731
  rate-constant: {A: 1.55e+07, b: 2.0, Ea: 430.0}
- equation: C4H4 + HO2 => C3H3 + HCO + OH  # Reaction 732
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 1.4e+04}
- equation: C3H3 + HCCO <=> C4H4 + CO  # Reaction 733
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 0.0}
- equation: C2H2 + C2H3 <=> NC4H5  # Reaction 734
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.026 atm, A: 1.1e+32, b: -7.33, Ea: 6200.0}
  - {P: 1.0 atm, A: 9.3e+38, b: -8.76, Ea: 1.2e+04}
  - {P: 10.0 atm, A: 8.1e+37, b: -8.09, Ea: 1.34e+04}
  - {P: 100.0 atm, A: 8.1e+37, b: -7.7, Ea: 1.622e+04}
- equation: C4H4 + H (+M) <=> NC4H5 (+M)  # Reaction 735
  type: falloff
  low-P-rate-constant: {A: 4.3854e+44, b: -8.85, Ea: 900.0}
  high-P-rate-constant: {A: 2.2822e+10, b: 0.88, Ea: 1100.0}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + NC4H5 <=> C4H4 + H2  # Reaction 736
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 0.0}
- equation: H + NC4H5 <=> 2 C2H3  # Reaction 737
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 6.15e+26, b: -3.35, Ea: 1.394e+04}
  - {P: 1.0 atm, A: 4.45e+31, b: -4.7, Ea: 1.807e+04}
  - {P: 10.0 atm, A: 2.7e+32, b: -4.82, Ea: 2.12e+04}
  - {P: 50.0 atm, A: 1.69e+25, b: -2.68, Ea: 1.925e+04}
- equation: H + NC4H5 <=> C3H3 + CH3  # Reaction 738
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 8.36e+30, b: -5.37, Ea: 5880.0}
  - {P: 1.0 atm, A: 1.7e+34, b: -6.31, Ea: 8820.0}
  - {P: 10.0 atm, A: 3.26e+46, b: -9.72, Ea: 1.92e+04}
  - {P: 50.0 atm, A: 1.3e+23, b: -2.88, Ea: 9210.0}
- equation: H + NC4H5 <=> H + IC4H5  # Reaction 739
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 1.59e+17, b: -1.27, Ea: 4330.0}
  - {P: 1.0 atm, A: 8.14e+19, b: -2.03, Ea: 6850.0}
  - {P: 10.0 atm, A: 5.65e+13, b: -0.15, Ea: 6190.0}
  - {P: 50.0 atm, A: 1.14e+19, b: -1.53, Ea: 1.33e+04}
- equation: NC4H5 + O <=> C2H3 + CH2CO  # Reaction 740
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: NC4H5 + OH <=> C4H4 + H2O  # Reaction 741
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 0.0}
- equation: NC4H5 + O2 <=> CH2CHCHCHO + O  # Reaction 742
  rate-constant: {A: 4.0492e+11, b: 0.29, Ea: 11.0}
- equation: NC4H5 + O2 <=> C2H3CHO + HCO  # Reaction 743
  rate-constant: {A: 7.6351e+16, b: -1.39, Ea: 1010.0}
- equation: HO2 + NC4H5 => C2H3 + CH2CO + OH  # Reaction 744
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 0.0}
- equation: HO2 + NC4H5 <=> C4H6 + O2  # Reaction 745
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 0.0}
- equation: H2O2 + NC4H5 <=> C4H6 + HO2  # Reaction 746
  rate-constant: {A: 1.21e+10, b: 0.0, Ea: -596.0}
- equation: HCO + NC4H5 <=> C4H6 + CO  # Reaction 747
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 0.0}
- equation: CH3 + NC4H5 <=> C4H4 + CH4  # Reaction 748
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: -765.0}
- equation: NC4H5 <=> IC4H5  # Reaction 749
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.026 atm, A: 1.3e+62, b: -16.38, Ea: 4.96e+04}
  - {P: 1.0 atm, A: 1.5e+67, b: -16.89, Ea: 5.91e+04}
  - {P: 10.0 atm, A: 2.0e+60, b: -14.46, Ea: 5.86e+04}
  - {P: 100.0 atm, A: 3.57e+45, b: -9.88, Ea: 5.395e+04}
- equation: C2H2 + C2H3 <=> IC4H5  # Reaction 750
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.026 atm, A: 2.1e+36, b: -8.78, Ea: 9100.0}
  - {P: 1.0 atm, A: 1.6e+46, b: -10.98, Ea: 1.86e+04}
  - {P: 10.0 atm, A: 5.1e+53, b: -12.64, Ea: 2.88e+04}
  - {P: 100.0 atm, A: 1.45e+56, b: -12.87, Ea: 3.55e+04}
- equation: C4H4 + H (+M) <=> IC4H5 (+M)  # Reaction 751
  type: falloff
  low-P-rate-constant: {A: 2.5173e+46, b: -9.19, Ea: -200.0}
  high-P-rate-constant: {A: 6.5449e+10, b: 0.86, Ea: 1200.0}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H5 <=> C3H3 + CH3  # Reaction 752
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 7.95e+11, b: 0.76, Ea: 330.0}
  - {P: 1.0 atm, A: 9.92e+13, b: 0.16, Ea: 2145.0}
  - {P: 10.0 atm, A: 1.21e+19, b: -1.3, Ea: 5410.0}
  - {P: 50.0 atm, A: 7.08e+12, b: 0.62, Ea: 4520.0}
- equation: H + IC4H5 <=> C4H4 + H2  # Reaction 753
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: 2 C2H3 <=> H + IC4H5  # Reaction 754
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 6.94e+15, b: -1.1, Ea: 3570.0}
  - {P: 1.0 atm, A: 4.0e+13, b: -0.37, Ea: 4340.0}
  - {P: 10.0 atm, A: 4.73e+06, b: 1.73, Ea: 3490.0}
  - {P: 50.0 atm, A: 1.61e+34, b: -6.02, Ea: 2.4e+04}
- equation: IC4H5 + O <=> C2H3 + CH2CO  # Reaction 755
  rate-constant: {A: 2.8138e+13, b: 0.0, Ea: 0.0}
- equation: IC4H5 + OH <=> C4H4 + H2O  # Reaction 756
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 0.0}
- equation: IC4H5 + O2 <=> CH2CHO + CH2CO  # Reaction 757
  rate-constant: {A: 2.16e+10, b: 0.0, Ea: 2500.0}
- equation: HO2 + IC4H5 <=> C4H6 + O2  # Reaction 758
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H5 => C2H3 + CH2CO + OH  # Reaction 759
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 0.0}
- equation: H2O2 + IC4H5 <=> C4H6 + HO2  # Reaction 760
  rate-constant: {A: 1.21e+10, b: 0.0, Ea: -596.0}
- equation: HCO + IC4H5 <=> C4H6 + CO  # Reaction 761
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 0.0}
- equation: CH3 + IC4H5 <=> C4H4 + CH4  # Reaction 762
  rate-constant: {A: 8.5112e+12, b: 0.0, Ea: -765.0}
- equation: C4H5-2 <=> IC4H5  # Reaction 763
  rate-constant: {A: 1.2458e+67, b: -16.89, Ea: 5.91e+04}
- equation: C4H5-2 + H <=> C3H3 + CH3  # Reaction 764
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 8.3696e+17, b: -0.94, Ea: 3930.0}
  - {P: 1.0 atm, A: 3.1246e+24, b: -2.76, Ea: 9360.0}
  - {P: 10.0 atm, A: 9.8575e+26, b: -3.36, Ea: 1.36e+04}
  - {P: 50.0 atm, A: 3.0409e+31, b: -4.52, Ea: 1.98e+04}
- equation: C4H5-2 + H <=> C4H6-2  # Reaction 765
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 1.48e+64, b: -16.42, Ea: 1.4e+04}
  - {P: 1.0 atm, A: 4.3e+70, b: -17.7, Ea: 2.047e+04}
  - {P: 10.0 atm, A: 1.88e+85, b: -21.4, Ea: 3.14e+04}
  - {P: 50.0 atm, A: 9.05e+61, b: -14.38, Ea: 2.12e+04}
- equation: C4H5-2 + O <=> CH3CO + H2CC  # Reaction 766
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: C4H5-2 + O2 <=> CH2CO + CH3CO  # Reaction 767
  rate-constant: {A: 2.16e+10, b: 0.0, Ea: 2500.0}
- equation: C4H5-2 + HO2 => C2H2 + CH3CO + OH  # Reaction 768
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 0.0}
- equation: 2 C2H3 <=> C4H6  # Reaction 769
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 1.9473e+26, b: -4.24, Ea: 3376.0}
  - {P: 0.066 atm, A: 4.6757e+35, b: -8.11, Ea: 5270.0}
  - {P: 1.0 atm, A: 2.7605e+32, b: -5.88, Ea: 6050.0}
  - {P: 10.0 atm, A: 1.055e+26, b: -3.8, Ea: 4310.0}
  - {P: 50.0 atm, A: 3.7448e+21, b: -2.38, Ea: 2950.0}
- equation: C2H4 + H2CC <=> C4H6  # Reaction 770
  rate-constant: {A: 1.5732e+12, b: 0.0, Ea: 0.0}
- equation: C3H3 + CH3 <=> C4H6  # Reaction 771
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 3.6e+54, b: -13.0, Ea: 1.696e+04}
  - {P: 1.0 atm, A: 4.8e+59, b: -14.3, Ea: 2.32e+04}
  - {P: 10.0 atm, A: 3.88e+41, b: -8.73, Ea: 1.87e+04}
  - {P: 50.0 atm, A: 8.0e+51, b: -11.51, Ea: 2.92e+04}
- equation: C4H6 <=> C4H4 + H2  # Reaction 772
  rate-constant: {A: 2.5e+15, b: 0.0, Ea: 9.47e+04}
- equation: H + NC4H5 <=> C4H6  # Reaction 773
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 2.9e+46, b: -10.9, Ea: 8340.0}
  - {P: 1.0 atm, A: 2.87e+42, b: -9.2, Ea: 8280.0}
  - {P: 10.0 atm, A: 1.9e+46, b: -10.16, Ea: 1.04e+04}
  - {P: 50.0 atm, A: 1.42e+37, b: -7.24, Ea: 7760.0}
- equation: H + IC4H5 <=> C4H6  # Reaction 774
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 6.07e+53, b: -12.79, Ea: 1.174e+04}
  - {P: 1.0 atm, A: 3.9e+32, b: -5.91, Ea: 5970.0}
  - {P: 10.0 atm, A: 3.88e+37, b: -7.35, Ea: 8100.0}
  - {P: 50.0 atm, A: 2.22e+30, b: -5.06, Ea: 5890.0}
- equation: C4H6 + H <=> H2 + NC4H5  # Reaction 775
  rate-constant: {A: 1.4859e+06, b: 2.53, Ea: 1.224e+04}
- equation: C4H6 + H <=> H2 + IC4H5  # Reaction 776
  rate-constant: {A: 5.0252e+05, b: 2.53, Ea: 9240.0}
- equation: C4H6 + H <=> CH3 + PC3H4  # Reaction 777
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 7000.0}
- equation: C4H6 + H <=> AC3H4 + CH3  # Reaction 778
  rate-constant: {A: 1.8744e+12, b: 0.0, Ea: 7000.0}
- equation: C2H3 + C2H4 <=> C4H6 + H  # Reaction 779
  rate-constant: {A: 1.6733e+05, b: 2.14, Ea: 2740.0}
- equation: C4H6 + O <=> NC4H5 + OH  # Reaction 780
  rate-constant: {A: 8.193e+06, b: 1.9, Ea: 3740.0}
- equation: C4H6 + O <=> IC4H5 + OH  # Reaction 781
  rate-constant: {A: 7.5e+06, b: 1.9, Ea: 3740.0}
- equation: C4H6 + O <=> CH3CHCHCO + H  # Reaction 782
  rate-constant: {A: 1.5e+08, b: 1.45, Ea: -860.0}
- equation: C4H6 + O <=> CH2CHCHCHO + H  # Reaction 783
  rate-constant: {A: 4.5e+08, b: 1.45, Ea: -860.0}
- equation: C4H6 + OH <=> H2O + NC4H5  # Reaction 784
  rate-constant: {A: 7.2742e+06, b: 2.0, Ea: 3430.0}
- equation: C4H6 + OH <=> H2O + IC4H5  # Reaction 785
  rate-constant: {A: 2.1328e+06, b: 2.0, Ea: 430.0}
- equation: C4H6 + HO2 <=> C2H3COCH3 + OH  # Reaction 786
  rate-constant: {A: 6.7888e+12, b: 0.0, Ea: 1.4e+04}
- equation: C2H3 + C2H3CHO <=> C4H6 + HCO  # Reaction 787
  rate-constant: {A: 2.8e+21, b: -2.44, Ea: 1.472e+04}
- equation: C2H3 + C3H6 <=> C4H6 + CH3  # Reaction 788
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: 5000.0}
- equation: C4H6 + CH3 <=> CH4 + NC4H5  # Reaction 789
  rate-constant: {A: 2.1864e+14, b: 0.0, Ea: 2.28e+04}
- equation: C4H6 + CH3 <=> CH4 + IC4H5  # Reaction 790
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 1.98e+04}
- equation: C2H3 + C4H6 <=> C2H4 + NC4H5  # Reaction 791
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 2.28e+04}
- equation: C2H3 + C4H6 <=> C2H4 + IC4H5  # Reaction 792
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 1.98e+04}
- equation: C3H3 + C4H6 <=> AC3H4 + NC4H5  # Reaction 793
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 2.25e+04}
- equation: C3H3 + C4H6 <=> AC3H4 + IC4H5  # Reaction 794
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 1.95e+04}
- equation: C3H5 + C4H6 <=> C3H6 + NC4H5  # Reaction 795
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 2.25e+04}
- equation: C3H5 + C4H6 <=> C3H6 + IC4H5  # Reaction 796
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 1.95e+04}
- equation: 2 C2H3 <=> C4H612  # Reaction 797
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 1.0 atm, A: 2.8e+39, b: -9.06, Ea: 7300.0}
  - {P: 10.0 atm, A: 4.41e+31, b: -6.46, Ea: 6210.0}
  - {P: 50.0 atm, A: 1.6e+18, b: -2.18, Ea: 3110.0}
- equation: C3H3 + CH3 <=> C4H612  # Reaction 798
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 1.3103e+44, b: -9.88, Ea: 8350.0}
  - {P: 1.0 atm, A: 2.6946e+48, b: -11.0, Ea: 1.086e+04}
  - {P: 10.0 atm, A: 1.7435e+26, b: -3.96, Ea: 4100.0}
  - {P: 50.0 atm, A: 3.3814e+14, b: -0.22, Ea: 675.0}
- equation: H + NC4H5 <=> C4H612  # Reaction 799
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 2.6e+46, b: -12.13, Ea: 7550.0}
  - {P: 1.0 atm, A: 4.33e+34, b: -7.59, Ea: 5365.0}
  - {P: 10.0 atm, A: 5.2e+29, b: -5.79, Ea: 5450.0}
  - {P: 50.0 atm, A: 2.0e+22, b: -3.33, Ea: 4500.0}
- equation: H + IC4H5 <=> C4H612  # Reaction 800
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 7.82e+44, b: -11.0, Ea: 6100.0}
  - {P: 1.0 atm, A: 1.06e+50, b: -12.2, Ea: 8390.0}
  - {P: 10.0 atm, A: 1.62e+53, b: -12.8, Ea: 1.07e+04}
  - {P: 50.0 atm, A: 5.81e+18, b: -1.46, Ea: 2090.0}
- equation: C4H612 <=> C4H6  # Reaction 801
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 6.3e+04}
- equation: C4H612 + H <=> C4H6 + H  # Reaction 802
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 4000.0}
- equation: C4H612 + H <=> H2 + IC4H5  # Reaction 803
  rate-constant: {A: 1.7e+05, b: 2.5, Ea: 2490.0}
- equation: C4H612 + H <=> AC3H4 + CH3  # Reaction 804
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 2000.0}
- equation: C4H612 + H <=> CH3 + PC3H4  # Reaction 805
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 2000.0}
- equation: C4H612 + O <=> C2H4 + CH2CO  # Reaction 806
  rate-constant: {A: 1.2e+08, b: 1.65, Ea: 327.0}
- equation: C4H612 + O <=> IC4H5 + OH  # Reaction 807
  rate-constant: {A: 1.8e+11, b: 0.7, Ea: 5880.0}
- equation: C4H612 + OH <=> H2O + IC4H5  # Reaction 808
  rate-constant: {A: 3.1e+06, b: 2.0, Ea: -298.0}
- equation: C4H612 + HO2 <=> H2O2 + IC4H5  # Reaction 809
  rate-constant: {A: 2.7e+04, b: 2.5, Ea: 1.234e+04}
- equation: C4H612 + HO2 => C2H4 + CH2CO + OH  # Reaction 810
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 1.4e+04}
- equation: C4H612 + CH3 <=> CH4 + IC4H5  # Reaction 811
  rate-constant: {A: 7.0e+13, b: 0.0, Ea: 1.85e+04}
- equation: C2H3 + C4H612 <=> C2H4 + IC4H5  # Reaction 812
  rate-constant: {A: 2.21, b: 3.5, Ea: 4690.0}
- equation: C3H3 + CH3 <=> C4H6-2  # Reaction 813
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.066 atm, A: 1.0e+71, b: -17.5, Ea: 2.365e+04}
  - {P: 1.0 atm, A: 1.74e+36, b: -7.07, Ea: 7425.0}
  - {P: 10.0 atm, A: 3.49e+40, b: -8.03, Ea: 1.235e+04}
  - {P: 50.0 atm, A: 2.32e+21, b: -2.36, Ea: 2930.0}
- equation: C4H6-2 <=> C4H6  # Reaction 814
  rate-constant: {A: 2.7714e+13, b: 0.0, Ea: 6.5e+04}
- equation: C4H6-2 <=> C4H612  # Reaction 815
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 6.7e+04}
- equation: C4H6-2 + H <=> C4H612 + H  # Reaction 816
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 4000.0}
- equation: C4H6-2 + H <=> C4H5-2 + H2  # Reaction 817
  rate-constant: {A: 3.4e+05, b: 2.5, Ea: 2490.0}
- equation: C4H6-2 + H <=> CH3 + PC3H4  # Reaction 818
  rate-constant: {A: 2.6e+05, b: 2.5, Ea: 1000.0}
- equation: C4H6-2 + O => C2H3 + CH3 + CO  # Reaction 819
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 1659.0}
- equation: C4H6-2 + OH <=> C4H5-2 + H2O  # Reaction 820
  rate-constant: {A: 9.84e+12, b: 0.0, Ea: 483.0}
- equation: C4H6-2 + HO2 <=> C4H5-2 + H2O2  # Reaction 821
  rate-constant: {A: 1.8e+04, b: 2.5, Ea: 1.234e+04}
- equation: C4H6-2 + HO2 => C2H3 + CH3 + CO + OH  # Reaction 822
  rate-constant: {A: 3.0e+12, b: 0.0, Ea: 1.9e+04}
- equation: C4H6-2 + CH3 <=> C4H5-2 + CH4  # Reaction 823
  rate-constant: {A: 1.4e+14, b: 0.0, Ea: 1.85e+04}
- equation: C2H3 + C4H6-2 <=> C2H4 + C4H5-2  # Reaction 824
  rate-constant: {A: 4.42, b: 3.5, Ea: 4690.0}
- equation: CH3CHCHCHO <=> C3H6 + CO  # Reaction 825
  rate-constant: {A: 3.9e+14, b: 0.0, Ea: 6.9e+04}
- equation: CH3CHCHCHO + H <=> CH2CHCHCHO + H2  # Reaction 826
  rate-constant: {A: 1.7e+05, b: 2.5, Ea: 2490.0}
- equation: CH3CHCHCHO + H <=> CH3CHCHCO + H2  # Reaction 827
  rate-constant: {A: 1.0e+05, b: 2.5, Ea: 2490.0}
- equation: CH3CHCHCHO + H <=> C2H3CHO + CH3  # Reaction 828
  rate-constant: {A: 4.0e+21, b: -2.39, Ea: 1.118e+04}
- equation: CH3CHCHCHO + H <=> C3H6 + HCO  # Reaction 829
  rate-constant: {A: 4.0e+21, b: -2.39, Ea: 1.118e+04}
- equation: CH3CHCHCHO + O => C3H5 + CO + OH  # Reaction 830
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 1979.0}
- equation: CH3CHCHCHO + OH <=> CH2CHCHCHO + H2O  # Reaction 831
  rate-constant: {A: 1.65e+07, b: 1.8, Ea: 954.0}
- equation: CH3CHCHCHO + OH <=> CH3CHCHCO + H2O  # Reaction 832
  rate-constant: {A: 1.02e+13, b: 0.0, Ea: 0.0}
- equation: CH3CHCHCHO + HO2 => C3H5 + CO + H2O2  # Reaction 833
  rate-constant: {A: 1.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: CH3 + CH3CHCHCHO <=> CH2CHCHCHO + CH4  # Reaction 834
  rate-constant: {A: 2.1, b: 3.5, Ea: 5675.0}
- equation: CH3 + CH3CHCHCHO <=> CH3CHCHCO + CH4  # Reaction 835
  rate-constant: {A: 1.1, b: 3.05, Ea: 5675.0}
- equation: C2H3 + CH3CHCHCHO <=> C2H4 + CH2CHCHCHO  # Reaction 836
  rate-constant: {A: 2.21, b: 3.5, Ea: 4682.0}
- equation: C2H3 + CH3CHCHCHO <=> C2H4 + CH3CHCHCO  # Reaction 837
  rate-constant: {A: 1.11, b: 3.5, Ea: 4682.0}
- equation: CH3CHCHCO <=> C3H5 + CO  # Reaction 838
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 3.0e+04}
- equation: CH3CHCHCO + H <=> CH3CHCHCHO  # Reaction 839
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 0.0}
- equation: CH2CHCHCHO <=> C3H5 + CO  # Reaction 840
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 2.5e+04}
- equation: CH2CHCHCHO + H <=> CH3CHCHCHO  # Reaction 841
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 0.0}
- equation: C4H6 + H <=> C4H7  # Reaction 842
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 6.5622e+52, b: -12.09, Ea: 1.76e+04}
  - {P: 1.0 atm, A: 4.1276e+45, b: -9.7, Ea: 1.599e+04}
  - {P: 10.0 atm, A: 4.7457e+35, b: -6.57, Ea: 1.258e+04}
  - {P: 100.0 atm, A: 1.7499e+15, b: -0.44, Ea: 3520.0}
- equation: C4H7 + H <=> C3H5 + CH3  # Reaction 843
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.51e+32, b: -5.0, Ea: 1.32e+04}
  - {P: 1.0 atm, A: 1.1295e+33, b: -5.1, Ea: 1.646e+04}
  - {P: 10.0 atm, A: 7.8438e+43, b: -8.11, Ea: 2.64e+04}
  - {P: 100.0 atm, A: 9.6845e+36, b: -6.0, Ea: 2.626e+04}
- equation: C4H7 + H <=> C4H6 + H2  # Reaction 844
  rate-constant: {A: 1.8e+12, b: 0.0, Ea: 0.0}
- equation: C4H7 + O <=> C3H5 + CH2O  # Reaction 845
  rate-constant: {A: 4.42e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + OH <=> C4H6 + H2O  # Reaction 846
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + O2 <=> C4H6 + HO2  # Reaction 847
  rate-constant: {A: 5.8541e+10, b: 0.0, Ea: 0.0}
- equation: C4H7 + HO2 => C3H5 + CH2O + OH  # Reaction 848
  rate-constant: {A: 2.7388e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + HCO <=> C4H81 + CO  # Reaction 849
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + CH3 <=> C4H6 + CH4  # Reaction 850
  rate-constant: {A: 1.2154e+13, b: 0.0, Ea: 0.0}
- equation: AC3H4 + CH3 (+M) <=> IC4H7 (+M)  # Reaction 851
  type: falloff
  low-P-rate-constant: {A: 1.4361e+89, b: -21.18, Ea: 4.2e+04}
  high-P-rate-constant: {A: 5537.3, b: 2.92, Ea: 7448.0}
  Troe: {A: 2.3, T3: 1196.0, T1: 466.0, T2: 689.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H7 <=> C3H5 + CH3  # Reaction 852
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 5.4e+42, b: -8.0, Ea: 2.425e+04}
  - {P: 1.0 atm, A: 4.6e+47, b: -9.16, Ea: 3.34e+04}
  - {P: 10.0 atm, A: 2.0e+59, b: -12.3, Ea: 4.81e+04}
  - {P: 100.0 atm, A: 2.0e+05, b: 3.0, Ea: 1.8e+04}
- equation: H + IC4H7 => C4H612 + H2  # Reaction 853
  rate-constant: {A: 1.41e+07, b: 1.72, Ea: 1.079e+04}
- equation: H + IC4H7 <=> AC3H4 + CH4  # Reaction 854
  rate-constant: {A: 1232.0, b: 3.035, Ea: 2582.0}
- equation: IC4H7 + O <=> CH2O + CH3CCH2  # Reaction 855
  rate-constant: {A: 9.6653e+13, b: 0.0, Ea: 0.0}
- equation: IC4H7 + OH <=> CH2OH + CH3CCH2  # Reaction 856
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 1.2e+04}
- equation: IC4H7 + O2 => AC3H4 + CH2O + OH  # Reaction 857
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 10.0e-05 atm, A: 7.0359e+29, b: -5.32, Ea: 2.6224e+04}
  - {P: 0.001 atm, A: 6.6874e+29, b: -5.31, Ea: 2.6201e+04}
  - {P: 0.01 atm, A: 3.3354e+30, b: -5.51, Ea: 2.6575e+04}
  - {P: 0.079 atm, A: 1.7839e+36, b: -7.09, Ea: 3.1267e+04}
  - {P: 0.1 atm, A: 1.676e+36, b: -7.07, Ea: 3.1462e+04}
  - {P: 1.0 atm, A: 1.1367e+34, b: -6.31, Ea: 3.312e+04}
  - {P: 10.0 atm, A: 8.8778e+27, b: -4.38, Ea: 3.396e+04}
- equation: HO2 + IC4H7 <=> CH2O + CH3CCH2 + OH  # Reaction 858
  rate-constant: {A: 7.989e+12, b: 0.0, Ea: 0.0}
- equation: IC4H7-1 <=> IC4H7  # Reaction 859
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 6.107e+54, b: -14.51, Ea: 5.072e+04}
  - {P: 1.0 atm, A: 2.349e+51, b: -13.0, Ea: 5.022e+04}
  - {P: 10.0 atm, A: 4.557e+48, b: -11.71, Ea: 5.062e+04}
  - {P: 100.0 atm, A: 5.168e+43, b: -9.82, Ea: 5.032e+04}
- equation: CH3 + PC3H4 <=> IC4H7-1  # Reaction 860
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.4e+32, b: -7.14, Ea: 1.0e+04}
  - {P: 1.0 atm, A: 3.2e+35, b: -7.76, Ea: 1.33e+04}
  - {P: 10.0 atm, A: 2.4e+38, b: -8.21, Ea: 1.71e+04}
  - {P: 100.0 atm, A: 1.4e+39, b: -8.06, Ea: 2.02e+04}
- equation: H + IC4H7-1 <=> H + IC4H7  # Reaction 861
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 3.47e+16, b: -0.84, Ea: 711.0}
  - {P: 0.01 atm, A: 453.0, b: 2.94, Ea: -4342.0}
  - {P: 0.1 atm, A: 1.47e+21, b: -2.26, Ea: 3180.0}
  - {P: 0.1 atm, A: 3.31e+11, b: 0.59, Ea: -749.0}
  - {P: 1.0 atm, A: 1.75e+30, b: -4.82, Ea: 1.0284e+04}
  - {P: 1.0 atm, A: 1.59e+13, b: 0.16, Ea: 963.0}
  - {P: 10.0 atm, A: 7.23e+28, b: -4.17, Ea: 1.3614e+04}
  - {P: 10.0 atm, A: 1.24e+10, b: 0.98, Ea: 842.0}
  - {P: 100.0 atm, A: 3.74e+28, b: -3.92, Ea: 1.8561e+04}
  - {P: 100.0 atm, A: 1.36e+06, b: 2.06, Ea: 447.0}
- equation: H + IC4H7-1 <=> CH3 + CH3CCH2  # Reaction 862
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 1.43e+16, b: -0.59, Ea: 4573.0}
  - {P: 0.01 atm, A: 4.31e+13, b: -0.01, Ea: 435.0}
  - {P: 0.1 atm, A: 1.76e+15, b: -0.314, Ea: 3087.0}
  - {P: 0.1 atm, A: 9.21e+13, b: -0.22, Ea: 782.0}
  - {P: 1.0 atm, A: 2.09e+22, b: -2.34, Ea: 8157.0}
  - {P: 1.0 atm, A: 9.24e+09, b: 1.12, Ea: 844.0}
  - {P: 10.0 atm, A: 1.76e+25, b: -3.01, Ea: 1.3177e+04}
  - {P: 10.0 atm, A: 4.4e+08, b: 1.41, Ea: 1351.0}
  - {P: 100.0 atm, A: 9.72e+30, b: -4.44, Ea: 2.2834e+04}
  - {P: 100.0 atm, A: 6.46e+12, b: 0.22, Ea: 5469.0}
- equation: IC4H7-1 + O <=> C3H6 + HCO  # Reaction 863
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: IC4H7-1 + OH => C3H6 + H + HCO  # Reaction 864
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 0.0}
- equation: HCO + IC4H7-1 <=> CO + IC4H8  # Reaction 865
  rate-constant: {A: 9.0e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H7-1 => C3H6 + HCO + OH  # Reaction 866
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + C2H5 <=> C4H81  # Reaction 867
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 8.85e+52, b: -13.2, Ea: 1.03e+04}
  - {P: 1.0 atm, A: 1.03e+51, b: -12.2, Ea: 1.163e+04}
  - {P: 10.0 atm, A: 6.3e+40, b: -8.73, Ea: 9000.0}
  - {P: 100.0 atm, A: 2.2e+27, b: -4.43, Ea: 4850.0}
- equation: C3H5 + CH3 <=> C4H81  # Reaction 868
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 3.0488e+41, b: -8.84, Ea: 9250.0}
  - {P: 1.0 atm, A: 6.4635e+31, b: -5.75, Ea: 6250.0}
  - {P: 10.0 atm, A: 1.2306e+23, b: -3.0, Ea: 3350.0}
  - {P: 100.0 atm, A: 1.3082e+17, b: -1.14, Ea: 1290.0}
- equation: C4H7 + H <=> C4H81  # Reaction 869
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.4e+47, b: -10.6, Ea: 1.02e+04}
  - {P: 1.0 atm, A: 1.54e+39, b: -7.84, Ea: 8230.0}
  - {P: 10.0 atm, A: 2.3e+28, b: -4.4, Ea: 4735.0}
  - {P: 100.0 atm, A: 3.52e+20, b: -1.95, Ea: 2160.0}
- equation: C4H81 + H <=> C2H4 + C2H5  # Reaction 870
  rate-constant: {A: 8.0e+21, b: -2.39, Ea: 1.118e+04}
- equation: C4H81 + H <=> C3H6 + CH3  # Reaction 871
  rate-constant: {A: 1.8351e+22, b: -2.39, Ea: 1.118e+04}
- equation: C4H81 + H <=> C4H7 + H2  # Reaction 872
  rate-constant: {A: 8.04e+06, b: 2.11, Ea: 3380.0}
- equation: C4H81 + O <=> HCO + NC3H7  # Reaction 873
  rate-constant: {A: 3.3e+08, b: 1.45, Ea: -402.0}
- equation: C4H81 + O <=> C4H7 + OH  # Reaction 874
  duplicate: true
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 5760.0}
- equation: C4H81 + O <=> C4H7 + OH  # Reaction 875
  duplicate: true
  rate-constant: {A: 2.6e+13, b: 0.0, Ea: 4470.0}
- equation: C4H81 + OH <=> C4H7 + H2O  # Reaction 876
  rate-constant: {A: 4.2e+05, b: 2.4, Ea: -932.0}
- equation: C4H81 + O2 <=> C4H7 + HO2  # Reaction 877
  rate-constant: {A: 1.26e+12, b: 0.0, Ea: 3.49e+04}
- equation: C4H81 + HO2 <=> C4H7 + H2O2  # Reaction 878
  rate-constant: {A: 0.391, b: 3.97, Ea: 1.1702e+04}
- equation: C4H81 + HO2 => HCO + NC3H7 + OH  # Reaction 879
  rate-constant: {A: 1.69e+10, b: 0.51, Ea: 1.6606e+04}
- equation: C4H81 + CH3 <=> C4H7 + CH4  # Reaction 880
  rate-constant: {A: 161.0, b: 3.12, Ea: 5813.0}
- equation: C4H81 <=> C4H82  # Reaction 881
  rate-constant: {A: 2.42e+15, b: -0.22, Ea: 7.077e+04}
- equation: C4H7 + H <=> C4H82  # Reaction 882
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 2.8e+39, b: -8.0, Ea: 8330.0}
  - {P: 1.0 atm, A: 2.4e+28, b: -4.4, Ea: 4825.0}
  - {P: 10.0 atm, A: 1.04e+20, b: -1.8, Ea: 2000.0}
  - {P: 100.0 atm, A: 5.4e+15, b: -0.44, Ea: 500.0}
- equation: H + IC4H7 <=> C4H82  # Reaction 883
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.89e+28, b: -4.17, Ea: 1.194e+04}
  - {P: 1.0 atm, A: 6.6e+32, b: -5.3, Ea: 1.86e+04}
  - {P: 10.0 atm, A: 1.82e+30, b: -4.42, Ea: 2.11e+04}
  - {P: 100.0 atm, A: 4.0e+29, b: -4.23, Ea: 2.416e+04}
- equation: C4H82 + H <=> C4H7 + H2  # Reaction 884
  rate-constant: {A: 4.86e+06, b: 2.28, Ea: 4320.0}
- equation: C4H82 + H <=> C3H6 + CH3  # Reaction 885
  rate-constant: {A: 1.4434e+22, b: -2.39, Ea: 1.118e+04}
- equation: C4H82 + O <=> C2H4 + CH3CHO  # Reaction 886
  rate-constant: {A: 2.4e+08, b: 1.65, Ea: 327.0}
- equation: C4H82 + O <=> C4H7 + OH  # Reaction 887
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 4500.0}
- equation: C4H82 + OH <=> C4H7 + H2O  # Reaction 888
  rate-constant: {A: 3.88e+06, b: 2.23, Ea: 1073.0}
- equation: C4H82 + O2 <=> C4H7 + HO2  # Reaction 889
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 3.776e+04}
- equation: C4H82 + HO2 <=> C4H7 + H2O2  # Reaction 890
  rate-constant: {A: 0.345, b: 4.0, Ea: 1.2103e+04}
- equation: C4H82 + HO2 => C2H4 + CH3CHO + OH  # Reaction 891
  rate-constant: {A: 1.79e+08, b: 1.25, Ea: 1.237e+04}
- equation: C4H82 + CH3 <=> C4H7 + CH4  # Reaction 892
  rate-constant: {A: 276.57, b: 3.24, Ea: 7010.0}
- equation: H + IC4H7 <=> IC4H8  # Reaction 893
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.1 atm, A: 1.8582e+35, b: -6.6, Ea: 7000.0}
  - {P: 1.0 atm, A: 6.5707e+25, b: -3.6, Ea: 3970.0}
  - {P: 10.0 atm, A: 1.0249e+19, b: -1.47, Ea: 1655.0}
  - {P: 100.0 atm, A: 3.6397e+15, b: -0.4, Ea: 450.0}
- equation: H + IC4H7-1 <=> IC4H8  # Reaction 894
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 5.82e+56, b: -14.28, Ea: 1.6407e+04}
  - {P: 0.01 atm, A: 1.95e+45, b: -11.4, Ea: 6309.0}
  - {P: 0.1 atm, A: 1.24e+62, b: -15.22, Ea: 1.9112e+04}
  - {P: 0.1 atm, A: 2.65e+48, b: -11.75, Ea: 7584.0}
  - {P: 1.0 atm, A: 3.77e+60, b: -14.24, Ea: 2.0603e+04}
  - {P: 1.0 atm, A: 4.28e+42, b: -9.54, Ea: 6789.0}
  - {P: 10.0 atm, A: 9.1e+56, b: -12.74, Ea: 2.2284e+04}
  - {P: 10.0 atm, A: 4.44e+34, b: -6.79, Ea: 5170.0}
  - {P: 100.0 atm, A: 6.39e+49, b: -10.35, Ea: 2.1902e+04}
  - {P: 100.0 atm, A: 5.11e+26, b: -4.13, Ea: 3313.0}
  - {P: 1000.0 atm, A: 1.42e+14, b: -0.06, Ea: 24.0}
  - {P: 1000.0 atm, A: 4.42e+11, b: 0.65, Ea: -306.0}
- equation: CH3 + CH3CCH2 <=> IC4H8  # Reaction 895
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 2.1448e+61, b: -14.91, Ea: 1.9559e+04}
  - {P: 0.01 atm, A: 4.2008e+46, b: -11.15, Ea: 7332.0}
  - {P: 0.1 atm, A: 8.3237e+58, b: -13.81, Ea: 2.0442e+04}
  - {P: 0.1 atm, A: 3.1784e+40, b: -8.97, Ea: 6234.0}
  - {P: 1.0 atm, A: 1.0824e+56, b: -12.62, Ea: 2.193e+04}
  - {P: 1.0 atm, A: 8.0459e+33, b: -6.71, Ea: 4848.0}
  - {P: 10.0 atm, A: 8.5571e+50, b: -10.88, Ea: 2.2198e+04}
  - {P: 10.0 atm, A: 2.5338e+27, b: -4.53, Ea: 3329.0}
  - {P: 100.0 atm, A: 2.3004e+48, b: -9.9, Ea: 2.4315e+04}
  - {P: 100.0 atm, A: 6.0011e+23, b: -3.31, Ea: 2522.0}
- equation: H + IC4H8 <=> H2 + IC4H7  # Reaction 896
  rate-constant: {A: 4470.4, b: 3.08, Ea: 3540.0}
- equation: H + IC4H8 <=> H2 + IC4H7-1  # Reaction 897
  rate-constant: {A: 869.1, b: 3.247, Ea: 1.217e+04}
- equation: H + IC4H8 <=> C3H6 + CH3  # Reaction 898
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.01 atm, A: 4.3919e+13, b: 0.06, Ea: 6944.0}
  - {P: 0.1 atm, A: 1.1517e+16, b: -0.6, Ea: 9117.0}
  - {P: 1.0 atm, A: 6.1682e+16, b: -0.75, Ea: 1.097e+04}
  - {P: 10.0 atm, A: 5.9535e+13, b: 0.22, Ea: 1.156e+04}
  - {P: 100.0 atm, A: 1.2395e+06, b: 2.54, Ea: 1.035e+04}
  - {P: 1000.0 atm, A: 1.5616e-05, b: 5.77, Ea: 7702.0}
- equation: IC4H8 + O => CH2CO + 2 CH3  # Reaction 899
  rate-constant: {A: 1.2e+08, b: 1.65, Ea: 327.0}
- equation: IC4H8 + O <=> HCO + IC3H7  # Reaction 900
  rate-constant: {A: 3.7263e+07, b: 1.65, Ea: -972.0}
- equation: IC4H8 + O <=> IC4H7 + OH  # Reaction 901
  rate-constant: {A: 2.9e+05, b: 2.5, Ea: 3640.0}
- equation: IC4H8 + O <=> IC4H7-1 + OH  # Reaction 902
  rate-constant: {A: 1.2e+11, b: 0.7, Ea: 8959.1}
- equation: IC4H8 + OH <=> H2O + IC4H7  # Reaction 903
  rate-constant: {A: 3.6568e+07, b: 1.77, Ea: 271.4}
- equation: IC4H8 + OH <=> H2O + IC4H7-1  # Reaction 904
  rate-constant: {A: 1.25e+06, b: 2.16, Ea: 1414.0}
- equation: IC4H8 + O2 <=> HO2 + IC4H7  # Reaction 905
  rate-constant: {A: 9.7257e+17, b: -1.156, Ea: 4.5132e+04}
- equation: IC4H8 + O2 <=> HO2 + IC4H7-1  # Reaction 906
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 6.227e+04}
- equation: HO2 + IC4H8 <=> H2O2 + IC4H7  # Reaction 907
  rate-constant: {A: 0.292, b: 4.12, Ea: 1.28e+04}
- equation: HO2 + IC4H8 <=> H2O2 + IC4H7-1  # Reaction 908
  rate-constant: {A: 957.0, b: 3.059, Ea: 2.0799e+04}
- equation: HO2 + IC4H8 => CH2CO + 2 CH3 + OH  # Reaction 909
  rate-constant: {A: 5.3e+04, b: 2.1, Ea: 1.1797e+04}
- equation: CH3 + IC4H8 <=> CH4 + IC4H7  # Reaction 910
  rate-constant: {A: 135.91, b: 3.22, Ea: 7035.0}
- equation: CH3 + IC4H8 <=> CH4 + IC4H7-1  # Reaction 911
  rate-constant: {A: 719.0, b: 2.938, Ea: 1.3913e+04}
- equation: IC4H8 <=> C4H81  # Reaction 912
  rate-constant: {A: 5.7965e+14, b: -0.23, Ea: 7.736e+04}
- equation: IC4H8 <=> C4H82  # Reaction 913
  rate-constant: {A: 3.7005e+14, b: -0.22, Ea: 7.671e+04}
- equation: C4H81 + H (+M) <=> NC4H9 (+M)  # Reaction 914
  type: falloff
  low-P-rate-constant: {A: 6.26e+38, b: -6.66, Ea: 7000.0}
  high-P-rate-constant: {A: 2.5e+11, b: 0.51, Ea: 2620.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 1310.0, T2: 4.81e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C2H4 + C2H5 (+M) <=> NC4H9 (+M)  # Reaction 915
  type: falloff
  low-P-rate-constant: {A: 1.24e+46, b: -9.5, Ea: 9910.0}
  high-P-rate-constant: {A: 1.32e+04, b: 2.48, Ea: 6130.0}
  Troe: {A: 0.731, T3: 6945.0, T1: 165.0, T2: 9855.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + NC4H9 (+M) <=> C4H10 (+M)  # Reaction 916
  type: falloff
  low-P-rate-constant: {A: 1.1e+107, b: -28.15, Ea: 2.741e+04}
  high-P-rate-constant: {A: 3.6e+13, b: 0.0, Ea: 0.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + NC4H9 <=> 2 C2H5  # Reaction 917
  rate-constant: {A: 3.7e+24, b: -2.92, Ea: 1.2505e+04}
- equation: H + NC4H9 <=> C4H81 + H2  # Reaction 918
  rate-constant: {A: 1.8e+12, b: 0.0, Ea: 0.0}
- equation: NC4H9 + O <=> CH2O + NC3H7  # Reaction 919
  rate-constant: {A: 9.6e+13, b: 0.0, Ea: 0.0}
- equation: NC4H9 + OH <=> C4H81 + H2O  # Reaction 920
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: NC4H9 + O2 <=> C4H81 + HO2  # Reaction 921
  rate-constant: {A: 2.7e+11, b: 0.0, Ea: 0.0}
- equation: HO2 + NC4H9 => CH2O + NC3H7 + OH  # Reaction 922
  rate-constant: {A: 2.2528e+13, b: 0.0, Ea: 0.0}
- equation: HCO + NC4H9 <=> C4H10 + CO  # Reaction 923
  rate-constant: {A: 9.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + NC4H9 <=> C4H81 + CH4  # Reaction 924
  rate-constant: {A: 1.1e+13, b: 0.0, Ea: 0.0}
- equation: C4H81 + H (+M) <=> SC4H9 (+M)  # Reaction 925
  type: falloff
  low-P-rate-constant: {A: 1.8109e+53, b: -11.1, Ea: 5700.0}
  high-P-rate-constant: {A: 4.5166e+11, b: 0.51, Ea: 1230.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 645.4, T2: 6844.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C4H82 + H (+M) <=> SC4H9 (+M)  # Reaction 926
  type: falloff
  low-P-rate-constant: {A: 1.7e+53, b: -11.1, Ea: 5700.0}
  high-P-rate-constant: {A: 5.0e+11, b: 0.51, Ea: 2620.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 645.4, T2: 6844.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C3H6 + CH3 (+M) <=> SC4H9 (+M)  # Reaction 927
  type: falloff
  low-P-rate-constant: {A: 2.31e+28, b: -4.27, Ea: 1831.0}
  high-P-rate-constant: {A: 1.76e+04, b: 2.48, Ea: 6130.0}
  Troe: {A: 0.565, T3: 6.0e+04, T1: 534.2, T2: 3007.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + SC4H9 (+M) <=> C4H10 (+M)  # Reaction 928
  type: falloff
  low-P-rate-constant: {A: 1.1e+107, b: -28.15, Ea: 2.741e+04}
  high-P-rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + SC4H9 <=> 2 C2H5  # Reaction 929
  rate-constant: {A: 1.4e+28, b: -3.94, Ea: 1.5916e+04}
- equation: H + SC4H9 <=> C4H81 + H2  # Reaction 930
  rate-constant: {A: 3.2e+12, b: 0.0, Ea: 0.0}
- equation: H + SC4H9 <=> C4H82 + H2  # Reaction 931
  rate-constant: {A: 2.1e+12, b: 0.0, Ea: 0.0}
- equation: O + SC4H9 <=> C2H5 + CH3CHO  # Reaction 932
  rate-constant: {A: 9.6e+13, b: 0.0, Ea: 0.0}
- equation: OH + SC4H9 <=> C4H81 + H2O  # Reaction 933
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: OH + SC4H9 <=> C4H82 + H2O  # Reaction 934
  rate-constant: {A: 1.6e+13, b: 0.0, Ea: 0.0}
- equation: O2 + SC4H9 <=> C4H81 + HO2  # Reaction 935
  rate-constant: {A: 5.1e+10, b: 0.0, Ea: 0.0}
- equation: O2 + SC4H9 <=> C4H82 + HO2  # Reaction 936
  rate-constant: {A: 1.2e+11, b: 0.0, Ea: 0.0}
- equation: HO2 + SC4H9 => C2H5 + CH3CHO + OH  # Reaction 937
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: HCO + SC4H9 <=> C4H10 + CO  # Reaction 938
  rate-constant: {A: 1.2e+14, b: 0.0, Ea: 0.0}
- equation: CH3 + SC4H9 <=> C4H81 + CH4  # Reaction 939
  rate-constant: {A: 2.2e+14, b: -0.68, Ea: 0.0}
- equation: CH3 + SC4H9 <=> C4H82 + CH4  # Reaction 940
  rate-constant: {A: 1.5e+14, b: -0.68, Ea: 0.0}
- equation: H + IC4H8 (+M) <=> IC4H9 (+M)  # Reaction 941
  type: falloff
  low-P-rate-constant: {A: 6.26e+38, b: -6.66, Ea: 7000.0}
  high-P-rate-constant: {A: 6.25e+11, b: 0.51, Ea: 2620.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 1310.0, T2: 4.81e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C3H6 + CH3 (+M) <=> IC4H9 (+M)  # Reaction 942
  type: falloff
  low-P-rate-constant: {A: 1.3e+28, b: -4.27, Ea: 2431.0}
  high-P-rate-constant: {A: 1890.0, b: 2.67, Ea: 6830.0}
  Troe: {A: 0.565, T3: 6.0e+04, T1: 534.2, T2: 3007.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H9 (+M) <=> IC4H10 (+M)  # Reaction 943
  type: falloff
  low-P-rate-constant: {A: 1.1e+107, b: -28.15, Ea: 2.741e+04}
  high-P-rate-constant: {A: 3.6e+13, b: 0.0, Ea: 0.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H9 <=> CH3 + IC3H7  # Reaction 944
  rate-constant: {A: 1.9e+35, b: -5.83, Ea: 2.247e+04}
- equation: H + IC4H9 <=> H2 + IC4H8  # Reaction 945
  rate-constant: {A: 9.0e+11, b: 0.0, Ea: 0.0}
- equation: IC4H9 + O <=> CH2O + IC3H7  # Reaction 946
  rate-constant: {A: 9.6e+13, b: 0.0, Ea: 0.0}
- equation: IC4H9 + OH <=> H2O + IC4H8  # Reaction 947
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: IC4H9 + O2 <=> HO2 + IC4H8  # Reaction 948
  rate-constant: {A: 2.4e+10, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H9 => CH2O + IC3H7 + OH  # Reaction 949
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: HCO + IC4H9 <=> CO + IC4H10  # Reaction 950
  rate-constant: {A: 3.6e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + IC4H9 <=> CH4 + IC4H8  # Reaction 951
  rate-constant: {A: 6.0e+12, b: -0.32, Ea: 0.0}
- equation: TC4H9 (+M) <=> H + IC4H8 (+M)  # Reaction 952
  type: falloff
  low-P-rate-constant: {A: 1.9e+41, b: -7.36, Ea: 3.663e+04}
  high-P-rate-constant: {A: 5.66e+11, b: 0.7, Ea: 3.657e+04}
  Troe: {A: 0.293, T3: 649.0, T1: 6.0e+04, T2: 3426.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, CH2O: 2.5, CH3OH: 3.0,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: H + TC4H9 (+M) <=> IC4H10 (+M)  # Reaction 953
  type: falloff
  low-P-rate-constant: {A: 1.1e+107, b: -28.15, Ea: 2.741e+04}
  high-P-rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + TC4H9 <=> CH3 + IC3H7  # Reaction 954
  rate-constant: {A: 2.6e+36, b: -6.12, Ea: 2.564e+04}
- equation: H + TC4H9 <=> H2 + IC4H8  # Reaction 955
  rate-constant: {A: 5.42e+12, b: 0.0, Ea: 0.0}
- equation: O + TC4H9 <=> IC4H8 + OH  # Reaction 956
  rate-constant: {A: 1.8e+14, b: 0.0, Ea: 0.0}
- equation: O + TC4H9 <=> CH3 + CH3COCH3  # Reaction 957
  rate-constant: {A: 1.8e+14, b: 0.0, Ea: 0.0}
- equation: OH + TC4H9 <=> H2O + IC4H8  # Reaction 958
  rate-constant: {A: 1.8e+13, b: 0.0, Ea: 0.0}
- equation: O2 + TC4H9 <=> HO2 + IC4H8  # Reaction 959
  rate-constant: {A: 4.8e+11, b: 0.0, Ea: 0.0}
- equation: HO2 + TC4H9 => CH3 + CH3COCH3 + OH  # Reaction 960
  rate-constant: {A: 1.8e+13, b: 0.0, Ea: 0.0}
- equation: HCO + TC4H9 <=> CO + IC4H10  # Reaction 961
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + TC4H9 <=> CH4 + IC4H8  # Reaction 962
  rate-constant: {A: 3.8e+15, b: -1.0, Ea: 0.0}
- equation: CH3 + NC3H7 (+M) <=> C4H10 (+M)  # Reaction 963
  type: falloff
  low-P-rate-constant: {A: 2.9137e+61, b: -13.24, Ea: 6000.0}
  high-P-rate-constant: {A: 2.0983e+14, b: -0.32, Ea: 0.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 1434.0, T2: 5329.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: 2 C2H5 (+M) <=> C4H10 (+M)  # Reaction 964
  type: falloff
  low-P-rate-constant: {A: 3.1689e+61, b: -13.42, Ea: 6000.0}
  high-P-rate-constant: {A: 9.1303e+14, b: -0.5, Ea: 0.0}
  Troe: {A: 1.0, T3: 1000.0, T1: 1434.0, T2: 5329.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: C4H10 + H <=> H2 + NC4H9  # Reaction 965
  rate-constant: {A: 9.2e+05, b: 2.54, Ea: 6756.0}
- equation: C4H10 + H <=> H2 + SC4H9  # Reaction 966
  rate-constant: {A: 1.6131e+06, b: 2.4, Ea: 4471.0}
- equation: C4H10 + O <=> NC4H9 + OH  # Reaction 967
  rate-constant: {A: 5.1548e+06, b: 2.4, Ea: 5500.0}
- equation: C4H10 + O <=> OH + SC4H9  # Reaction 968
  rate-constant: {A: 3.963e+05, b: 2.6, Ea: 2580.0}
- equation: C4H10 + OH <=> H2O + NC4H9  # Reaction 969
  rate-constant: {A: 3.6064e+07, b: 1.8, Ea: 954.0}
- equation: C4H10 + OH <=> H2O + SC4H9  # Reaction 970
  rate-constant: {A: 3.9225e+06, b: 2.0, Ea: -596.0}
- equation: C4H10 + O2 <=> HO2 + NC4H9  # Reaction 971
  rate-constant: {A: 4.0e+13, b: 0.0, Ea: 5.093e+04}
- equation: C4H10 + O2 <=> HO2 + SC4H9  # Reaction 972
  rate-constant: {A: 8.0e+13, b: 0.0, Ea: 4.759e+04}
- equation: C4H10 + HO2 <=> H2O2 + NC4H9  # Reaction 973
  rate-constant: {A: 4.76e+04, b: 2.55, Ea: 1.649e+04}
- equation: C4H10 + HO2 <=> H2O2 + SC4H9  # Reaction 974
  rate-constant: {A: 2.0412e+04, b: 2.6, Ea: 1.391e+04}
- equation: C4H10 + CH3 <=> CH4 + NC4H9  # Reaction 975
  rate-constant: {A: 2354.0, b: 2.98, Ea: 1.09e+04}
- equation: C4H10 + CH3 <=> CH4 + SC4H9  # Reaction 976
  rate-constant: {A: 1520.9, b: 2.84, Ea: 8600.0}
- equation: C2H3 + C4H10 <=> C2H4 + NC4H9  # Reaction 977
  rate-constant: {A: 731.0, b: 3.03, Ea: 6144.0}
- equation: C2H3 + C4H10 <=> C2H4 + SC4H9  # Reaction 978
  rate-constant: {A: 488.0, b: 3.03, Ea: 4644.0}
- equation: CH3 + IC3H7 (+M) <=> IC4H10 (+M)  # Reaction 979
  type: falloff
  low-P-rate-constant: {A: 4.4832e+61, b: -13.33, Ea: 3903.0}
  high-P-rate-constant: {A: 4.9789e+15, b: -0.68, Ea: 0.0}
  Troe: {A: 0.931, T3: 6.0e+04, T1: 1265.0, T2: 5470.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H5OH: 4.0, C2H6: 3.0,
    C3H6: 4.0, C3H8: 4.0, CH2O: 2.5, CH3OH: 3.0, CH4: 2.0, CO: 1.5, CO2: 2.0,
    H2: 2.0, H2O: 6.0, HE: 0.7}
- equation: H + IC4H10 <=> H2 + IC4H9  # Reaction 980
  rate-constant: {A: 1.427e+06, b: 2.54, Ea: 6760.0}
- equation: H + IC4H10 <=> H2 + TC4H9  # Reaction 981
  rate-constant: {A: 5.2838e+05, b: 2.4, Ea: 2580.0}
- equation: IC4H10 + O <=> IC4H9 + OH  # Reaction 982
  rate-constant: {A: 4.3e+05, b: 2.5, Ea: 3640.0}
- equation: IC4H10 + O <=> OH + TC4H9  # Reaction 983
  rate-constant: {A: 1.57e+05, b: 2.5, Ea: 1110.0}
- equation: IC4H10 + OH <=> H2O + IC4H9  # Reaction 984
  rate-constant: {A: 2.1705e+08, b: 1.53, Ea: 775.0}
- equation: IC4H10 + OH <=> H2O + TC4H9  # Reaction 985
  rate-constant: {A: 5.73e+10, b: 0.51, Ea: 64.0}
- equation: HO2 + IC4H10 <=> H2O2 + IC4H9  # Reaction 986
  rate-constant: {A: 3.0e+04, b: 2.55, Ea: 1.55e+04}
- equation: HO2 + IC4H10 <=> H2O2 + TC4H9  # Reaction 987
  rate-constant: {A: 3600.0, b: 2.55, Ea: 1.05e+04}
- equation: IC4H10 + O2 <=> HO2 + IC4H9  # Reaction 988
  rate-constant: {A: 4.0e+13, b: 0.0, Ea: 5.09e+04}
- equation: IC4H10 + O2 <=> HO2 + TC4H9  # Reaction 989
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 4.82e+04}
- equation: CH3 + IC4H10 <=> CH4 + IC4H9  # Reaction 990
  rate-constant: {A: 810.0, b: 3.01, Ea: 1.08e+04}
- equation: CH3 + IC4H10 <=> CH4 + TC4H9  # Reaction 991
  rate-constant: {A: 1250.0, b: 2.75, Ea: 7000.0}
- equation: C2H3 + IC4H10 <=> C2H4 + IC4H9  # Reaction 992
  rate-constant: {A: 1100.0, b: 3.03, Ea: 6144.0}
- equation: C2H3 + IC4H10 <=> C2H4 + TC4H9  # Reaction 993
  rate-constant: {A: 0.9, b: 3.46, Ea: 2603.0}
- equation: C2H3COCH3 => C2H3 + CH3 + CO  # Reaction 994
  rate-constant: {A: 7.24e+25, b: -2.72, Ea: 8.77e+04}
- equation: C2H3COCH3 + H => C2H3 + CH2CO + H2  # Reaction 995
  rate-constant: {A: 4.9e+05, b: 2.43, Ea: 5160.0}
- equation: C2H3COCH3 + O => C2H3 + CH2CO + OH  # Reaction 996
  rate-constant: {A: 2.56e+11, b: 0.21, Ea: 4890.0}
- equation: C2H3COCH3 + OH => C2H3 + CH2CO + H2O  # Reaction 997
  rate-constant: {A: 4.17e+13, b: 0.0, Ea: 4670.0}
- equation: C2H3COCH3 + HO2 => C2H3 + CH2CO + H2O2  # Reaction 998
  rate-constant: {A: 8.5e+12, b: 0.0, Ea: 2.046e+04}
- equation: C2H3COCH3 + CH3 => C2H3 + CH2CO + CH4  # Reaction 999
  rate-constant: {A: 1.73e+11, b: 0.0, Ea: 9678.0}
- equation: C2H3COCH3 + C2H3 => C2H4 + CH2CO + C2H3  # Reaction 1000
  rate-constant: {A: 301.0, b: 3.3, Ea: 1.05e+04}
- equation: HCO + NC3H7 <=> C3H7CHO  # Reaction 1001
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + CH2CHO <=> C3H7CHO  # Reaction 1002
  rate-constant: {A: 3.12e+14, b: -0.5, Ea: 0.0}
- equation: C3H7CHO + H => CO + H2 + NC3H7  # Reaction 1003
  rate-constant: {A: 4.1e+09, b: 1.16, Ea: 2405.0}
- equation: C3H7CHO + O => CO + NC3H7 + OH  # Reaction 1004
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 1709.0}
- equation: C3H7CHO + OH => CO + H2O + NC3H7  # Reaction 1005
  rate-constant: {A: 5.36e+06, b: 2.06, Ea: -1308.0}
- equation: C3H7CHO + HO2 => CO + H2O2 + NC3H7  # Reaction 1006
  rate-constant: {A: 1.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C3H7CHO + CH3 => CH4 + CO + NC3H7  # Reaction 1007
  rate-constant: {A: 6.31e+11, b: 0.0, Ea: 7293.0}
- equation: C2H3 + C3H7CHO => C2H4 + CO + NC3H7  # Reaction 1008
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: HCO + IC3H7 <=> IC3H7CHO  # Reaction 1009
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: H + IC3H7CHO => CO + H2 + IC3H7  # Reaction 1010
  rate-constant: {A: 4.1e+09, b: 1.16, Ea: 2405.0}
- equation: IC3H7CHO + O => CO + IC3H7 + OH  # Reaction 1011
  rate-constant: {A: 7.91e+12, b: 0.0, Ea: 1451.0}
- equation: IC3H7CHO + OH => CO + H2O + IC3H7  # Reaction 1012
  rate-constant: {A: 5.36e+06, b: 2.06, Ea: -1308.0}
- equation: HO2 + IC3H7CHO => CO + H2O2 + IC3H7  # Reaction 1013
  rate-constant: {A: 1.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: CH3 + IC3H7CHO => CH4 + CO + IC3H7  # Reaction 1014
  rate-constant: {A: 3.98e+12, b: 0.0, Ea: 8704.0}
- equation: C2H3 + IC3H7CHO => C2H4 + CO + IC3H7  # Reaction 1015
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 8440.0}
- equation: C2H5 + CH3CO <=> C2H5COCH3  # Reaction 1016
  rate-constant: {A: 3.12e+14, b: -0.5, Ea: 0.0}
- equation: CH3 + CH3COCH2 <=> C2H5COCH3  # Reaction 1017
  rate-constant: {A: 1.93e+14, b: -0.32, Ea: 0.0}
- equation: C2H5COCH3 + H => C2H5 + CH2CO + H2  # Reaction 1018
  rate-constant: {A: 4.9e+05, b: 2.43, Ea: 5160.0}
- equation: C2H5COCH3 + H => C2H4 + CH3CO + H2  # Reaction 1019
  rate-constant: {A: 4.9e+05, b: 2.43, Ea: 5160.0}
- equation: C2H5COCH3 + O => C2H5 + CH2CO + OH  # Reaction 1020
  rate-constant: {A: 2.48e+11, b: 0.0, Ea: 2583.0}
- equation: C2H5COCH3 + O => C2H4 + CH3CO + OH  # Reaction 1021
  rate-constant: {A: 2.48e+11, b: 0.0, Ea: 2583.0}
- equation: C2H5COCH3 + OH => C2H5 + CH2CO + H2O  # Reaction 1022
  rate-constant: {A: 3.18e+13, b: 0.0, Ea: 4511.0}
- equation: C2H5COCH3 + OH => C2H4 + CH3CO + H2O  # Reaction 1023
  rate-constant: {A: 3.18e+13, b: 0.0, Ea: 4511.0}
- equation: C2H5COCH3 + HO2 => C2H5 + CH2CO + H2O2  # Reaction 1024
  rate-constant: {A: 8.5e+12, b: 0.0, Ea: 2.046e+04}
- equation: C2H5COCH3 + HO2 => C2H4 + CH3CO + H2O2  # Reaction 1025
  rate-constant: {A: 8.5e+12, b: 0.0, Ea: 2.046e+04}
- equation: C2H5COCH3 + CH3 => C2H5 + CH2CO + CH4  # Reaction 1026
  rate-constant: {A: 1.73e+11, b: 0.0, Ea: 9678.0}
- equation: C2H5COCH3 + CH3 => C2H4 + CH3CO + CH4  # Reaction 1027
  rate-constant: {A: 1.73e+11, b: 0.0, Ea: 9678.0}
- equation: C2H3 + C2H5COCH3 => C2H4 + C2H5 + CH2CO  # Reaction 1028
  rate-constant: {A: 301.0, b: 3.3, Ea: 1.05e+04}
- equation: C2H3 + C2H5COCH3 => 2 C2H4 + CH3CO  # Reaction 1029
  rate-constant: {A: 301.0, b: 3.3, Ea: 1.05e+04}
- equation: CH + O2 <=> CO + OH*  # Reaction 1030
  rate-constant: {A: 1.8e+11, b: 0.0, Ea: 0.0}
- equation: C2H + O <=> CH* + CO  # Reaction 1031
  rate-constant: {A: 2.5e+12, b: 0.0, Ea: 0.0}
- equation: C2H + O2 <=> CH* + CO2  # Reaction 1032
  rate-constant: {A: 3.2e+11, b: 0.0, Ea: 1600.0}
- equation: H + O + M => OH* + M  # Reaction 1033
  type: three-body
  rate-constant: {A: 5.45e+12, b: 0.0, Ea: 0.0}
- equation: H + 2 OH => H2O + OH*  # Reaction 1034
  rate-constant: {A: 1.45e+15, b: 0.0, Ea: 0.0}
- equation: CH* => CH  # Reaction 1035
  rate-constant: {A: 1.85e+06, b: 0.0, Ea: 0.0}
- equation: CH* + N2 <=> CH + N2  # Reaction 1036
  rate-constant: {A: 303.0, b: 3.4, Ea: -381.0}
- equation: CH* + O2 <=> CH + O2  # Reaction 1037
  rate-constant: {A: 2.4e+06, b: 2.14, Ea: -1720.0}
- equation: CH* + H2O <=> CH + H2O  # Reaction 1038
  rate-constant: {A: 5.3e+13, b: 0.0, Ea: 0.0}
- equation: CH* + H2 <=> CH + H2  # Reaction 1039
  rate-constant: {A: 1.47e+14, b: 0.0, Ea: 1361.0}
- equation: CH* + CO2 <=> CH + CO2  # Reaction 1040
  rate-constant: {A: 0.241, b: 4.3, Ea: -1694.0}
- equation: CH* + CO <=> CH + CO  # Reaction 1041
  rate-constant: {A: 2.44e+12, b: 0.5, Ea: 0.0}
- equation: CH* + CH4 <=> CH + CH4  # Reaction 1042
  rate-constant: {A: 1.73e+13, b: 0.0, Ea: 167.0}
- equation: AR + CH* <=> AR + CH  # Reaction 1043
  rate-constant: {A: 1.25e+10, b: 0.5, Ea: 0.0}
- equation: CH* + HE <=> CH + HE  # Reaction 1044
  rate-constant: {A: 1.95e+09, b: 0.5, Ea: 0.0}
- equation: OH* => OH  # Reaction 1045
  rate-constant: {A: 1.45e+06, b: 0.0, Ea: 0.0}
- equation: N2 + OH* <=> N2 + OH  # Reaction 1046
  rate-constant: {A: 1.08e+11, b: 0.5, Ea: -1238.0}
- equation: O2 + OH* <=> O2 + OH  # Reaction 1047
  rate-constant: {A: 2.1e+12, b: 0.5, Ea: -482.0}
- equation: H2O + OH* <=> H2O + OH  # Reaction 1048
  rate-constant: {A: 5.92e+12, b: 0.5, Ea: -861.0}
- equation: H2 + OH* <=> H2 + OH  # Reaction 1049
  rate-constant: {A: 2.95e+12, b: 0.5, Ea: -444.0}
- equation: CO2 + OH* <=> CO2 + OH  # Reaction 1050
  rate-constant: {A: 2.75e+12, b: 0.5, Ea: -968.0}
- equation: CO + OH* <=> CO + OH  # Reaction 1051
  rate-constant: {A: 3.23e+12, b: 0.5, Ea: -787.0}
- equation: CH4 + OH* <=> CH4 + OH  # Reaction 1052
  rate-constant: {A: 3.36e+12, b: 0.5, Ea: -635.0}
- equation: AR + OH* <=> AR + OH  # Reaction 1053
  rate-constant: {A: 1.25e+10, b: 0.5, Ea: 0.0}
- equation: HE + OH* <=> HE + OH  # Reaction 1054
  rate-constant: {A: 1.95e+09, b: 0.5, Ea: 0.0}
